Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+)
Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+)
8th Edition
ISBN: 9780135213759
Author: John McMurry, David Ballantine
Publisher: PEARSON+
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Chapter 14.2, Problem 14.5P

(a)

Interpretation Introduction

Interpretation:

The alcohol should be identified as primary, secondary or tertiary alcohol.

Concept introduction:

Classification of alcohol:

Alcohols can be classified in to three types,

Primary,

Secondary,

Tertiary

Primary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with three hydrogen atoms attached or two hydrogen atoms and one alkyl or aryl group is called primary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  1

Secondary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with one hydrogen atoms and two alkyl or aryl group (two substituent) is called secondary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  2

Tertiary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with three alkyl or aryl group (three substituent) is called tertiary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  3

(b)

Interpretation Introduction

Interpretation:

The alcohol should be identified as primary, secondary or tertiary alcohol.

Concept Introduction:

Classification of alcohol:

Alcohols can be classified in to three types,

Primary,

Secondary,

Tertiary

Primary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with three hydrogen atoms attached or two hydrogen atoms and one alkyl or aryl group is called primary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  4

Secondary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with one hydrogen atoms and two alkyl or aryl group (two substituent) is called secondary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  5

Tertiary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with three alkyl or aryl group (three substituent) is called tertiary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  6

(c)

Interpretation Introduction

Interpretation:

The alcohol should be identified as primary, secondary or tertiary alcohol.

Concept Introduction:

Classification of alcohol:

Alcohols can be classified in to three types,

Primary,

Secondary,

Tertiary

Primary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with three hydrogen atoms attached or two hydrogen atoms and one alkyl or aryl group is called primary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  7

Secondary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with one hydrogen atoms and two alkyl or aryl group (two substituent) is called secondary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  8

Tertiary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with three alkyl or aryl group (three substituent) is called tertiary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  9

(d)

Interpretation Introduction

Interpretation:

The alcohol should be identified as primary, secondary or tertiary alcohol.

Concept Introduction:

Classification of alcohol:

Alcohols can be classified in to three types,

Primary,

Secondary,

Tertiary

Primary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with three hydrogen atoms attached or two hydrogen atoms and one alkyl or aryl group is called primary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  10

Secondary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with one hydrogen atoms and two alkyl or aryl group (two substituent) is called secondary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  11

Tertiary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with three alkyl or aryl group (three substituent) is called tertiary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  12

(e)

Interpretation Introduction

Interpretation:

The alcohol should be identified as primary, secondary or tertiary alcohol.

Concept introduction:

Classification of alcohol:

Alcohols can be classified in to three types,

Primary,

Secondary,

Tertiary

Primary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with three hydrogen atoms attached or two hydrogen atoms and one alkyl or aryl group is called primary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  13

Secondary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with one hydrogen atoms and two alkyl or aryl group (two substituent) is called secondary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  14

Tertiary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with three alkyl or aryl group (three substituent) is called tertiary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  15

(f)

Interpretation Introduction

Interpretation:

The alcohol should be identified as primary, secondary or tertiary alcohol.

Concept introduction:

Classification of alcohol:

Alcohols can be classified in to three types,

Primary,

Secondary,

Tertiary

Primary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with three hydrogen atoms attached or two hydrogen atoms and one alkyl or aryl group is called primary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  16

Secondary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with one hydrogen atoms and two alkyl or aryl group (two substituent) is called secondary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  17

Tertiary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with three alkyl or aryl group (three substituent) is called tertiary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  18

(g)

Interpretation Introduction

Interpretation:

The alcohol should be identified as primary, secondary or tertiary alcohol.

Concept introduction:

Classification of alcohol:

Alcohols can be classified in to three types,

Primary,

Secondary,

Tertiary

Primary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with three hydrogen atoms attached or two hydrogen atoms and one alkyl or aryl group is called primary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  19

Secondary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with one hydrogen atoms and two alkyl or aryl group (two substituent) is called secondary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  20

Tertiary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with three alkyl or aryl group (three substituent) is called tertiary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  21

(h)

Interpretation Introduction

Interpretation:

The alcohol should be identified as primary, secondary or tertiary alcohol.

Concept introduction:

Classification of alcohol:

Alcohols can be classified in to three types,

Primary,

Secondary,

Tertiary

Primary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with three hydrogen atoms attached or two hydrogen atoms and one alkyl or aryl group is called primary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  22

Secondary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with one hydrogen atoms and two alkyl or aryl group (two substituent) is called secondary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  23

Tertiary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with three alkyl or aryl group (three substituent) is called tertiary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  24

(i)

Interpretation Introduction

Interpretation:

The alcohol should be identified as primary, secondary or tertiary alcohol.

Concept introduction:

Classification of alcohol:

Alcohols can be classified in to three types,

Primary,

Secondary,

Tertiary

Primary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with three hydrogen atoms attached or two hydrogen atoms and one alkyl or aryl group is called primary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  25

Secondary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with one hydrogen atoms and two alkyl or aryl group (two substituent) is called secondary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  26

Tertiary alcohol:

Hydroxyl group (OH) is attached to carbon atom which is bonded with three alkyl or aryl group (three substituent) is called tertiary alcohol.

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+), Chapter 14.2, Problem 14.5P , additional homework tip  27

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Students have asked these similar questions
The beta-lactamase hydrolyzes the lactam-ring in penicillin. Describe the mechanism  of hydrolysis, insuring to include the involvement of S, D, & K in the reaction sequence. Please help
To map the active site of beta-lactamase, the enzyme was hydrolyzed with trypsin to yield a hexapeptide (P1) with the following amino acids. Glu, Lys, Leu, Phe, Met, and Ser. Treatment of P1 with phenyl isothiocyanate yielded a PTH derivative of phenylalanine and a peptide (P2). Treatment of P1 with cyanogenbromide gave an acidic tetrapeptide (P3) and a dipeptide (P4).Treatment of P2 with 1-fluoro-2,4-dinitrobenzene, followed by complete hydrolysis, yields N-2,4-dinitrophenyl-Glu. P1, P2, and P3 contain the active site serine. Why doesn't D in this hexapeptide not participate in the hydrolysis of the beta-lactam ring even though S, K, and D are involved in the catalyst?
To map the active site of -lactamase, the enzyme was hydrolyzed with trypsin to yield a hexapeptide (P1) with the following amino acids. Glu, Lys, Leu, Phe, Met, and Ser. Treatment of P1 with phenyl isothiocyanate yielded a PTH derivative of phenylalanine and a peptide (P2). Treatment of P1 with cyanogenbromide gave an acidic tetrapeptide (P3) and a dipeptide (P4).Treatment of P2 with 1-fluoro-2,4-dinitrobenzene, followed by complete hydrolysis, yields N-2,4-dinitrophenyl-Glu. P1, P2, and P3 contain the active site serine.  Using the experimental results described above derive the primary sequence of the active site hexapeptide. Please help!

Chapter 14 Solutions

Pearson eText Fundamentals of General, Organic, and Biological Chemistry -- Instant Access (Pearson+)

Ch. 14.4 - Prob. 14.8PCh. 14.4 - What alcohols yield the following alkenes as the...Ch. 14.4 - Prob. 14.10KCPCh. 14.4 - What products would you expect from oxidation of...Ch. 14.4 - Prob. 14.12PCh. 14.4 - Prob. 14.13KCPCh. 14.5 - Prob. 14.14PCh. 14.5 - Prob. 14.15PCh. 14.7 - Prob. 14.1CIAPCh. 14.7 - Prob. 14.2CIAPCh. 14.7 - Prob. 14.3CIAPCh. 14.7 - Prob. 14.16PCh. 14.8 - What disulfides would you obtain from oxidation of...Ch. 14.9 - Prob. 14.18PCh. 14.10 - Prob. 14.19PCh. 14.10 - Prob. 14.20PCh. 14.10 - Prob. 14.4CIAPCh. 14.10 - Prob. 14.5CIAPCh. 14.10 - Prob. 14.6CIAPCh. 14.10 - Prob. 14.7CIAPCh. 14 - Prob. 14.21UKCCh. 14 - Prob. 14.22UKCCh. 14 - Prob. 14.23UKCCh. 14 - Prob. 14.24UKCCh. 14 - Prob. 14.25UKCCh. 14 - How do alcohols, ethers, and phenols differ...Ch. 14 - What is the structural difference between primary,...Ch. 14 - Prob. 14.28APCh. 14 - Prob. 14.29APCh. 14 - The Taxane nucleus is shown here; it is the basis...Ch. 14 - Vitamin E has the structure shown. Identify the...Ch. 14 - Give systematic names for the following alcohols:...Ch. 14 - Give systematic names for the following compound...Ch. 14 - Draw structures corresponding to the following...Ch. 14 - Draw structures corresponding to the following...Ch. 14 - Prob. 14.36APCh. 14 - Locate the alcohol functional groups in the taxane...Ch. 14 - Prob. 14.38APCh. 14 - Prob. 14.39APCh. 14 - Prob. 14.40APCh. 14 - Prob. 14.41APCh. 14 - Prob. 14.42APCh. 14 - Prob. 14.43APCh. 14 - Assume that you have samples of the following two...Ch. 14 - Which of the following alcohols can undergo...Ch. 14 - The following alkenes can be prepared by...Ch. 14 - Prob. 14.47APCh. 14 - Prob. 14.48APCh. 14 - What alcohols would you oxidize to obtain the...Ch. 14 - Prob. 14.50APCh. 14 - What is the structural relationship between a...Ch. 14 - Prob. 14.52APCh. 14 - Prob. 14.53APCh. 14 - Prob. 14.54APCh. 14 - Prob. 14.55APCh. 14 - Prob. 14.56APCh. 14 - Prob. 14.57APCh. 14 - Identify the chiral center(s) in each of the...Ch. 14 - Are the following molecules chiral or achiral? If...Ch. 14 - Prob. 14.60CPCh. 14 - Prob. 14.61CPCh. 14 - 1-Propanol is freely soluble in water, 1-butanol...Ch. 14 - Prob. 14.63CPCh. 14 - Prob. 14.64CPCh. 14 - Prob. 14.65CPCh. 14 - Prob. 14.66CPCh. 14 - Prob. 14.67CPCh. 14 - Prob. 14.68CPCh. 14 - Prob. 14.69CPCh. 14 - Prob. 14.70CPCh. 14 - Prob. 14.71CPCh. 14 - Prob. 14.72CPCh. 14 - (a)Draw all possible cyclic C7H14O alcohol isomers...Ch. 14 - Prob. 14.74GPCh. 14 - Prob. 14.75GP
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