Chemistry In Focus
Chemistry In Focus
7th Edition
ISBN: 9781337399692
Author: Tro, Nivaldo J.
Publisher: Cengage Learning,
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Chapter 14, Problem 37E
Interpretation Introduction

Interpretation:

The overall cell reaction for the given half-cell is to be determined.

Concept Introduction:

Oxidation is the addition of an electronegative element or the removal of an electropositive element in a chemical reaction.

Reduction is the addition of an electropositive element or the removal of an electronegative element in a chemical reaction.

The chemical reaction in which both oxidation and reduction takes place simultaneously is called a redox reaction.

Electrolysis is the process in which a redox reaction takes place at the electrodes. The electrode that is charged positively is called the anode. The electrode that is charged negatively is called the cathode. During electrolysis, the reduction takes place at the cathode and oxidation takes place at the anode.

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Reagan is doing an atomic absorption experiment that requires a set of zinc standards in the 0.4- 1.6 ppm range. A 1000 ppm Zn solution was prepared by dissolving the necessary amount of solid Zn(NO3)2 in water. The standards can be prepared by diluting the 1000 ppm Zn solution. Table 1 shows one possible set of serial dilutions (stepwise dilution of a solution) that Reagan could perform to make the necessary standards. Solution A was prepared by diluting 5.00 ml of the 1000 ppm Zn standard to 50.00 ml. Solutions C-E are called "calibration standards" because they will be used to calibrate the atomic absorption spectrometer. Table 1: Dilutions of Zinc Solutions Solution Zinc Solution Volume Diluted Solution Concentration used volume (ppm Zn) (mL) (mL) concentration (ppm Zn) Solution concentration A 1000 5.00 50.00 1.00×10² (ppm Zn(NO3)2) 2.90×10² Solution concentration (M Zn(NO3)2 1.53×10-3 B Solution A 5.00 100.00 5.00 C Solution B 5.00 50.00 0.50 7.65×10-6 D Solution B 10.00 50.00…
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Chemistry In Focus

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