Chemistry In Focus
7th Edition
ISBN: 9781337399692
Author: Tro, Nivaldo J.
Publisher: Cengage Learning,
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Chapter 14, Problem 12E
Interpretation Introduction
Interpretation:
The working principle of an
Concept Introduction:
Oxidation is the addition of an electronegative element or the removal of an electropositive element in a
Reduction is the addition of an electropositive element or the removal of an electronegative element in a chemical reaction.
The chemical reaction in which oxidation process and reduction process take place simultaneously, is called a redox reaction.
An electrochemical cell is also known as a galvanic or voltaic cell.
The electrochemical cell is a type of battery that converts chemical energy into electrical energy.
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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
with full details solution please
Chapter 14 Solutions
Chemistry In Focus
Ch. 14 - For the following redox reaction, identify the...Ch. 14 - Prob. 14.2YTCh. 14 - Prob. 1SCCh. 14 - The respiration reaction is shown below. Identify...Ch. 14 - Closely examine Figure 14.1 and explain why no...Ch. 14 - Prob. 1ECh. 14 - Explain the basic principle involved common...Ch. 14 - Prob. 3ECh. 14 - Prob. 4ECh. 14 - Prob. 5E
Ch. 14 - Can an oxidation reaction occur without a...Ch. 14 - Prob. 7ECh. 14 - Why is bromine reduced in the following reaction...Ch. 14 - What is an oxidizing agent? A reducing agent?Ch. 14 - Prob. 10ECh. 14 - Write equations for respiration and...Ch. 14 - Prob. 12ECh. 14 - Prob. 13ECh. 14 - Prob. 14ECh. 14 - Prob. 15ECh. 14 - Give a thermodynamic argument for why it is more...Ch. 14 - Prob. 17ECh. 14 - Use chemical equations to explain how the molten...Ch. 14 - Prob. 19ECh. 14 - Prob. 20ECh. 14 - Prob. 21ECh. 14 - Prob. 22ECh. 14 - Prob. 23ECh. 14 - Prob. 24ECh. 14 - Draw Lewis structures for each chemical reaction,...Ch. 14 - Draw Lewis structures for each chemical reaction,...Ch. 14 - Prob. 27ECh. 14 - For each reaction, indicate which elements are...Ch. 14 - For each reaction, indicate which elements are...Ch. 14 - For each reaction, indicate which elements are...Ch. 14 - For each reaction, identify the oxidizing agent...Ch. 14 - Prob. 32ECh. 14 - Prob. 33ECh. 14 - Prob. 34ECh. 14 - Which would you expect to be a better oxidizing...Ch. 14 - Prob. 36ECh. 14 - Prob. 37ECh. 14 - Sum each of the following oxidation and reduction...Ch. 14 - Prob. 39ECh. 14 - Prob. 40ECh. 14 - Which of the following factors might affect the...Ch. 14 - Prob. 42ECh. 14 - Prob. 43ECh. 14 - Fossil fuel, nuclear, and hydroelectric power...Ch. 14 - The following diagram shows an electrochemical...Ch. 14 - The following diagram shows a molecular view of...
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