Concept explainers
Blood is buffered mainly by the
(a) Calculate the
(b) What does the pH become if 15% of the
(c) What does the pH become if 15% of the
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Chemistry: Principles and Reactions
- At 25 C, a 0.10% aqueous solution of adipic acid, C5H9O2COOH, has a pH of 3.2. A saturated solution of the acid, which contains 1.44 g acid per 100. mL of solution, has a pH = 2.7. Calculate the percent dissociation of adipic acid in each solution.arrow_forwardWhat is the pH of a solution obtained by mixing 235 mL of NaOH with a pH of 11.57 and 316 mL of Sr(OH)2 with a pH of 12.09? Assume that volumes are additive.arrow_forwardWrite an equation for each of the following buffering actions. a. the response of a HPO42/PO43 buffer to the addition of OH ions b. the response of a HF/F buffer to the addition of OH ions c. the response of a HCN/CN buffer to the addition of H3O+ ions d. the response of a H3PO4/H2PO4 buffer to the addition of H3O+ ionsarrow_forward
- Two strategies are also followed when solving for the pH of a base in water. What is the strategy for calculating the pH of a strong base in water? List the strong bases mentioned in the text that should be committed to memory. Why is calculating the pH of Ca(OH)2 solutions a little more difficult than calculating the pH of NaOH solutions? Most bases are weak bases. The presence of what element most commonly results in basic properties for an organic compound? What is present on this element in compounds that allows it to accept a proton? Table 13-3 and Appendix 5 of the text list Kb values for some weak bases. What strategy is used to solve for the pH of a weak base in water? What assumptions are made when solving for the pH of weak base solutions? If the 5% rule fails, how do you calculate the pH of a weak base in water?arrow_forwardAcids You make a solution by dissolving 0.0010 mol of HCl in enough water to make 1.0 L of solution. a Write the chemical equation for the reaction of HCl(aq) and water. b Without performing calculations, give a rough estimate of the pH of the HCl solution. Justify your answer. c Calculate the H3O+ concentration and the pH of the solution. d Is there any concentration of the base OH present in this solution of HCl(aq)? If so, where did it come from? e If you increase the OH concentration of the solution by adding NaOH, does the H3O+ concentration change? If you think it does, explain why this change occurs and whether the H3O+ concentration increases or decreases. f If you were to measure the pH of 10 drops of the original HCl solution, would you expect it to be different from the pH of the entire sample? Explain. g Explain how two different volumes of your original HCl solution can have the same pH yet contain different moles of H3O+. h If 1.0 L of pure water were added to the HCl solution, would this have any impact on the pH? Explain.arrow_forward. A buffered solution is prepared containing acetic acid, HC2H3O2, and sodium acetate, NaC2H3O2, both at 0.5 M. Write a chemical equation showing how this buffered solution would resist a decrease in its pH if a few drops of aqueous strong acid HCI solution were added to it. Write a chemical equation showing how this buffered solution would resist an increase in its pH if a few drops of aqueous strong base NaOH solution were added to it.arrow_forward
- Methylammonium chloride is a salt of methylamine, CH3NH2. A 0.10 M solution of this salt has a pH of 5.82. a Calculate the value for the equilibrium constant for the reaction CH3NH3++H2OCH3NH2+H3O+ b What is the Kb value for methylamine? c What is the pH of a solution in which 0.450 mol of solid methylammonium chloride is added to 1.00 L of a 0.250 M solution of methylamine? Assume no volume change.arrow_forwardBarbituric acid, HC4H3N2O3, is used to prepare barbiturates, a class of drugs used as sedatives. A 325-mL aqueous solution of barbituric acid has a pH of 2.34 and contains 9.00 g of the acid. What is Ka for barbituric acid?arrow_forwardChloroacetic acid, HC2H2ClO2, has a greater acid strength than acetic acid, because the electronegative chlorine atom pulls electrons away from the OH bond and thus weakens it. Calculate the hydronium-ion concentration and the pH of a 0.0020 M solution of chloroacetic acid, Ka is 1.3 103.arrow_forward
- Consider a solution prepared by mixing a weak acid HA and HCl. What are the major species? Explain what is occurring in solution. How would you calculate the pH? What if you added NaA to this solution? Then added NaOH?arrow_forwardIonization of the first proton from H2SO4 is complete (H2SO4 is a strong acid); the acid-ionization constant for the second proton is 1.1 102. a What would be the approximate hydronium-ion concentration in 0.100 M H2SO4 if ionization of the second proton were ignored? b The ionization of the second proton must be considered for a more exact answer, however. Calculate the hydronium-ion concentration in 0.100 M H2SO4, accounting for the ionization of both protons.arrow_forwardThe pH of Mixtures of Acid, Base, and Salt Solutions a When 0.10 mol of the ionic solid NaX, where X is an unknown anion, is dissolved in enough water to make 1.0 L of solution, the pH of the solution is 9.12. When 0.10 mol of the ionic solid ACl, where A is an unknown cation, is dissolved in enough water to make 1.0 L of solution, the pH of the solution is 7.00. What would be the pH of 1.0 L of solution that contained 0.10 mol of AX? Be sure to document how you arrived at your answer. b In the AX solution prepared above, is there any OH present? If so, compare the [OH] in the solution to the [H3O+]. c From the information presented in part a, calculate Kb for the X(aq) anion and Ka for the conjugate acid of X(aq). d To 1.0 L of solution that contains 0.10 mol of AX, you add 0.025 mol of HCl. How will the pH of this solution compare to that of the solution that contained only NaX? Use chemical reactions as part of your explanation; you do not need to solve for a numerical answer. e Another 1.0 L sample of solution is prepared by mixing 0.10 mol of AX and 0.10 mol of HCl. The pH of the resulting solution is found to be 3.12. Explain why the pH of this solution is 3.12. f Finally, consider a different 1.0-L sample of solution that contains 0.10 mol of AX and 0.1 mol of NaOH. The pH of this solution is found to be 13.00. Explain why the pH of this solution is 13.00. g Some students mistakenly think that a solution that contains 0.10 mol of AX and 0.10 mol of HCl should have a pH of 1.00. Can you come up with a reason why students have this misconception? Write an approach that you would use to help these students understand what they are doing wrong.arrow_forward
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