For the given reaction under given reaction conditions that is with given slope value as + 0.04 L / m o l . s the rate law for the given chemical equation should be determined. Concept introduction: In order to establish the plausibility of a mechanism, one must compare the rate law of the rate determining step to the experimentally determined rate law. Rate determining step: In a chemical reaction the rate determining step is the slowest step in which the rate of the reaction depends on the rate of that slowest step. Rate law: It is generally the rate equation that consists of the reaction rate with the concentration or the pressures of the reactants and constant parameters. Activation energy: It is defined as the minimum energy required by the reacting species in order to undergo chemical reaction. Rate constant: The rate constant for a chemical reaction is the proportionality term in the chemical reaction rate law which gives the relationship between the rate and the concentration of the reactant present in the chemical reaction. Intermediate species: It is the species formed during the middle of the chemical reaction between the reactant and the desired product.
For the given reaction under given reaction conditions that is with given slope value as + 0.04 L / m o l . s the rate law for the given chemical equation should be determined. Concept introduction: In order to establish the plausibility of a mechanism, one must compare the rate law of the rate determining step to the experimentally determined rate law. Rate determining step: In a chemical reaction the rate determining step is the slowest step in which the rate of the reaction depends on the rate of that slowest step. Rate law: It is generally the rate equation that consists of the reaction rate with the concentration or the pressures of the reactants and constant parameters. Activation energy: It is defined as the minimum energy required by the reacting species in order to undergo chemical reaction. Rate constant: The rate constant for a chemical reaction is the proportionality term in the chemical reaction rate law which gives the relationship between the rate and the concentration of the reactant present in the chemical reaction. Intermediate species: It is the species formed during the middle of the chemical reaction between the reactant and the desired product.
Solution Summary: The author explains the rate law for a given chemical reaction under given reaction conditions. The rate determining step is the slowest step.
Definition Definition Transformation of a chemical species into another chemical species. A chemical reaction consists of breaking existing bonds and forming new ones by changing the position of electrons. These reactions are best explained using a chemical equation.
Chapter 14, Problem 35PS
Interpretation Introduction
Interpretation:
For the given reaction under given reaction conditions that is with given slope value as +0.04L/mol.s the rate law for the given chemical equation should be determined.
Concept introduction:
In order to establish the plausibility of a mechanism, one must compare the rate law of the rate determining step to the experimentally determined rate law.
Rate determining step: In a chemical reaction the rate determining step is the slowest step in which the rate of the reaction depends on the rate of that slowest step.
Rate law: It is generally the rate equation that consists of the reaction rate with the concentration or the pressures of the reactants and constant parameters.
Activation energy: It is defined as the minimum energy required by the reacting species in order to undergo chemical reaction.
Rate constant: The rate constant for a chemical reaction is the proportionality term in the chemical reaction rate law which gives the relationship between the rate and the concentration of the reactant present in the chemical reaction.
Intermediate species: It is the species formed during the middle of the chemical reaction between the reactant and the desired product.
Describe the principle of resonance and give a set of Lewis Structures to illustrate your explanation.
Don't used hand raiting
It is not unexpected that the methoxyl substituent on a cyclohexane ring
prefers to adopt the equatorial conformation.
OMe
H
A G₂ = +0.6 kcal/mol
OMe
What is unexpected is that the closely related 2-methoxytetrahydropyran
prefers the axial conformation:
H
H
OMe
OMe
A Gp=-0.6 kcal/mol
Methoxy: CH3O group
Please be specific and clearly write the reason why this is observed. This effect that provides
stabilization of the axial OCH 3 group in this molecule is called the anomeric effect. [Recall in the way of
example, the staggered conformer of ethane is more stable than eclipsed owing to bonding MO
interacting with anti-bonding MO...]
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