Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 14, Problem 21PS
At 573 K, gaseous NO2(g) decomposes, forming NO(g) and O2(g). If a vessel containing NO2(g) has an initial concentration of 1.9 × 10−2 mol/L, how long will it take for 75% of the NO2(g) to decompose? The decomposition of NO2(g) is second-order in the reactant and the rate constant for this reaction, at 573 K, is 1.1 L/mol · s.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
None
In the phase diagram of steel (two components Fe and C), region A is the gamma austenite solid and region B contains the gamma solid and liquid. Indicate the degrees of freedom that the fields A and B have,
For a condensed binary system in equilibrium at constant pressure, indicate the maximum number of phases that can exist.
Chapter 14 Solutions
Chemistry & Chemical Reactivity
Ch. 14.1 - Sucrose decomposes to fructose and glucose in acid...Ch. 14.1 - What are the relative rates of appearance or...Ch. 14.3 - The initial rate ( [NO]/ t] of the reaction of...Ch. 14.3 - The rate constant, k, at 25 C is 0.27/h for the...Ch. 14.4 - Sucrose, a sugar, decomposes in acid solution to...Ch. 14.4 - Gaseous azomethane (CH3N2CH3) decomposes to ethane...Ch. 14.4 - Prob. 14.7CYUCh. 14.4 - The catalyzed decomposition of hydrogen peroxide...Ch. 14.4 - Americium is used in smoke detectors and in...Ch. 14.5 - Prob. 14.10CYU
Ch. 14.5 - The colorless gas N2O4, decomposes to the brown...Ch. 14.7 - Nitrogen monoxide is reduced by hydrogen to give...Ch. 14.7 - Prob. 14.13CYUCh. 14.7 - One possible mechanism for the decomposition of...Ch. 14.7 - Prob. 1.1ACPCh. 14.7 - Prob. 1.2ACPCh. 14.7 - Prob. 2.1ACPCh. 14.7 - Prob. 2.2ACPCh. 14.7 - Prob. 2.3ACPCh. 14.7 - Determine the activation energy for the reaction...Ch. 14 - Give the relative rates of disappearance of...Ch. 14 - Give the relative rates of disappearance of...Ch. 14 - In the reaction 2 O3(g) 3 O2(g), the rate of...Ch. 14 - In the synthesis of ammonia, if [H2]/t = 4.5 104...Ch. 14 - Experimental data are listed here for the reaction...Ch. 14 - Phenyl acetate, an ester, reacts with water...Ch. 14 - Using the rate equation Rate = k[A]2[B], define...Ch. 14 - A reaction has the experimental rate equation Rate...Ch. 14 - The reaction between ozone and nitrogen dioxide at...Ch. 14 - Nitrosyl bromide, NOBr, is formed from NO and Br2:...Ch. 14 - The data in the table are for the reaction of NO...Ch. 14 - The reaction 2 NO(g) + 2 H2(g) N2(g) + 2 H2O(g)...Ch. 14 - Data for the reaction NO(g) + O2(g) NO2(g) are...Ch. 14 - Data for the following reaction are given in the...Ch. 14 - The rate equation for the hydrolysis of sucrose to...Ch. 14 - The decomposition of N2O5 in CCl4 is a first-order...Ch. 14 - The decomposition of SO2Cl2 is a first-order...Ch. 14 - The conversion of cyclopropane to propene (Example...Ch. 14 - Hydrogen peroxide, H2O2(aq), decomposes to H2O()...Ch. 14 - The decomposition of nitrogen dioxide at a high...Ch. 14 - At 573 K, gaseous NO2(g) decomposes, forming NO(g)...Ch. 14 - The dimerization of butadiene, C4H6, to form...Ch. 14 - The decomposition of ammonia on a metal surface to...Ch. 14 - Hydrogen iodide decomposes when heated, forming...Ch. 14 - The rate equation for the decomposition of N2O5...Ch. 14 - Gaseous azomethane, CH3N=NCH3, decomposes in a...Ch. 14 - The decomposition of SO2Cl2 SO2Cl2(g) SO2(g) +...Ch. 14 - The compound Xe(CF3)2 decomposes in a first-order...Ch. 14 - The radioactive isotope 64Cu is used in the form...Ch. 14 - Radioactive gold-198 is used in the diagnosis of...Ch. 14 - Prob. 31PSCh. 14 - Ammonia decomposes when heated according to the...Ch. 14 - Gaseous NO2 decomposes at 573 K. NO2(g) NO(g) + ...Ch. 14 - The decomposition of HOF occurs at 25 C. HOF(g) ...Ch. 14 - Prob. 35PSCh. 14 - Prob. 36PSCh. 14 - Calculate the activation energy, Ea, for the...Ch. 14 - If the rate constant for a reaction triples when...Ch. 14 - When healed lo a high temperature, cyclobutane,...Ch. 14 - When heated, cyclopropane is converted to propene...Ch. 14 - The reaction of H2 molecules with F atoms H2(g) +...Ch. 14 - Prob. 42PSCh. 14 - Compare the lock-and-key and induced-fit models...Ch. 14 - Prob. 44PSCh. 14 - Prob. 45PSCh. 14 - The enzyme carbonic anhydrase catalyzes the...Ch. 14 - What is the rate law for each of the following...Ch. 14 - What is the rate law for each of the following...Ch. 14 - Ozone, O3, in the Earths upper atmosphere...Ch. 14 - The reaction of NO2(g) and CO(g) is thought to...Ch. 14 - A proposed mechanism for the reaction of NO2 and...Ch. 14 - The mechanism for the reaction of CH3OH and HBr is...Ch. 14 - A reaction has the following experimental rate...Ch. 14 - For a first-order reaction, what fraction of...Ch. 14 - Prob. 55GQCh. 14 - Data for the following reaction are given in the...Ch. 14 - Formic acid decomposes at 550 C according to the...Ch. 14 - Isomerization of CH3NC occurs slowly when CH3NC is...Ch. 14 - When heated, tetrafluoroethylene dimerizes to form...Ch. 14 - Data in the table were collected at 540 K for the...Ch. 14 - Ammonium cyanate, NH4NCO, rearranges in water to...Ch. 14 - Prob. 62GQCh. 14 - At temperatures below 500 K, the reaction between...Ch. 14 - Nitryl fluoride can be made by treating nitrogen...Ch. 14 - The decomposition of dinitrogen pentaoxide N2O5(g)...Ch. 14 - The data in the table give the temperature...Ch. 14 - The decomposition of gaseous dimethyl ether at...Ch. 14 - The decomposition of phosphine, PH3, proceeds...Ch. 14 - The thermal decomposition of diacetylene, C4H2,...Ch. 14 - Prob. 70GQCh. 14 - The ozone in the Earths ozone layer decomposes...Ch. 14 - Hundreds of different reactions occur in the...Ch. 14 - Data for the reaction [Mn(CO)5(CH3CN)]+ + NC5H5 ...Ch. 14 - The gas-phase reaction 2 N2O5(g) 4 NO2(g) + O2(g)...Ch. 14 - Prob. 75GQCh. 14 - The decomposition of SO2Cl2 to SO2 and Cl2 is...Ch. 14 - The decomposition of nitrogen dioxide at a high...Ch. 14 - Prob. 78GQCh. 14 - Egg protein albumin is precipitated when an egg is...Ch. 14 - A The compound 1,3-butadiene (C4H6) forms...Ch. 14 - Hypofluorous acid, HOF, is very unstable,...Ch. 14 - We know that the decomposition of SO2Cl2 is...Ch. 14 - Nitramide, NO2NH2, decomposes slowly in aqueous...Ch. 14 - Prob. 84GQCh. 14 - The color change accompanying the reaction of...Ch. 14 - Prob. 87ILCh. 14 - Prob. 88ILCh. 14 - The oxidation of iodide ion by the hypochlorite...Ch. 14 - The acid-catalyzed iodination of acetone...Ch. 14 - Prob. 91SCQCh. 14 - The following statements relate to the reaction...Ch. 14 - Chlorine atoms contribute to the destruction of...Ch. 14 - Prob. 95SCQCh. 14 - Prob. 96SCQCh. 14 - The reaction cyclopropane propene occurs on a...Ch. 14 - Prob. 98SCQCh. 14 - Examine the reaction coordinate diagram given...Ch. 14 - Draw a reaction coordinate diagram for an...Ch. 14 - Consider the reaction of ozone and nitrogen...
Additional Science Textbook Solutions
Find more solutions based on key concepts
6. How can you use the features found in each chapter?
Human Anatomy & Physiology (2nd Edition)
Describe the role and impact of microbes on the earth.
Microbiology Fundamentals: A Clinical Approach
More than one choice may apply. Using the terms listed below, fill in the blank with the proper term. anterior ...
Essentials of Human Anatomy & Physiology (12th Edition)
The validity of a scientific law.
Physical Universe
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Part V. Label ad match the carbons in compounds Jane and Diane w/ the corresponding peak no. in the Spectra (Note: use the given peak no. To label the carbons, other peak no are intentionally omitted) 7 4 2 -0.13 -0.12 -0.11 -0.10 -0.08 8 CI Jane 1 -0.09 5 210 200 190 180 170 160 150 140 130 120 110 100 -8 90 f1 (ppm) 11 8 172.4 172.0 f1 (ppr HO CI NH Diane 7 3 11 80 80 -80 -R 70 60 60 2 5 -8 50 40 8. 170 160 150 140 130 120 110 100 90 -0 80 70 20 f1 (ppm) 15 30 -20 20 -60 60 -0.07 -0.06 -0.05 -0.04 -0.03 -0.02 -0.01 -0.00 -0.01 10 -0.17 16 15 56 16 -0.16 -0.15 -0.14 -0.13 -0.12 -0.11 -0.10 -0.09 -0.08 -0.07 -0.06 -0.05 -0.04 17.8 17.6 17.4 17.2 17.0 f1 (ppm) -0.03 -0.02 550 106 40 30 20 20 -0.01 -0.00 F-0.01 10 0arrow_forwardConsider the reaction of 2-methylpropane with a halogen. With which halogen will the product be almost exclusively 2-halo-2-methylpropane? 1. F2 2. Cl2 3. Br2 4. I2arrow_forwardNonearrow_forward
- Nonearrow_forwardn Feb 3 A T + 4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how you confirmed the structure. 5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of Limonene. 6. (1 pts) Predict the 1H NMR spectral data of R-Limonene. Proton NMR: 5.3 pon multiplet (H Ringarrow_forwardPart VI. Ca H 10 O is the molecular formula of compound Tom and gives the in the table below. Give a possible structure for compound Tom. 13C Signals summarized C1 C2 C3 C4 C5 C6 C7 13C shift (ppm) 23.5 27.0 33.0 35.8 127 162 205 DEPT-90 + DEPT-135 + +arrow_forward
- 2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at 373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.arrow_forwardPart VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forward
- Part IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward13C NMR is good for: a) determining the molecular weight of the compound b) identifying certain functional groups. c) determining the carbon skeleton, for example methyl vs ethyl vs propyl groups d) determining how many different kinds of carbon are in the moleculearrow_forward6 D 2. (1 pt) Limonene can be isolated by performing steam distillation of orange peel. Could you have performed this experiment using hexane instead of water? Explain. 3. (2 pts) Using GCMS results, analyze and discuss the purity of the Limonene obtained from the steam distillation of orange peel.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Kinetics: Initial Rates and Integrated Rate Laws; Author: Professor Dave Explains;https://www.youtube.com/watch?v=wYqQCojggyM;License: Standard YouTube License, CC-BY