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OWLv2 for Ebbing/Gammon's General Chemistry, 11th Edition, [Instant Access], 1 term (6 months)
11th Edition
ISBN: 9781305673939
Author: Darrell Ebbing; Steven D. Gammon
Publisher: Cengage Learning US
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Textbook Question
Chapter 14, Problem 14.59QP
Hydrogen fluoride decomposes according to the following equation:
The value of Kc at room temperature is 10 × 10−95. From the magnitude of Kc, do you think the decomposition occurs to any great extent at room temperature? If an equilibrium mixture in a 1.0-L vessel contains 1.0 mol HF, what is the amount of H2 formed? Does this result agree with what you expect from the magnitude of Kc?
Expert Solution & Answer
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Part I.
a) Elucidate
the structure of compound A using the following information.
• mass spectrum: m+ = 102, m/2=57
312=29
• IR spectrum:
1002.5
% TRANSMITTANCE
Ngg
50
40
30
20
90
80
70
60
MICRONS
5
8
9 10
12
13
14 15 16
19
1740 cm
M
10
0
4000
3600
3200
2800
2400
2000
1800
1600
13
• CNMR
'H
-NMR
Peak
8
ppm (H)
Integration
multiplicity
a
1.5 (3H)
triplet
b
1.3
1.5 (3H)
triplet
C
2.3
1 (2H)
quartet
d
4.1
1 (2H)
quartet
& ppm (c)
10
15
28
60
177 (C=0)
b) Elucidate the structure of compound B using the following information
13C/DEPT NMR 150.9 MHz
IIL
1400
WAVENUMBERS (CM-1)
DEPT-90
DEPT-135
85 80 75
70
65
60
55
50
45 40
35
30 25 20
ppm
1200
1000
800
600
400
•
Part II.
a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below:
• IR spectra
% TRANSMITTANCE
1002.5
90
80
70
60
50
40
30
20
10
0
4000
3600
3200
2800
2400
2000
1800
1600
• Information from 'HAMR
MICRONS
8 9 10
11
14 15 16
19
25
1400
WAVENUMBERS (CM-1)
1200
1000
800
600
400
peak
8 ppm
Integration
multiplicity
a
2.1
1.5 (3H)
Singlet
b
3.6
1 (2H)
singlet
с
3.8
1.5 (3H)
Singlet
d
6.8
1(2H)
doublet
7.1
1(2H)
doublet
Information from 13C-nmR
Normal carbon
29ppm
Dept 135
Dept -90
+
NO peak
NO peak
50 ppm
55 ppm
+
NO peak
114 ppm
t
126 ppm
No peak
NO peak
130 ppm
t
+
159 ppm
No peak
NO peak
207 ppm
по реак
NO peak
Could you redraw these and also explain how to solve them for me pleas
Chapter 14 Solutions
OWLv2 for Ebbing/Gammon's General Chemistry, 11th Edition, [Instant Access], 1 term (6 months)
Ch. 14.1 - Synthesis gas (a mixture of CO and H2) is...Ch. 14.1 - Two substances A and B react to produce substance...Ch. 14.2 - a. Write the equilibrium-constant expression Kc...Ch. 14.2 - When 1.00 mol each of carbon monoxide and water...Ch. 14.2 - Hydrogen sulfide, a colorless gas with a foul...Ch. 14.2 - Phosphorus pentachloride dissociates on heating:...Ch. 14.2 - Consider the following hypothetical reactions. The...Ch. 14.3 - The Mond process for purifying nickel involves the...Ch. 14.4 - The equilibrium constant Kc for the reaction...Ch. 14.5 - A 10.0-L vessel contains 0.0015 mol CO2 and 0.10...
Ch. 14.5 - Carbon monoxide and hydrogen react in the presence...Ch. 14.6 - Phosphorus pentachloride gives an equilibrium...Ch. 14.6 - What is the equilibrium composition of a reaction...Ch. 14.6 - Phosphorus pentachloride, PCl5, decomposes when...Ch. 14.6 - Prob. 14.4CCCh. 14.7 - Prob. 14.12ECh. 14.8 - Can you increase the amount of product in each of...Ch. 14.8 - Prob. 14.14ECh. 14.8 - Prob. 14.5CCCh. 14.8 - Prob. 14.15ECh. 14 - Consider the reaction N2O4(g)2NO2(g). Draw a graph...Ch. 14 - When 1.0 mol each of H2(g) and I2(g) are mixed at...Ch. 14 - Prob. 14.3QPCh. 14 - Obtain the equilibrium constant for the reaction...Ch. 14 - Which of the following reactions involve...Ch. 14 - Prob. 14.6QPCh. 14 - Prob. 14.7QPCh. 14 - Prob. 14.8QPCh. 14 - Prob. 14.9QPCh. 14 - Prob. 14.10QPCh. 14 - How is it possible for a catalyst to give products...Ch. 14 - Prob. 14.12QPCh. 14 - A chemist put 1.18 mol of substance A and 2.85 mol...Ch. 14 - The reaction 3A(g)+B(s)2C(aq)+D(aq) occurs at 25C...Ch. 14 - A graduate student places 0.272 mol of PCl3(g) and...Ch. 14 - An experimenter places the following...Ch. 14 - Chemical Equilibrium I Part 1: You run the...Ch. 14 - Chemical Equilibrium II Magnesium hydroxide....Ch. 14 - During an experiment with the Haber process, a...Ch. 14 - Suppose liquid water and water vapor exist in...Ch. 14 - A mixture initially consisting of 2 mol CO and 2...Ch. 14 - Prob. 14.22QPCh. 14 - For the reaction 2HI(g)H2(g)+I2(g) carried out at...Ch. 14 - An experimenter introduces 4.0 mol of gas A into a...Ch. 14 - The following reaction is earned out at 500 K in a...Ch. 14 - For the endothermic reaction AB(g)A(g)+B(g), the...Ch. 14 - Prob. 14.27QPCh. 14 - Prob. 14.28QPCh. 14 - A 2.500-mol sample of phosphorus pentachloride,...Ch. 14 - You place 4.00 mol of dinitrogen trioxide, N2O3,...Ch. 14 - You place 0.600 mol of nitrogen, N2, and 1.800 mol...Ch. 14 - Nitrogen monoxide, NO, reacts with bromine, Br2,...Ch. 14 - In the contact process, sulfuric acid is...Ch. 14 - Methanol, CH3OH, formerly known as wood alcohol,...Ch. 14 - Write equilibrium-constant expressions Kc for each...Ch. 14 - Write equilibrium-constant expressions Kc for each...Ch. 14 - The equilibrium-constant expression for a gas...Ch. 14 - Prob. 14.38QPCh. 14 - The equilibrium-constant expression for a reaction...Ch. 14 - Prob. 14.40QPCh. 14 - The equilibrium constant Kc, for the equation...Ch. 14 - The equilibrium constant Kc for the equation...Ch. 14 - A 13.0-L reaction vessel at 499C contained...Ch. 14 - A 4.00-L vessel contained 0.0148 mol of phosphorus...Ch. 14 - Obtain the value of Kc for the following reaction...Ch. 14 - Obtain the value of Kc for the following reaction...Ch. 14 - At 60C, 3.76 mol of nitrosyl bromide, NOBr, placed...Ch. 14 - A 2 00-mol sample of nitrogen dioxide was placed...Ch. 14 - Write equilibrium-constant expressions Kp for each...Ch. 14 - Write equilibrium-constant expressions Kp for each...Ch. 14 - The value of Kc for the following reaction at 298C...Ch. 14 - The equilibrium constant Kc equals 0.0952 for the...Ch. 14 - The reaction SO2(g)+12O2(g)SO3(g) has Kp equal to...Ch. 14 - Fluorine, F2, dissociates into atoms on heating....Ch. 14 - Write the expression for the equilibrium constant...Ch. 14 - For each of the following equations, give the...Ch. 14 - On the basis of the value of Kc decide whether or...Ch. 14 - Would either of the following reactions go almost...Ch. 14 - Hydrogen fluoride decomposes according to the...Ch. 14 - Suppose sulfur dioxide reacts with oxygen at 25C....Ch. 14 - The following reaction has an equilibrium constant...Ch. 14 - The following reaction has an equilibrium constant...Ch. 14 - Methanol, CH3OH, is manufactured industrially by...Ch. 14 - Sulfur trioxide, used to manufacture sulfuric...Ch. 14 - Phosgene, COCl2, used in the manufacture of...Ch. 14 - Nitrogen monoxide, NO, is formed in automobile...Ch. 14 - Iodine and bromine react to give iodine...Ch. 14 - Initially a mixture contains 0.850 mol each of N2...Ch. 14 - Calculate the composition of the gaseous mixture...Ch. 14 - The equilibrium constant Kc, for the reaction...Ch. 14 - Suppose 1.000 mol CO and 3.000 mol H2 are put in a...Ch. 14 - The equilibrium constant Kc for the reaction...Ch. 14 - Consider the equilibrium FeO(s)+CO(g)Fe(s)+CO2(g)...Ch. 14 - a Predict the direction of reaction when chlorine...Ch. 14 - What would you expect to be the effect of an...Ch. 14 - Indicate whether either an increase or a decrease...Ch. 14 - Methanol is prepared industrially from synthesis...Ch. 14 - One way of preparing hydrogen is by the...Ch. 14 - Use thermochemical data (Appendix C) to decide...Ch. 14 - Use thermochemical data (Appendix C) to decide...Ch. 14 - What would you expect to be the general...Ch. 14 - Predict the general temperature and pressure...Ch. 14 - A mixture of carbon monoxide, hydrogen, and...Ch. 14 - Prob. 14.84QPCh. 14 - At 850C and 1.000 atm pressure, a gaseous mixture...Ch. 14 - An equilibrium mixture of dinitrogen tetroxide,...Ch. 14 - A 2.50-L vessel contains 1.75 mol N2, 1.75 mol H2,...Ch. 14 - A vessel originally contained 0.0200 mol iodine...Ch. 14 - A gaseous mixture containing 1.00 mol each of CO,...Ch. 14 - A 2.0-L reaction flask initially contains 0.010...Ch. 14 - Hydrogen bromide decomposes when heated according...Ch. 14 - Iodine monobromide, IBr, occurs as brownish-black...Ch. 14 - Phosgene, COCl2, is a toxic gas used in the...Ch. 14 - Dinitrogen tetroxide, N2O4, is a colorless gas...Ch. 14 - Prob. 14.95QPCh. 14 - Prob. 14.96QPCh. 14 - The amount of nitrogen dioxide formed by...Ch. 14 - The equilibrium constant Kc for the synthesis of...Ch. 14 - For the reaction N2(g)+3H2(g)2NH3(g) show that Kc...Ch. 14 - Prob. 14.100QPCh. 14 - At high temperatures, a dynamic equilibrium exists...Ch. 14 - At high temperatures, a dynamic equilibrium exists...Ch. 14 - The equilibrium constant Kc for the reaction...Ch. 14 - At 25C in a closed system, ammonium hydrogen...Ch. 14 - At moderately high temperatures, SbCl5 decomposes...Ch. 14 - The following reaction is important in the...Ch. 14 - Sulfuryl chloride is used in organic chemistry as...Ch. 14 - Phosgene was used as a poisonous gas in World War...Ch. 14 - Gaseous acetic acid molecules have a certain...Ch. 14 - Gaseous acetic acid molecules have a certain...Ch. 14 - When 0.112 mol of NO and 18.22 g of bromine are...Ch. 14 - Prob. 14.112QPCh. 14 - Prob. 14.113QPCh. 14 - Prob. 14.114QPCh. 14 - A chemist placed a mixture of CO2(g) and CF4(g)...Ch. 14 - Prob. 14.116QPCh. 14 - Prob. 14.117QPCh. 14 - The equilibrium constant Kc for the equation...Ch. 14 - Consider the reaction N2O4(g)2NO2(g). Would you...Ch. 14 - A researcher put 0.400 mol PCl3 and 0.600 mol Cl2...Ch. 14 - Ammonium hydrogen sulfide. NH4HS, is unstable at...Ch. 14 - A chemist wants to prepare phosgene, COCl2, by the...Ch. 14 - Prob. 14.123QPCh. 14 - Prob. 14.124QPCh. 14 - Prob. 14.125QPCh. 14 - A container with a volume of 1.500 L was evacuated...Ch. 14 - Prob. 14.127QPCh. 14 - Prob. 14.128QPCh. 14 - Prob. 14.129QPCh. 14 - Sulfur dioxide reacts with oxygen to produce...Ch. 14 - Molecular bromine, Br2, dissociates at elevated...Ch. 14 - Consider the production of ammonia from its...Ch. 14 - A mixture of 0.0565 mol phosphorus pentachloride,...Ch. 14 - Calcium carbonate, CaCO3, decomposes when heated...Ch. 14 - The following equilibrium was studied by analyzing...Ch. 14 - Prob. 14.136QPCh. 14 - Phosphorus pentachloride, PCl5, decomposes on...Ch. 14 - Antimony(V) chloride. SbCl5, decomposes on heating...
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