Quantitative Chemical Analysis
Quantitative Chemical Analysis
9th Edition
ISBN: 9781464135385
Author: Daniel C. Harris
Publisher: W. H. Freeman
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Chapter 14, Problem 14.32P
Interpretation Introduction

Interpretation:

Eo value for the half-reaction has to be calculated.

Concept introduction:

Nernst equation can be used to determine the cell potential at any instant, the difference from the standard state.

E = E0.05916nlog[B]b[H+]m[A]a

Where:

E = cell potential under nonstandard conditions

Eo = cell potential under standard conditions
n = number of moles of electrons exchanged in the electrochemical reaction

Solubility product: Ksp It is defined as the product formed from mathematical product of its concentration of dissolved ion raised up to the power of their stoichiometric coefficient.

MyXz(s)yM(aq)Z++zX(aq)y-Ksp=[MZ+]y[Xy-]z

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