Quantitative Chemical Analysis
Quantitative Chemical Analysis
9th Edition
ISBN: 9781464135385
Author: Daniel C. Harris
Publisher: W. H. Freeman
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Chapter 14, Problem 14.31P
Interpretation Introduction

Interpretation:

The net cell reaction and its equilibrium constant has to be calculated.

Concept introduction:

Nernst equation can be used to determine the cell potential at any instant, the difference from the standard state.

E = E0.05916nlog[B]b[H+]m[A]a

Where:

E = cell potential under nonstandard conditions

Eo = cell potential under standard conditions
n = number of moles of electrons exchanged in the electrochemical reaction

Finding K from Eo

K=10nEo0.05916at25oC

Where K is equilibrium constant

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Quantitative Chemical Analysis

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