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Concept explainers
(a)
Interpretation:
Resonance contributor for the enolate ion formed from the given compounds has to be identified.
Concept Introduction:
Tautomerism is the ability of a molecule to exist in more than one chemical form. Tautomers are formed by the migration of a hydrogen atom, accompanied by the switching of a single and neighboring double bond.
The only difference in keto-enol tautomers is the location of hydrogen and double bond.
Enol tautomer is much less stable than the keto tautomer.
Enol tautomer is more stable when enol tautomer is
Resonance: The delocalization of electrons which is characterized as several structural changes.
(b)
Interpretation:
Resonance contributor for the enolate ion formed from the given compounds has to be identified.
Concept Introduction:
Tautomerism is the ability of a molecule to exist in more than one chemical form. Tautomers are formed by the migration of a hydrogen atom, accompanied by the switching of a single and neighboring double bond.
The only difference in keto-enol tautomers is the location of hydrogen and double bond.
Enol tautomer is much less stable than the keto tautomer.
Enol tautomer is more stable when enol tautomer is aromatic or when the double bonds are conjugated.
Resonance: The delocalization of electrons which is characterized as several structural changes.
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Chapter 13 Solutions
EBK ESSENTIAL ORGANIC CHEMISTRY
- Explain the difference between the propagated uncertainty and the standard deviation. Which number would you use to describe the uncertainty in the measurement? if the standard deviation is 0.01 and the propagated uncertainty is 0.03arrow_forwardPropagation of uncertainty. Find the absolute and percent relative uncertainty assuming the ±-values are random error. 7.65±0.04 + 5.28±0.02 – 1.12±0.01 85.6±0.9 × 50.2±0.7 ÷ 13.8±0.5 [4.88±0.07 + 3.22±0.05] / 1.53±0.02arrow_forwardExplain the difference between the propagated uncertainty and the standard deviation. Which number would you use to describe the uncertainty in the measurement?arrow_forward
- Circle the compound in each pair where the indicated bond vibrates at higher frequency. WHY IS THIS? Provide thorough explanation to tie topic.arrow_forwardHow can you distinguish between each pair of compounds below using IR? Cite a bond and frequency that can be used to distinguish. Provide thorough steps and explanation.arrow_forwardPropagation of uncertainty. Find the absolute and percent relative uncertainty assuming the ±-values are random error. 65±0.04 + 5.28±0.02 – 1.12±0.01 6±0.9 × 50.2±0.7 ÷ 13.8±0.5 [4.88±0.07 + 3.22±0.05] / 1.53±0.02arrow_forward
- Match to correct spectrum and explain the bonds and frequencies used to tell what spectrum connected to the given option. Thanks.arrow_forwardDraw the virtual orbitals for the planar and pyramidal forms of CH3 and for the linear and bent forms of CH2arrow_forwardQ2: Draw the molecules based on the provided nomenclatures below: (2R,3S)-2-chloro-3-methylpentane: (2S, 2R)-2-hydroxyl-3,6-dimethylheptane:arrow_forward
- Q3: Describes the relationship (identical, constitutional isomers, enantiomers or diastereomers) of each pair of compounds below. ག H CH3 OH OH CH3 H3C OH OH OH ////////// C CH3 CH3 CH3 CH3 H3C CH 3 C/III..... Physics & Astronomy www.physics.northweste COOH H нош..... H 2 OH HO CH3 HOOC H CH3 CH3 CH3 Br. H H Br and H H H Harrow_forwardQ1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label each compound as chiral or achiral. OH HO CI Br H CI CI Br CI CI Xf x f g Br D OH Br Br H₂N R. IN Ill I -N S OMe D II H CO₂H 1/111 DuckDuckGarrow_forwardThese are synthesis questions. You need to show how the starting material can be converted into the product(s) shown. You may use any reactions we have learned. Show all the reagents you need. Show each molecule synthesized along the way and be sure to pay attention to the regiochemistry and stereochemistry preferences for each reaction. If a racemic molecule is made along the way, you need to draw both enantiomers and label the mixture as "racemic". All of the carbon atoms of the products must come from the starting material! ? H Harrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage LearningOrganic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
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