EBK ESSENTIAL ORGANIC CHEMISTRY
EBK ESSENTIAL ORGANIC CHEMISTRY
3rd Edition
ISBN: 8220100659461
Author: Bruice
Publisher: PEARSON
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Chapter 13, Problem 48P
Interpretation Introduction

Interpretation: Reason behind the formation of acetone containing 18O when enzymatic decarboxylation of acetoacetate is carried out in H218O has to be stated.

Concept introduction: Decarboxylation of acetoacetate is initiated by an enzyme named acetoacetate decarboxylase. Enzyme forms protonate imine with substrate acetoacetate. It loses carbondioxide in presence of a H218O to form an enamine. The reaction proceeds further and undergoes hydrolysis to regenerate the enzyme.

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5. Drawn the structure of the compound (molecular formula C12H16) with the longest λmax in its UV-vis spectrum.
Use solubility rules to complete balance molecular equations, and provide total and net ionic equations.
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