(a) Interpretation: The structure of cis-2-octene should be drawn. Concept Introduction: The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

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Answer 1

Question

Chapter 13.3, Problem 13.5PP

Interpretation Introduction

(a)

Interpretation:

The structure of cis-2-octene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

Interpretation Introduction

(b)

Interpretation:

The structure of trans-3-heptene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

Interpretation Introduction

(c)

Interpretation:

The structure of trans-4-methyl-2-pentene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

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Answer 2

Question

Chapter 13.3, Problem 13.5PP

Interpretation Introduction

(a)

Interpretation:

The structure of cis-2-octene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

Interpretation Introduction

(b)

Interpretation:

The structure of trans-3-heptene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

Interpretation Introduction

(c)

Interpretation:

The structure of trans-4-methyl-2-pentene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

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Answer 3

Question

Chapter 13.3, Problem 13.5PP

Interpretation Introduction

(a)

Interpretation:

The structure of cis-2-octene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

Interpretation Introduction

(b)

Interpretation:

The structure of trans-3-heptene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

Interpretation Introduction

(c)

Interpretation:

The structure of trans-4-methyl-2-pentene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

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Answer 4

Question

Chapter 13.3, Problem 13.5PP

Interpretation Introduction

(a)

Interpretation:

The structure of cis-2-octene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

Interpretation Introduction

(b)

Interpretation:

The structure of trans-3-heptene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

Interpretation Introduction

(c)

Interpretation:

The structure of trans-4-methyl-2-pentene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

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Answer 5

Chapter 13.3, Problem 13.5PP

Interpretation Introduction

(a)

Interpretation:

The structure of cis-2-octene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

Interpretation Introduction

(b)

Interpretation:

The structure of trans-3-heptene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

Interpretation Introduction

(c)

Interpretation:

The structure of trans-4-methyl-2-pentene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

Answer 6

Chapter 13.3, Problem 13.5PP

Interpretation Introduction

(a)

Interpretation:

The structure of cis-2-octene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

Answer 7

Chapter 13.3, Problem 13.5PP

Interpretation Introduction

(a)

Interpretation:

The structure of cis-2-octene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of trans-3-heptene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of trans-3-heptene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of trans-4-methyl-2-pentene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of trans-4-methyl-2-pentene should be drawn.

Concept Introduction:

The rotation around the carbon atoms of a double bond is restricted. So, groups on one side of the double bond cannot rotate to the other side. Depending on the side of the alkyl group attached to the double bond, there are two stereoisomers as cis and trans. Trans indicates that the alkyl groups are on opposing sides and cis indicates that the alkyl groups are on same side.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 13.1 - Convert each condensed structure to a complete...Ch. 13.1 - Prob. 13.1P Ch. 13.1 - Complete the structure of zingiberene, a component...Ch. 13.2 - Prob. 13.2PP Ch. 13.2 - Prob. 13.3P Ch. 13.2 - Prob. 13.3PP Ch. 13.2 - Prob. 13.4PP Ch. 13.3 - Prob. 13.5PP Ch. 13.3 - Prob. 13.4P Ch. 13.3 - Prob. 13.6PP

Solution Summary: The author explains that the rotation around the carbon atoms of a double bond is restricted.

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