(a) Interpretation: The structure of muscalure must be drawn with the correct geometry around the double bond. Concept introduction: cis-trans isomerism is also known as geometric isomerism, is used for di-substituted double bonds. Cis isomers have the two substitutes on the same side and trans isomers have the substituents on opposite sides of the double bonds.

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Answer 1

Question

Chapter 13, Problem 42P

Interpretation Introduction

(a)

Interpretation:

The structure of muscalure must be drawn with the correct geometry around the double bond.

Concept introduction:

cis-trans isomerism is also known as geometric isomerism, is used for di-substituted double bonds. Cis isomers have the two substitutes on the same side and trans isomers have the substituents on opposite sides of the double bonds.

Interpretation Introduction

(b)

Interpretation:

The structure of cinnamaldehyde must be drawn with the correct geometry around the double bond.

Concept introduction:

cis-trans isomerism is also known as geometric isomerism, is used for di-substituted double bonds. Cis isomers have the two substitutes on the same side and trans isomers have the substituents on opposite sides of the double bonds.

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Two cations that exchange an electron in an interface, the exchange density is worth 1.39 mA/cm2 and the current density is worth 15 mA/cm2 at 25°C. If the overvoltage is 0.14 V, calculate the reaction rate and symmetry factor. Data: R = 8,314 J mol-1 k-1: F = 96500 C

With the help of the Tafel line, it is estimated that the interchange density of the VO2+/VO2+ system on the carbon paper has a value of 3 mA cm-2. Calculate a) the current density if the voltage has a value of 1.6 mV and the temperature is 25°C. b) the beta value of the anódico process if the Tafel pendulum is 0.6 V at 25°C. Data: R = 8.314 JK-1mol-1, y F = 96485 C mol-1.

Answer 2

Question

Chapter 13, Problem 42P

Interpretation Introduction

(a)

Interpretation:

The structure of muscalure must be drawn with the correct geometry around the double bond.

Concept introduction:

cis-trans isomerism is also known as geometric isomerism, is used for di-substituted double bonds. Cis isomers have the two substitutes on the same side and trans isomers have the substituents on opposite sides of the double bonds.

Interpretation Introduction

(b)

Interpretation:

The structure of cinnamaldehyde must be drawn with the correct geometry around the double bond.

Concept introduction:

cis-trans isomerism is also known as geometric isomerism, is used for di-substituted double bonds. Cis isomers have the two substitutes on the same side and trans isomers have the substituents on opposite sides of the double bonds.

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Answer 3

Question

Chapter 13, Problem 42P

Interpretation Introduction

(a)

Interpretation:

The structure of muscalure must be drawn with the correct geometry around the double bond.

Concept introduction:

cis-trans isomerism is also known as geometric isomerism, is used for di-substituted double bonds. Cis isomers have the two substitutes on the same side and trans isomers have the substituents on opposite sides of the double bonds.

Interpretation Introduction

(b)

Interpretation:

The structure of cinnamaldehyde must be drawn with the correct geometry around the double bond.

Concept introduction:

cis-trans isomerism is also known as geometric isomerism, is used for di-substituted double bonds. Cis isomers have the two substitutes on the same side and trans isomers have the substituents on opposite sides of the double bonds.

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Answer 4

Question

Chapter 13, Problem 42P

Interpretation Introduction

(a)

Interpretation:

The structure of muscalure must be drawn with the correct geometry around the double bond.

Concept introduction:

cis-trans isomerism is also known as geometric isomerism, is used for di-substituted double bonds. Cis isomers have the two substitutes on the same side and trans isomers have the substituents on opposite sides of the double bonds.

Interpretation Introduction

(b)

Interpretation:

The structure of cinnamaldehyde must be drawn with the correct geometry around the double bond.

Concept introduction:

cis-trans isomerism is also known as geometric isomerism, is used for di-substituted double bonds. Cis isomers have the two substitutes on the same side and trans isomers have the substituents on opposite sides of the double bonds.

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Answer 5

Chapter 13, Problem 42P

Interpretation Introduction

(a)

Interpretation:

The structure of muscalure must be drawn with the correct geometry around the double bond.

Concept introduction:

cis-trans isomerism is also known as geometric isomerism, is used for di-substituted double bonds. Cis isomers have the two substitutes on the same side and trans isomers have the substituents on opposite sides of the double bonds.

Interpretation Introduction

(b)

Interpretation:

The structure of cinnamaldehyde must be drawn with the correct geometry around the double bond.

Concept introduction:

cis-trans isomerism is also known as geometric isomerism, is used for di-substituted double bonds. Cis isomers have the two substitutes on the same side and trans isomers have the substituents on opposite sides of the double bonds.

Answer 6

Chapter 13, Problem 42P

Interpretation Introduction

(a)

Interpretation:

The structure of muscalure must be drawn with the correct geometry around the double bond.

Concept introduction:

cis-trans isomerism is also known as geometric isomerism, is used for di-substituted double bonds. Cis isomers have the two substitutes on the same side and trans isomers have the substituents on opposite sides of the double bonds.

Answer 7

Chapter 13, Problem 42P

Interpretation Introduction

(a)

Interpretation:

The structure of muscalure must be drawn with the correct geometry around the double bond.

Concept introduction:

cis-trans isomerism is also known as geometric isomerism, is used for di-substituted double bonds. Cis isomers have the two substitutes on the same side and trans isomers have the substituents on opposite sides of the double bonds.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of cinnamaldehyde must be drawn with the correct geometry around the double bond.

Concept introduction:

cis-trans isomerism is also known as geometric isomerism, is used for di-substituted double bonds. Cis isomers have the two substitutes on the same side and trans isomers have the substituents on opposite sides of the double bonds.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of cinnamaldehyde must be drawn with the correct geometry around the double bond.

Concept introduction:

cis-trans isomerism is also known as geometric isomerism, is used for di-substituted double bonds. Cis isomers have the two substitutes on the same side and trans isomers have the substituents on opposite sides of the double bonds.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 13.1 - Convert each condensed structure to a complete...Ch. 13.1 - Prob. 13.1P Ch. 13.1 - Complete the structure of zingiberene, a component...Ch. 13.2 - Prob. 13.2PP Ch. 13.2 - Prob. 13.3P Ch. 13.2 - Prob. 13.3PP Ch. 13.2 - Prob. 13.4PP Ch. 13.3 - Prob. 13.5PP Ch. 13.3 - Prob. 13.4P Ch. 13.3 - Prob. 13.6PP

Solution Summary: The author explains that cis-trans isomerism is used for di-substituted double bonds. The functional groups of the double bond should be drawn on the same side.

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Chapter 13 Solutions