Organic Chemistry, Books a la Carte Edition (9th Edition)

9th Edition

ISBN: 9780134160382

Author: Leroy G. Wade, Jan W. Simek

Publisher: PEARSON

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Textbook Question

Chapter 13.10, Problem 13.18P

Predict the theoretical number of different NMR signals produced by each compound, and give approximate chemical shifts. Point out any diastereotopic relationships.

a. 2-bromobutane
b. cyclopentanol
c. Ph—CHBr—CH₂ Br
d. vinyl chloride

Chapter 13.10, Problem 13.18P, Predict the theoretical number of different NMR signals produced by each compound, and give

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Chapter 13.10, Problem 13.17P

Chapter 13.11B, Problem 13.19P

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Chapter 13 Solutions

Organic Chemistry, Books a la Carte Edition (9th Edition)

Ch. 13.5A - In a 300-MHz spectrometer, the protons in...Ch. 13.5B - Prob. 13.2P Ch. 13.6 - Determine the number of different kinds of protons...Ch. 13.6 - Prob. 13.4P Ch. 13.7 - Draw the integral trace expected for the NMR...Ch. 13.7 - Prob. 13.6P Ch. 13.8C - Draw the NMR spectra you would expect for the...Ch. 13.8D - Draw the NMR spectra you expect for the following...Ch. 13.8D - a. Assign protons to the peaks in the NMR spectrum...Ch. 13.8D - Prob. 13.10P

Ch. 13.8D - Two spectra are shown. Propose a structure that...Ch. 13.9 - Prob. 13.12P Ch. 13.9 - The spectrum of trans-hex-2-enoic acid follows. a....Ch. 13.9 - Prob. 13.14P Ch. 13.9 - Prob. 13.15P Ch. 13.10 - Prob. 13.16P Ch. 13.10 - If the imaginary replacement of either of two...Ch. 13.10 - Predict the theoretical number of different NMR...Ch. 13.11B - Prob. 13.19P Ch. 13.11B - Prob. 13.20P Ch. 13.11B - Prob. 13.21P Ch. 13.11B - Prob. 13.22P Ch. 13.11B - Prob. 13.23P Ch. 13.11B - Prob. 13.24P Ch. 13.12E - Draw the expected broadband-decoupled 13 C N M R...Ch. 13.12E - a. Show which carbon atoms correspond with which...Ch. 13.12E - Repeat Problem13-25, sketching the...Ch. 13.12F - Prob. 13.28P Ch. 13.13 - A bottle of allyl bromide was found to contain a...Ch. 13.13 - A laboratory student was converting cyclohexanol...Ch. 13.14 - Sets of spectra are given for two compounds. For...Ch. 13 - An unknown compound has the molecular formula C 9...Ch. 13 - Prob. 13.34SP Ch. 13 - Predict the approximate chemical shifts of the...Ch. 13 - Prob. 13.36SP Ch. 13 - Prob. 13.37SP Ch. 13 - Prob. 13.38SP Ch. 13 - Prob. 13.39SP Ch. 13 - Prob. 13.40SP Ch. 13 - For each compound shown below. 1. sketch the 13 C...Ch. 13 - Prob. 13.42SP Ch. 13 - Prob. 13.43SP Ch. 13 - Prob. 13.44SP Ch. 13 - Prob. 13.45SP Ch. 13 - Prob. 13.46SP Ch. 13 - A compound was isolated as a minor constituent in...Ch. 13 - Prob. 13.48SP Ch. 13 - The three isomers of dimethylbenzene are commonly...Ch. 13 - a. Draw all six isomers of formula C 4 H 8...Ch. 13 - Prob. 13.51SP Ch. 13 - Hexamethylbenzene undergoes free-radical...Ch. 13 - Each of these four structures has molecular...Ch. 13 - Prob. 13.54SP Ch. 13 - Phenyl Grignard reagent adds to 2-methylpropanal...Ch. 13 - Prob. 13.56SP

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Predict the theoretical number of different NMR signals produced by each compound, and give approximate chemical shifts. Point out any diastereotopic relationships. a. 2-bromobutane b. cyclopentanol c. Ph—CHBr—CH 2 Br d. vinyl chloride

Solution Summary: The author explains that NMR spectroscopy determines the carbon-hydrogen bonding of an organic compound.

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Chapter 13 Solutions