nucleophile: e-donor electrophile: e acceptor Q. No. IV). organometallics are always nucleophiles Predict the products for each of the following reactions. Indicate a rational mechanism in each case. Label each reactant as a nucleophile or an electrophile. 8 1. 2. (CH3)3 COH + (CH3)3CMaBr (CH3), comgBr + Mechanism: (CH3)3c0JH + (CH3)3 cm (CH3)3 CH γ Mechanism: 3. CH3C CH CHO + H CH3MgBr + NaN H2 + Mechanism: CH3 C = GJ H Mechanism: 5' BF3 Mechanism: CO2 CH3 Jmg Br + NGÀNH, Omg Br C-H CHB CH3C=C-Na + инзт Li + cooli ༠༠; CH3OCH3 F3B
nucleophile: e-donor electrophile: e acceptor Q. No. IV). organometallics are always nucleophiles Predict the products for each of the following reactions. Indicate a rational mechanism in each case. Label each reactant as a nucleophile or an electrophile. 8 1. 2. (CH3)3 COH + (CH3)3CMaBr (CH3), comgBr + Mechanism: (CH3)3c0JH + (CH3)3 cm (CH3)3 CH γ Mechanism: 3. CH3C CH CHO + H CH3MgBr + NaN H2 + Mechanism: CH3 C = GJ H Mechanism: 5' BF3 Mechanism: CO2 CH3 Jmg Br + NGÀNH, Omg Br C-H CHB CH3C=C-Na + инзт Li + cooli ༠༠; CH3OCH3 F3B
Chapter16: Chemistry Of Benzene: Electrophilic Aromatic Substitution
Section16.SE: Something Extra
Problem 30MP: The carbocation electrophile in a Friede1-Crafts reaction can be generated by an alternate means...
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(SE EX 2) Problems can you please explain them to me in detail and color-code anything if necessary?

Transcribed Image Text:nucleophile: e-donor
electrophile: e acceptor
Q. No. IV).
organometallics
are always
nucleophiles
Predict the products for each of the following reactions. Indicate a rational mechanism
in each case. Label each reactant as a nucleophile or an electrophile.
8
1.
2.
(CH3)3 COH
+
(CH3)3CMaBr
(CH3), comgBr
+
Mechanism:
(CH3)3c0JH
+
(CH3)3 cm
(CH3)3 CH
γ
Mechanism:
3.
CH3C CH
CHO
+
H
CH3MgBr
+ NaN H2
+
Mechanism:
CH3 C = GJ H
Mechanism:
5'
BF3
Mechanism:
CO2
CH3 Jmg Br
+
NGÀNH,
Omg Br
C-H
CHB
CH3C=C-Na
+
инзт
Li
+
cooli
༠༠;
CH3OCH3
F3B
<H3
L-A
+
L.B CH3
q
58-03
nucleophiles
attack positive_end
of polar bonds
Determine by polarity-
CH3
снэ
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