INTRO.TO GENERAL,ORGAN...-OWLV2 ACCESS
12th Edition
ISBN: 9781337915977
Author: Bettelheim
Publisher: CENGAGE L
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Chapter 13, Problem 43P
(Chemical Connections
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3.4
Consider the internal energy of a substance
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For a system, the excited state decays to the ground state with a half-life of 15 ns, emitting radiation of 6000 Å. Determine the Einstein coefficients for stimulated absorption and spontaneous emission and the dipole moment of the transition. Data: epsilon 0 = 8.85419x10-12 C2m-1J-1
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Chapter 13 Solutions
INTRO.TO GENERAL,ORGAN...-OWLV2 ACCESS
Ch. 13.1 - Prob. 13.1QCCh. 13.1 - Prob. 13.2QCCh. 13.2 - Problem 14-3 Draw structural formulas for the...Ch. 13.2 - Prob. 13.4QCCh. 13.2 - Prob. 13.5QCCh. 13.3 - Problem 14-6 Write the common name for each ether.Ch. 13.4 - Prob. 13.7QCCh. 13.4 - Prob. 13.8QCCh. 13 - 14-8 Answer true or false. The functional group of...Ch. 13 - 14-9 What is the difference in structure between a...
Ch. 13 - 14-10 Which of the following are secondary...Ch. 13 - 14-11 Which of the alcohols in Problem 14-10 are...Ch. 13 - 14-12 Write the 1UPAC name of each compound. (e)...Ch. 13 - Prob. 6PCh. 13 - Prob. 7PCh. 13 - 14-15 Both alcohols and phenols contain an —OH...Ch. 13 - Prob. 9PCh. 13 - 14-17 Explain in terms of noncovalent interactions...Ch. 13 - Prob. 11PCh. 13 - Prob. 12PCh. 13 - 14-20 Show hydrogen bonding between methanol and...Ch. 13 - 14-21 Show hydrogen bonding between the oxygen of...Ch. 13 - 14-22 Arrange these compounds in order of...Ch. 13 - 14-23 Arrange these compounds in order of...Ch. 13 - 14-24 2-Propanol (isopropyl alcohol) is commonly...Ch. 13 - Prob. 18PCh. 13 - Prob. 19PCh. 13 - Prob. 20PCh. 13 - 14-28 Give the structural formula of an alkene or...Ch. 13 - Prob. 22PCh. 13 - 14-30 Show how to distinguish between cyclohexanol...Ch. 13 - 14-31 Compare the acidity of alcohols and phenols,...Ch. 13 - 14-32 Both 2,6-diisopropylcyclohexanol and the...Ch. 13 - 14-33 Write equations for the reaction of...Ch. 13 - 14-34 Write equations for the reaction of...Ch. 13 - 14-35 Write equations for the reaction of each of...Ch. 13 - 14-36 Show how to convert cyclohexanol to these...Ch. 13 - Prob. 30PCh. 13 - Prob. 31PCh. 13 - 14-39 Name two important alcohols derived from...Ch. 13 - 14-40 Name two important alcohols derived from...Ch. 13 - Prob. 34PCh. 13 - 14-42 Write the common name for each ether. ch3...Ch. 13 - Prob. 36PCh. 13 - 14-44 Answer true or false. (a) The functional...Ch. 13 - Prob. 38PCh. 13 - Write the common name for each thiol in Problem 38...Ch. 13 - 14-47 Following are structural formulas for...Ch. 13 - 14-48 Explain why methanethiol, CH3SH, has a lower...Ch. 13 - 14-49 Answer true or false. Today, the major...Ch. 13 - (Chemical Connections 13A ) As stated in the...Ch. 13 - Prob. 44PCh. 13 - Prob. 45PCh. 13 - Prob. 46PCh. 13 - Prob. 47PCh. 13 - (Chemical Connections 13D ) Show that enflurane...Ch. 13 - Prob. 49PCh. 13 - 14-60 Write a balanced equation for the complete...Ch. 13 - 14-61 Knowing what you do about electronegativity,...Ch. 13 - 14-62 Draw structural formulas and write IUPAC...Ch. 13 - Prob. 53PCh. 13 - 14-64 Explain why the boiling point of ethylene...Ch. 13 - Prob. 55PCh. 13 - 14-66 1,4-Butanediol, hexane, and 1-pentanol have...Ch. 13 - 14-67 Of the three compounds given in Problem...Ch. 13 - Prob. 58PCh. 13 - 14-69 Show how to prepare each compound from...Ch. 13 - 14-70 Show how to prepare each compound from...Ch. 13 - 14-71 The mechanism of the acid-catalyzed...Ch. 13 - Prob. 62PCh. 13 - 14-73 Lipoic acid is a growth factor for many...Ch. 13 - 14-74 Following is a structural formula for the...Ch. 13 - Prob. 65PCh. 13 - Prob. 66PCh. 13 - Prob. 67PCh. 13 - 14-78 Consider alkenes A, B, and C. each of which...Ch. 13 - Prob. 69P
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- Don't used Ai solutionarrow_forward4.3 Explain the following terms: 4.3.1 Normal boiling point. 4.3.2 Cooling curve. 4.3.3 Congruent melting. 4.3.4 Ideal solution. 4.3.5 Phase diagram of a pure substance.arrow_forwardFor CO, an electronic transition occurs at 2x1015 Hz. If the dipole moment of the transition is of the order of 1 Debye, calculate:a) The Einstein coefficient of stimulated emissionb) The lifetime of the excited statec) The natural width (in Hz)Data: epsilon 0 = 8.85419x10-12 C2m-1J-1; 1 D = 3.33564x10-30 C m;arrow_forward
- A radiation of intensity l0 = 2.5x1010 photos s-1 cm2 affects a dispersion and produces a transmittance of 0.1122. How much incident radiation is absorbed by the music screen?arrow_forwardIf a radiation intensity l0 = 2.5x1010 fotones s-1 cm2 causes a dissolución and an absorbance of 0.95 will be recorded. How much incident radiation is absorbed by the music screen?arrow_forwardFrom the causes of the detection of a spectral band of a spectrum obtained by a signal in the gaseous phase that is indicated, you can avoid or minimize those that have their origin in:a) the Doppler effectb) collisionsc) the life time of the excited statearrow_forward
- a) Why is it possible that all types of atoms occupy the fundamental energy level?b) What should be the value of the participation function so that it occurs?c) keep in mind that the translational levels of a system are very close, which must be the condition that tenga lugar el condensado de átomos en el fundamental level?arrow_forwardAt the polar moment of Rnm transition, you can confirm thata) nunca can be ser 0b) is a very important magnitude in Raman spectroscopyc) is related to the probability of spectroscopic transactionsd) is related to the selection rulesarrow_forwardIn Fourier transformed spectroscopya) use a very sensitive monocromador systemb) the detection time is inferior to conventional spectroscopiac) the signal is detected depending on the frequencyd) occurs simultaneously at all frequency intervalsarrow_forward
- If a radiation intensity l0 = 2.5x1010 fotones s-1cm2 results in a dissolución, an absorption of 0.95 will be recorded. What is the percentage of incident radiation and transmission?a) 88.88% b) 5% c) 11.22% d) 95%arrow_forwardIndicate the spectroscopic transmission that requires greater energy radiation. Justification:a) NMR b) vibration c) electronica d) rotationarrow_forwardAfter an induced absorption process of an intensity, there are (without population inversion) transitions between:a) vibrational and rotational levels in the infrared region, we obtainb) vibrational levels exclusively in the infrared regionc) vibrational and rotational levels in the microwave regiond) transitions between nuclear spin levels in the radio frequency regionarrow_forward
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