Organic Chemistry - Standalone book
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 13, Problem 36P
Interpretation Introduction

Interpretation:

The reasonable structures for the two compounds formed in the reaction of 1, 2, 3, 4, 5-pentafluoro-6-nitrobenzene with sodium methoxide are to be suggested.

Concept introduction:

Aryl halides (halogens attached to the benzene ring) generally do not undergo nucleophilic aromatic substitution reaction, until and unless there are strong deactivating groups present either ortho and para to the halogen in the ring.

Nitro group (-NO2) is a strong deactivating group, and it helps in the nucleophilic substitution of the halogens from the benzene ring.

In nucleophilic aromatic substitutions, the most common aryl halides are those that have o- or p-nitro substituents.

Nucleophilic aromatic substitution reactions follow the second order rate law in which the rate of the reaction depends on the concentration of aryl halide and the nucleophile.

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Chapter 13 Solutions

Organic Chemistry - Standalone book

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