The suitable sequence for each of the given synthetic transformations is to be suggested. Concept introduction: The electron withdrawing groups deactivates the aromatic ring and gives substitution at the meta position. The electron donating groups activate the aromatic ring and give substitution at ortho-para position. Para substitution is preferred in case of steric hindrance. The alkyl benzene on reaction with strong oxidizing agent potassium permanganate gives benzoic acid. In Clemmensen reduction, the carbonyl group ( aldehyde or ketone ) is converted to methylene and the reagent used is zinc-mercury amalgam in concentrated hydrochloric acid, Zn(Hg)/HCl . In the presence of Lewis acid and an alkyl halide , the substitution of the alkyl group to the aromatic ring is nothing but the Friedel–Crafts alkylation reaction. The Friedel–Crafts acylation is the substitution of acyl group (carbonyl group) to the aromatic ring with an acyl halide in presence of Lewis acid. The nitration of arenes carried out by using fuming nitric acid in the presence of concentrated sulfuric acid.

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 13, Problem 54P

Interpretation Introduction

Interpretation:

The suitable sequence for each of the given synthetic transformations is to be suggested.

Concept introduction:

The electron withdrawing groups deactivates the aromatic ring and gives substitution at the meta position.

The electron donating groups activate the aromatic ring and give substitution at ortho-para position. Para substitution is preferred in case of steric hindrance.

The alkyl benzene on reaction with strong oxidizing agent potassium permanganate gives benzoic acid.

In Clemmensen reduction, the carbonyl group (aldehyde or ketone) is converted to methylene and the reagent used is zinc-mercury amalgam in concentrated hydrochloric acid, Zn(Hg)/HCl.

In the presence of Lewis acid and an alkyl halide, the substitution of the alkyl group to the aromatic ring is nothing but the Friedel–Crafts alkylation reaction.

The Friedel–Crafts acylation is the substitution of acyl group (carbonyl group) to the aromatic ring with an acyl halide in presence of Lewis acid.

The nitration of arenes carried out by using fuming nitric acid in the presence of concentrated sulfuric acid.

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C 5 4 3 CI 2 the Righ B A 5 4 3 The Lich. OH 10 4 5 3 1 LOOP- -147.52 T 77.17 -45.36 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 ppm B -126.25 77.03 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 ppm 200 190 180 170 160 150 140 130 120 110 100 90 80 TO LL <-50.00 70 60 50 40 30 20 10 ppm 45.06 30.18 -26.45 22.36 --0.00 45.07 7.5 1.93 2.05 -30.24 -22.36 C A 7 8 5 ° 4 3 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 ppm 9 8 5 4 3 ཡི་ OH 10 2 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 5 4 3 2 that th 7 I 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 115 2.21 4.00 1.0 ppm 6.96 2.76 5.01 1.0 ppm 6.30 1.00

Curved arrows were used to generate the significant resonance structure and labeled the most significant contribute. What are the errors in these resonance mechanisms. Draw out the correct resonance mechanisms with an brief explanation.

What are the: нсе * Moles of Hice while given: a) 10.0 ml 2.7M ? 6) 10.ome 12M ?

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 13, Problem 54P

Interpretation Introduction

Interpretation:

The suitable sequence for each of the given synthetic transformations is to be suggested.

Concept introduction:

The electron withdrawing groups deactivates the aromatic ring and gives substitution at the meta position.

The electron donating groups activate the aromatic ring and give substitution at ortho-para position. Para substitution is preferred in case of steric hindrance.

The alkyl benzene on reaction with strong oxidizing agent potassium permanganate gives benzoic acid.

In Clemmensen reduction, the carbonyl group (aldehyde or ketone) is converted to methylene and the reagent used is zinc-mercury amalgam in concentrated hydrochloric acid, Zn(Hg)/HCl.

In the presence of Lewis acid and an alkyl halide, the substitution of the alkyl group to the aromatic ring is nothing but the Friedel–Crafts alkylation reaction.

The Friedel–Crafts acylation is the substitution of acyl group (carbonyl group) to the aromatic ring with an acyl halide in presence of Lewis acid.

The nitration of arenes carried out by using fuming nitric acid in the presence of concentrated sulfuric acid.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 13, Problem 54P

Interpretation Introduction

Interpretation:

The suitable sequence for each of the given synthetic transformations is to be suggested.

Concept introduction:

The electron withdrawing groups deactivates the aromatic ring and gives substitution at the meta position.

The electron donating groups activate the aromatic ring and give substitution at ortho-para position. Para substitution is preferred in case of steric hindrance.

The alkyl benzene on reaction with strong oxidizing agent potassium permanganate gives benzoic acid.

In Clemmensen reduction, the carbonyl group (aldehyde or ketone) is converted to methylene and the reagent used is zinc-mercury amalgam in concentrated hydrochloric acid, Zn(Hg)/HCl.

In the presence of Lewis acid and an alkyl halide, the substitution of the alkyl group to the aromatic ring is nothing but the Friedel–Crafts alkylation reaction.

The Friedel–Crafts acylation is the substitution of acyl group (carbonyl group) to the aromatic ring with an acyl halide in presence of Lewis acid.

The nitration of arenes carried out by using fuming nitric acid in the presence of concentrated sulfuric acid.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 13, Problem 54P

Interpretation Introduction