The reasonable mechanism for the formation of each isomer is to be suggested excluding stereochemistry with the assumption that H 3 O + is a proton donor. Concept introduction: In Friedel-Crafts acylation, acyl halides are used to yield aryl ketones. In the intra-molecular Friedel -Craft acylation, the nucleophile, and electrophile are on the same molecule resulting in the formation of a ring. The electrophile in Friedel-Crafts acylation is the acyl cation or acylium cation. The acyl cation is generated by treating an acyl chloride with aluminum chloride. Acyl cations do not undergo any re-arrangement.

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 13, Problem 59P

Interpretation Introduction

Interpretation:

The reasonable mechanism for the formation of each isomer is to be suggested excluding stereochemistry with the assumption that H3O+ is a proton donor.

Concept introduction:

In Friedel-Crafts acylation, acyl halides are used to yield aryl ketones.

In the intra-molecular Friedel -Craft acylation, the nucleophile, and electrophile are on the same molecule resulting in the formation of a ring.

The electrophile in Friedel-Crafts acylation is the acyl cation or acylium cation. The acyl cation is generated by treating an acyl chloride with aluminum chloride. Acyl cations do not undergo any re-arrangement.

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 13, Problem 59P

Interpretation Introduction

Interpretation:

The reasonable mechanism for the formation of each isomer is to be suggested excluding stereochemistry with the assumption that H3O+ is a proton donor.

Concept introduction:

In Friedel-Crafts acylation, acyl halides are used to yield aryl ketones.

In the intra-molecular Friedel -Craft acylation, the nucleophile, and electrophile are on the same molecule resulting in the formation of a ring.

The electrophile in Friedel-Crafts acylation is the acyl cation or acylium cation. The acyl cation is generated by treating an acyl chloride with aluminum chloride. Acyl cations do not undergo any re-arrangement.

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Answer 3

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 13, Problem 59P

Interpretation Introduction

Interpretation:

The reasonable mechanism for the formation of each isomer is to be suggested excluding stereochemistry with the assumption that H3O+ is a proton donor.

Concept introduction:

In Friedel-Crafts acylation, acyl halides are used to yield aryl ketones.

In the intra-molecular Friedel -Craft acylation, the nucleophile, and electrophile are on the same molecule resulting in the formation of a ring.

The electrophile in Friedel-Crafts acylation is the acyl cation or acylium cation. The acyl cation is generated by treating an acyl chloride with aluminum chloride. Acyl cations do not undergo any re-arrangement.

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Answer 4

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 13, Problem 59P

Interpretation Introduction