The reasonable mechanism for the formation of each isomer is to be suggested excluding stereochemistry with the assumption that H 3 O + is a proton donor. Concept introduction: In Friedel-Crafts acylation, acyl halides are used to yield aryl ketones. In the intra-molecular Friedel -Craft acylation, the nucleophile, and electrophile are on the same molecule resulting in the formation of a ring. The electrophile in Friedel-Crafts acylation is the acyl cation or acylium cation. The acyl cation is generated by treating an acyl chloride with aluminum chloride. Acyl cations do not undergo any re-arrangement.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 13, Problem 59P

Interpretation Introduction

Interpretation:

The reasonable mechanism for the formation of each isomer is to be suggested excluding stereochemistry with the assumption that H3O+ is a proton donor.

Concept introduction:

In Friedel-Crafts acylation, acyl halides are used to yield aryl ketones.

In the intra-molecular Friedel -Craft acylation, the nucleophile, and electrophile are on the same molecule resulting in the formation of a ring.

The electrophile in Friedel-Crafts acylation is the acyl cation or acylium cation. The acyl cation is generated by treating an acyl chloride with aluminum chloride. Acyl cations do not undergo any re-arrangement.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Reaction Fill-ins Part 2! Predict the product(s) OR starting material of the following reactions. Remember, Hydride shifts are possible if/when a more stable carbocation can exist (depending on reaction mechanism)! Put your answers in the indicated boxes d. d. ง HCI

A cylinder contains 12 L of water vapour at 150˚C and 5 atm. The temperature of the water vapour is raised to 175˚C, and the volume of the cylinder is reduced to 8.5 L. What is the final pressure of the gas in atmospheres? assume that the gas is ideal

On the next page is an LC separation of the parabens found in baby wash. Parabens are suspected in a link to breast cancer therefore an accurate way to quantitate them is desired. a. In the chromatogram, estimate k' for ethyl paraben. Clearly indicate what values you used for all the terms in your calculation. b. Is this a "good" value for a capacity factor? Explain. c. What is the resolution between n-Propyl paraben and n-Butyl paraben? Again, indicate clearly what values you used in your calculation. MAU | Methyl paraben 40 20 0 -2 Ethyl paraben n-Propyl paraben n-Butyl paraben App ID 22925 6 8 min

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 13, Problem 59P

Interpretation Introduction

Interpretation:

The reasonable mechanism for the formation of each isomer is to be suggested excluding stereochemistry with the assumption that H3O+ is a proton donor.

Concept introduction:

In Friedel-Crafts acylation, acyl halides are used to yield aryl ketones.

In the intra-molecular Friedel -Craft acylation, the nucleophile, and electrophile are on the same molecule resulting in the formation of a ring.

The electrophile in Friedel-Crafts acylation is the acyl cation or acylium cation. The acyl cation is generated by treating an acyl chloride with aluminum chloride. Acyl cations do not undergo any re-arrangement.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 13, Problem 59P

Interpretation Introduction

Interpretation:

The reasonable mechanism for the formation of each isomer is to be suggested excluding stereochemistry with the assumption that H3O+ is a proton donor.

Concept introduction:

In Friedel-Crafts acylation, acyl halides are used to yield aryl ketones.

In the intra-molecular Friedel -Craft acylation, the nucleophile, and electrophile are on the same molecule resulting in the formation of a ring.

The electrophile in Friedel-Crafts acylation is the acyl cation or acylium cation. The acyl cation is generated by treating an acyl chloride with aluminum chloride. Acyl cations do not undergo any re-arrangement.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 13, Problem 59P

Interpretation Introduction