Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 13, Problem 20PS
The Henry’s law constant for O2 in water at 25 ° is given in Table 13.2. Which of the following is a reasonable constant when the temperature is 50 °C? Explain the reason for your choice.
- (a) 6.7 × 10−4 mol/kg · bar
- (b) 2.6 × 10−3 mol/kg · bar
- (c) 1.3 × 10−3 mol/kg · bar
- (d) 6.4 × 10−3 mol/kg · bar
TABLE 13.2
Henry’s Law Constants for Gases in Water (25 °C)*
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
Phosphorus pentachloride reacts violently with water togive a mixture of phosphoric acid and hydrochloric acid.(a) Write a balanced chemical equation for this reaction.(b) Determine the concentration (in moles per liter) of each of the acids that result from the complete reaction of 1.22 L of phosphorus pentachloride (measured at 215°C and 0.962 atm pressure) with enough water to give a solution volume of 697 mL.
The Henry's law constant for O2 is 1.3 x 10° mol · L. atm at 25°C. (a) What is the concentration of
O2 in water at 25°C if the partial pressure of O2 in the atmosphere is 0.21 atm? Express concentration:
(i) in mol/L, and (ii) in ppm (by mass). (b) How many grams of O2 is dissolved in water in a 1.0 x 10ʻ-
L capacity aquarium? (Assume density of solution is 1.0 g/mL).
6.
@
(b)
(c)
Write the equation for the dissolution of sulphur dioxide in water. For this
problem, assume that no other reaction other than dissolution takes place.
Write the expression for the Henry's Law constant (KH) for this reaction.
The average atmospheric sulphur dioxide concentration in Delhi, India is 13.4
µg/m³, which is equivalent to 5.11×10-9 atm. Calculate the concentration of
sulphur dioxide dissolved in water in equilibrium with dry Delhi air at 25°C.
Hint - you will need to look up the value of KH for sulphur dioxide.
Chapter 13 Solutions
Chemistry & Chemical Reactivity
Ch. 13.1 - (a) If you dissolve 10.0 g (about one heaping...Ch. 13.2 - Use the data in Table 13.1 to calculate the...Ch. 13.3 - Prob. 13.3CYUCh. 13.4 - Assume you dissolve 10.0 g of sucrose (C12H22O11)...Ch. 13.4 - What quantity of ethylene glycol, HOCH2CH2OH, must...Ch. 13.4 - In the northern United States, summer cottages are...Ch. 13.4 - Bradykinin is a small peptide (9 amino acids; 1060...Ch. 13.4 - An aluminum-containing compound has the empirical...Ch. 13.4 - A 1.40-g sample of polyethylene, a common plastic,...Ch. 13.4 - Calculate the freezing point of 525 g of water...
Ch. 13.5 - The blue line on the diagram illustrates the...Ch. 13.5 - How many theoretical plates are required to...Ch. 13.5 - Prob. 1.3ACPCh. 13.5 - The vapor pressure of pure heptane is 361.5 mm Hg...Ch. 13.5 - If the headspace of a soda is 25 mL and the...Ch. 13.5 - Prob. 2.2ACPCh. 13.5 - Prob. 2.3ACPCh. 13.5 - Prob. 2.4ACPCh. 13.5 - Prob. 3.1ACPCh. 13.5 - Prob. 3.2ACPCh. 13.5 - Prob. 3.3ACPCh. 13 - You dissolve 2.56 g of succinic acid, C2H4(CO2H)2,...Ch. 13 - You dissolve 45.0 g of camphor, C10H16O, in 425 mL...Ch. 13 - Prob. 3PSCh. 13 - Prob. 4PSCh. 13 - Prob. 5PSCh. 13 - Prob. 6PSCh. 13 - Prob. 7PSCh. 13 - Prob. 8PSCh. 13 - Hydrochloric acid is sold as a concentrated...Ch. 13 - Concentrated sulfuric acid has a density of 1.84...Ch. 13 - The average lithium ion concentration in seawater...Ch. 13 - Silver ion has an average concentration of 28 ppb...Ch. 13 - Which pairs of liquids will be miscible? (a) H2O...Ch. 13 - Acetone, CH3COCH3, is quite soluble in water....Ch. 13 - Prob. 15PSCh. 13 - Use the following data to calculate the enthalpy...Ch. 13 - You make a saturated solution of NaCl at 25 C. No...Ch. 13 - Some lithium chloride, LiCl, is dissolved in 100...Ch. 13 - Prob. 19PSCh. 13 - The Henrys law constant for O2 in water at 25 is...Ch. 13 - An unopened soda can has an aqueous CO2...Ch. 13 - Hydrogen gas has a Henrys law constant of 7.8 104...Ch. 13 - A sealed flask contains water and oxygen gas at 25...Ch. 13 - Butane, C4H10, has been suggested as the...Ch. 13 - A 35.0-g sample of ethylene glycol, HOCH2CH2OH, is...Ch. 13 - Urea, (NH2)2CO, which is widely used in...Ch. 13 - Pure ethylene glycol, HOCH2CH2OH, is added 2.00 kg...Ch. 13 - Pure iodine (105 g) is dissolved in 325 g of CCl4...Ch. 13 - Prob. 29PSCh. 13 - What is the boiling point of a solution composed...Ch. 13 - Prob. 31PSCh. 13 - Prob. 32PSCh. 13 - Prob. 33PSCh. 13 - Some ethylene glycol, HOCH2CH2OH, is added to your...Ch. 13 - You dissolve 15.0 g of sucrose, C12H22O11, in a...Ch. 13 - A typical bottle of wine consists of an 11%...Ch. 13 - Prob. 37PSCh. 13 - Estimate the osmotic pressure of human blood at 37...Ch. 13 - An aqueous solution containing 1.00 g of bovine...Ch. 13 - Calculate the osmotic pressure of a 0.0120 M...Ch. 13 - You add 0.255 g of an orange, crystalline compound...Ch. 13 - Butylated hydroxyanisole (BHA) is used in...Ch. 13 - Benzyl acetate is one of the active components of...Ch. 13 - Anthracene, a hydrocarbon obtained from coal, has...Ch. 13 - An aqueous solution contains 0.180 g of an...Ch. 13 - Aluminon, an organic compound, is used as a...Ch. 13 - Prob. 47PSCh. 13 - To make homemade ice cream, you cool the milk and...Ch. 13 - List the following aqueous solutions in order of...Ch. 13 - Arrange the following aqueous solutions in order...Ch. 13 - When solutions of BaCl2 and Na2SO4 are mixed, the...Ch. 13 - The dispersed phase of a certain colloidal...Ch. 13 - Phenylcarbinol is used in nasal sprays as a...Ch. 13 - (a) Which aqueous solution is expected to have the...Ch. 13 - Arrange the following aqueous solutions in order...Ch. 13 - Prob. 56GQCh. 13 - Dimethylglyoxime [DMG, (CH3CNOH)2] is used as a...Ch. 13 - A 10.7 m solution of NaOH has a density of 1.33...Ch. 13 - Concentrated aqueous ammonia has a molarity of...Ch. 13 - Prob. 60GQCh. 13 - If you want a solution that is 0.100 m in ions,...Ch. 13 - Consider the following aqueous solutions: (i) 0.20...Ch. 13 - (a) Which solution is expected to have the higher...Ch. 13 - The solubility of NaCl in water at 100 C is 39.1...Ch. 13 - Instead of using NaCl to melt the ice on your...Ch. 13 - The smell of ripe raspberries is due to...Ch. 13 - Hexachlorophene has been used in germicidal soap....Ch. 13 - The solubility of ammonium formate, NH4CHO2, in...Ch. 13 - How much N2 can dissolve in water at 25 C if the...Ch. 13 - Cigars are best stored in a humidor at 18 C and...Ch. 13 - An aqueous solution containing 10.0 g of starch...Ch. 13 - Prob. 72GQCh. 13 - Calculate the enthalpies of solution for Li2SO4...Ch. 13 - Water at 25 C has a density of 0.997 g/cm3....Ch. 13 - If a volatile solute is added to a volatile...Ch. 13 - A solution is made by adding 50.0 mL of ethanol...Ch. 13 - A 2.0% (by mass) aqueous solution of novocainium...Ch. 13 - A solution is 4.00% (by mass) maltose and 96.00%...Ch. 13 - The following table lists the concentrations of...Ch. 13 - A tree is 10.0 m tall. (a) What must be the total...Ch. 13 - Prob. 81GQCh. 13 - A compound is known to be a potassium halide, KX....Ch. 13 - Prob. 85GQCh. 13 - If one is very careful, it is possible to float a...Ch. 13 - A solution of benzoic acid in benzene has a...Ch. 13 - You dissolve 5.0 mg of iodine, I2, in 25 mL of...Ch. 13 - Prob. 89ILCh. 13 - In a police forensics lab, you examine a package...Ch. 13 - An organic compound contains carbon (71.17%),...Ch. 13 - Prob. 92ILCh. 13 - When sails of Mg2+, Ca2+, and Be2+ are placed in...Ch. 13 - Explain why a cucumber shrivels up when it is...Ch. 13 - Prob. 95SCQCh. 13 - A 100.-gram sample of sodium chloride (NaCl) is...Ch. 13 - Prob. 97SCQCh. 13 - Prob. 98SCQCh. 13 - Starch contains CC, CH, CO, and OH bonds....Ch. 13 - Prob. 100SCQCh. 13 - You have two aqueous solutions separated by a...Ch. 13 - Prob. 102SCQCh. 13 - Sodium chloride (NaCl) is commonly used to melt...Ch. 13 - Prob. 105SCQCh. 13 - Prob. 106SCQCh. 13 - Prob. 107SCQ
Additional Science Textbook Solutions
Find more solutions based on key concepts
For each of the following 2-dimensional shapes, determine the highest order rotation axis of symmetry.
Inorganic Chemistry
22.102 Write the structures of the cis and tram isomers, if any, for the following compounds:
Chemistry: The Molecular Nature of Matter
Real walls are never totally adiabatic. Use your experience to order the following walls in increasing order wi...
Thermodynamics, Statistical Thermodynamics, & Kinetics
The smallest building blocks inside your cell phone are about 1000 times smaller than the diameter of a human h...
Chemistry In Context
Q1. What is the empirical formula of a compound with the molecular formula
Chemistry: A Molecular Approach (4th Edition)
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- A 0.109 mol/kg aqueous solution of formic acid, HCOOH, freezes at −0.210 °C. Calculate the percent dissociation of formic acid.arrow_forward6-113 List the following aqueous solutions in order of decreasing freezing point: 0.040 M glycerin (C3H8O3) 0.025 M NaBr, and 0.015 M AI(NO3)3 Assume complete dissociation of any salts.arrow_forwardThe freezing point of a 0.21 m aqueous solution of H2SO4 is -0.796C. (a) What is i? (b) Is the solution made up primarily of (i) H2SO4 molecules only? (ii) H+ and HSO4- ions? (iii) 2H+ and 1SO42- ions?arrow_forward
- 6-111 As noted in Section 6-8C, the amount of external pressure that must be applied to a more concentrated solution to stop the passage of solvent molecules across a semipermeable membrane is known as the osmotic pressure The osmotic pressure obeys a law similar in form to the ideal gas law (discussed in Section 5-4), where Substituting for pressure and solving for osmotic pressures gives the following equation: RT MRT, where M is the concentration or molarity of the solution. (a) Determine the osmotic pressure at 25°C of a 0.0020 M sucrose (C12H22O11) solution. (b) Seawater contains 3.4 g of salts for every liter of solution. Assuming the solute consists entirely of NaCl (and complete dissociation of the NaCI salt), calculate the osmotic pressure of seawater at 25°C. (c) The average osmotic pressure of blood is 7.7 atm at 25°C. What concentration of glucose (C6H12O6) will be isotonic with blood? (d) Lysozyme is an enzyme that breaks bacterial cell walls. A solution containing 0.150 g of this enzyme in 210. mL of solution has an osmotic pressure of 0.953 torr at 25°C. What is the molar mass of lysozyme? (e) The osmotic pressure of an aqueous solution of a certain protein was measured in order to determine the protein's molar mass. The solution contained 3.50 mg of protein dissolved in sufficient water to form 5.00 mL of solution. The osmotic pressure of the solution at 25°C was found to be 1.54 torr. Calculate the molar mass of the protein.arrow_forward6-66 What gives nanotubes their unique optical and electrical properties?arrow_forwardWill red blood cells crenate, hemolyze, or remain unaffected when placed in each of the solutions in Problem 8-107?arrow_forward
- Concentrated hydrochloric acid contains 1.00 mol HCl dissolved in 3.31 mol H2O. What is the mole fraction of HCl in concentrated hydrochloric acid? What is the molal concentration of HCl?arrow_forwardSolutions of hydrogen in palladium may be formed by exposing Pd metal to H₂ gas. The concentration of hydrogen in the palladium depends on the pressure of H₂ gas applied, but in a more complex fashion than can be described by Henry's law. Under certain conditions, 0.78 g of hydrogen gas is dissolved in 224 g of palladium metal. (The density of the resulting solution is 11.7 g/cm³.) (a) Determine the molarity of this solution. M 4.0 (b) Determine the molality of this solution. m 4.0 (c) Determine the percent by mass of hydrogen in this solution. % 4.0arrow_forward(a) What is the charge density of an ion, and what two prop-erties of an ion affect it?(b) Arrange the following in order of increasing charge density:(c) How do the two properties in part (a) affect the ionic heat of hydration, ΔH(hydr)?arrow_forward
- (a) What is the molality of a solution made by dissolving 10 moles of hydrogen peroxide, H₂O₂, in 10 kg of water? (b) How much sodium aluminum hydride (NaAIH₂), in grams, is needed to be dissolved to make a 1.5 L solution of 0.25 M aqueous NaAlH, solution? The molar mass of NaAIH, is 54.003 g/mol. (c) How much sodium oxalate (Na2C2O4), in moles, is needed to be dissolved in 5 L of water to make a 2.0 M aqueous Na2C2O4 solution?arrow_forwardArrange the following compounds in order of increasing vapor pressure. NH PH C А Вarrow_forwardWhat is the boiling point of a 1.8 m Ca(NO3)2 solution?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Introduction to General, Organic and Biochemistry
Chemistry
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY