Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337399074
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
bartleby

Concept explainers

bartleby

Videos

Question
Book Icon
Chapter 13.5, Problem 2.4ACP
Interpretation Introduction

Interpretation: It should be determined that what mass of dissolved CO2 which is released to the atmosphere in order to reach equilibrium.

Concept introduction:

  • Henry’s law: The solubility of a gas in liquid is directly proportional to the gas pressure.

    Sg= kHPg,where,Sgisthegassolubility(inmol/kg)kHis Henry's constant Pg is the partial pressure of the gaseous solute.

  • Density=MassVolume

Expert Solution & Answer
Check Mark

Answer to Problem 2.4ACP

6.0gCO2 will be released to the atmosphere in order to reach equilibrium.

Explanation of Solution

Given,partialpressureofCO2=4barHenry'sconstant=0.034mol/kg.barAccordingtoHenry'slaw, Sg=kHPgsolubilityofCO2beforeopening=0.034mol/kg.bar×4bar =0.136mol/kg

Assume that, the density of the solution is 1.0g/cm3. Therefore 1.0L corresponds to 1kg. The amount of CO2 dissolved is 0.136mol.

Solubility of CO2after opening can be calculated as follows:

partialpressureofCO2=3.7×10-4barHenry'sconstant=0.034mol/kg.bar

According to Henry’s law:

Sg =kHPg

Substituting the given values in the above equation, the solubility can be calculated.

Sg=0.034mol/kg.bar×3.7×10-4bar=1.26×10-5mol/kg SolubilityofCO2afteropening=1.26×10-5mol/Kg.TheamountofCO2in1.0kgis1.26×10-5mol.

MassofCO2released=(AmountofCO2presentbeforeopeningsoda-AmountofCO2presentafteropeningsoda)×MolarmassofCO2 =(0.136molCO2-1.26×10-5molCO2)×44.01g/molCO2 =6.0gCO2

Conclusion

6.0gCO2 would be released to the atmosphere in order to reach equilibrium.

Want to see more full solutions like this?

Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!
Students have asked these similar questions
If the concentration of CO2 in the atmosphere were to reach 600 ppm what would be the concentration of CO2 in water at 25°C that is in equilibrium with that air. Put your answer in mg/L. The Henry's Law Constant for CO; is 3.38 x 102 mol/L-atm and the partial pressure of water at 25°C is 0.0313 atm. If the equilibrium concentration of CO, in water was to reach 0.89 mg/I., what would the resulting pH be? The equilibrium constant (K1) for the reaction of CO2 in water is 4.45 x 10
Consider the graph below that displays the solubility of KCI in water as a function of temperature. 50 g of KCI is mixed with 100 g of water at 25 °C and is then heated to 50 °C. Select which statement best describes what would be observed as the system proceeds to establish equilibrium. 100 Solubility (g per 100 g H₂O) 80 60 40 20 0 20 KCI 40 60 Temperature (°C) 80 100 O a. A homogeneous solution of hydrated ions is initially observed, when a further 10 g of KCI is added, some of the added KCI is observed to dissolve, but some of the additional KCI remains in solid form. O b. A heterogenous system involving an equilibrium between hydrated KCI ions and solid KCI is observed. O c. A homogeneous solution of hydrated ions is initially observed, when a further 1 g of KCI is added, this additional KCI is also observed to dissolve. O d. A homogeneous solution of hydrated ions is observed before spontaneous crystallisation of KCl occurs when the solution is poured onto a crystal of KCI.
2. Using the data given below, calculate the percentage of KHP in the impure sample. The molar mass of KHP is 204.219 g/mol. Molarity of NaOH Solution: Mass of Unknown: Volume of Water Used to Dissolve Unknown: Volume of NaOH Used to Reach Equivalence Point: Percent of KHP: 0.1955 M 1.1801 g 30.00 mL 17.01 mL % Stolal Vol)

Chapter 13 Solutions

Chemistry & Chemical Reactivity

Ch. 13.5 - The blue line on the diagram illustrates the...Ch. 13.5 - How many theoretical plates are required to...Ch. 13.5 - Prob. 1.3ACPCh. 13.5 - The vapor pressure of pure heptane is 361.5 mm Hg...Ch. 13.5 - If the headspace of a soda is 25 mL and the...Ch. 13.5 - Prob. 2.2ACPCh. 13.5 - Prob. 2.3ACPCh. 13.5 - Prob. 2.4ACPCh. 13.5 - Prob. 3.1ACPCh. 13.5 - Prob. 3.2ACPCh. 13.5 - Prob. 3.3ACPCh. 13 - You dissolve 2.56 g of succinic acid, C2H4(CO2H)2,...Ch. 13 - You dissolve 45.0 g of camphor, C10H16O, in 425 mL...Ch. 13 - Prob. 3PSCh. 13 - Prob. 4PSCh. 13 - Prob. 5PSCh. 13 - Prob. 6PSCh. 13 - Prob. 7PSCh. 13 - Prob. 8PSCh. 13 - Hydrochloric acid is sold as a concentrated...Ch. 13 - Concentrated sulfuric acid has a density of 1.84...Ch. 13 - The average lithium ion concentration in seawater...Ch. 13 - Silver ion has an average concentration of 28 ppb...Ch. 13 - Which pairs of liquids will be miscible? (a) H2O...Ch. 13 - Acetone, CH3COCH3, is quite soluble in water....Ch. 13 - Prob. 15PSCh. 13 - Use the following data to calculate the enthalpy...Ch. 13 - You make a saturated solution of NaCl at 25 C. No...Ch. 13 - Some lithium chloride, LiCl, is dissolved in 100...Ch. 13 - Prob. 19PSCh. 13 - The Henrys law constant for O2 in water at 25 is...Ch. 13 - An unopened soda can has an aqueous CO2...Ch. 13 - Hydrogen gas has a Henrys law constant of 7.8 104...Ch. 13 - A sealed flask contains water and oxygen gas at 25...Ch. 13 - Butane, C4H10, has been suggested as the...Ch. 13 - A 35.0-g sample of ethylene glycol, HOCH2CH2OH, is...Ch. 13 - Urea, (NH2)2CO, which is widely used in...Ch. 13 - Pure ethylene glycol, HOCH2CH2OH, is added 2.00 kg...Ch. 13 - Pure iodine (105 g) is dissolved in 325 g of CCl4...Ch. 13 - Prob. 29PSCh. 13 - What is the boiling point of a solution composed...Ch. 13 - Prob. 31PSCh. 13 - Prob. 32PSCh. 13 - Prob. 33PSCh. 13 - Some ethylene glycol, HOCH2CH2OH, is added to your...Ch. 13 - You dissolve 15.0 g of sucrose, C12H22O11, in a...Ch. 13 - A typical bottle of wine consists of an 11%...Ch. 13 - Prob. 37PSCh. 13 - Estimate the osmotic pressure of human blood at 37...Ch. 13 - An aqueous solution containing 1.00 g of bovine...Ch. 13 - Calculate the osmotic pressure of a 0.0120 M...Ch. 13 - You add 0.255 g of an orange, crystalline compound...Ch. 13 - Butylated hydroxyanisole (BHA) is used in...Ch. 13 - Benzyl acetate is one of the active components of...Ch. 13 - Anthracene, a hydrocarbon obtained from coal, has...Ch. 13 - An aqueous solution contains 0.180 g of an...Ch. 13 - Aluminon, an organic compound, is used as a...Ch. 13 - Prob. 47PSCh. 13 - To make homemade ice cream, you cool the milk and...Ch. 13 - List the following aqueous solutions in order of...Ch. 13 - Arrange the following aqueous solutions in order...Ch. 13 - When solutions of BaCl2 and Na2SO4 are mixed, the...Ch. 13 - The dispersed phase of a certain colloidal...Ch. 13 - Phenylcarbinol is used in nasal sprays as a...Ch. 13 - (a) Which aqueous solution is expected to have the...Ch. 13 - Arrange the following aqueous solutions in order...Ch. 13 - Prob. 56GQCh. 13 - Dimethylglyoxime [DMG, (CH3CNOH)2] is used as a...Ch. 13 - A 10.7 m solution of NaOH has a density of 1.33...Ch. 13 - Concentrated aqueous ammonia has a molarity of...Ch. 13 - Prob. 60GQCh. 13 - If you want a solution that is 0.100 m in ions,...Ch. 13 - Consider the following aqueous solutions: (i) 0.20...Ch. 13 - (a) Which solution is expected to have the higher...Ch. 13 - The solubility of NaCl in water at 100 C is 39.1...Ch. 13 - Instead of using NaCl to melt the ice on your...Ch. 13 - The smell of ripe raspberries is due to...Ch. 13 - Hexachlorophene has been used in germicidal soap....Ch. 13 - The solubility of ammonium formate, NH4CHO2, in...Ch. 13 - How much N2 can dissolve in water at 25 C if the...Ch. 13 - Cigars are best stored in a humidor at 18 C and...Ch. 13 - An aqueous solution containing 10.0 g of starch...Ch. 13 - Prob. 72GQCh. 13 - Calculate the enthalpies of solution for Li2SO4...Ch. 13 - Water at 25 C has a density of 0.997 g/cm3....Ch. 13 - If a volatile solute is added to a volatile...Ch. 13 - A solution is made by adding 50.0 mL of ethanol...Ch. 13 - A 2.0% (by mass) aqueous solution of novocainium...Ch. 13 - A solution is 4.00% (by mass) maltose and 96.00%...Ch. 13 - The following table lists the concentrations of...Ch. 13 - A tree is 10.0 m tall. (a) What must be the total...Ch. 13 - Prob. 81GQCh. 13 - A compound is known to be a potassium halide, KX....Ch. 13 - Prob. 85GQCh. 13 - If one is very careful, it is possible to float a...Ch. 13 - A solution of benzoic acid in benzene has a...Ch. 13 - You dissolve 5.0 mg of iodine, I2, in 25 mL of...Ch. 13 - Prob. 89ILCh. 13 - In a police forensics lab, you examine a package...Ch. 13 - An organic compound contains carbon (71.17%),...Ch. 13 - Prob. 92ILCh. 13 - When sails of Mg2+, Ca2+, and Be2+ are placed in...Ch. 13 - Explain why a cucumber shrivels up when it is...Ch. 13 - Prob. 95SCQCh. 13 - A 100.-gram sample of sodium chloride (NaCl) is...Ch. 13 - Prob. 97SCQCh. 13 - Prob. 98SCQCh. 13 - Starch contains CC, CH, CO, and OH bonds....Ch. 13 - Prob. 100SCQCh. 13 - You have two aqueous solutions separated by a...Ch. 13 - Prob. 102SCQCh. 13 - Sodium chloride (NaCl) is commonly used to melt...Ch. 13 - Prob. 105SCQCh. 13 - Prob. 106SCQCh. 13 - Prob. 107SCQ
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Text book image
Living By Chemistry: First Edition Textbook
Chemistry
ISBN:9781559539418
Author:Angelica Stacy
Publisher:MAC HIGHER
Text book image
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Text book image
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Text book image
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Text book image
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY