CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
8th Edition
ISBN: 9780135204634
Author: Robinson
Publisher: PEARSON
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Chapter 13, Problem 13.151MP
Combustion analysis of a 36.72-mg sample of the male hormone testosterone gave 106.43 mg CO2 and 32.10 mg H20 as the only combustion products. When 5.00 mg of testosterone was dissolved in 15.0 ml. of a suitable solvent at 25 °C, an osmotic pressure of 21.5 mm Hg was measured. What is the molecular formula of testosterone?
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LTS
Solid:
AT=Te-Ti
Trial 1
Trial 2
Trial 3
Average
ΔΗ
Mass water, g
24.096
23.976
23.975
Moles of solid, mol
0.01763
001767
0101781
Temp. change, °C
2.9°C
11700
2.0°C
Heat of reaction, J
-292.37J -170.473
-193.26J
AH, kJ/mole
16.58K 9.647 kJ 10.85 kr
16.58K59.64701
KJ
mol
12.35k
Minimum AS,
J/mol K
41.582
mol-k
Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn &
Show your calculations for:
AH in J and then in kJ/mole for Trial 1:
qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J
qsin =
qrxn =
292.35 292.37J
AH in J = 292.375 0.2923kJ
0.01763m01
=1.65×107
AH in kJ/mol =
=
16.58K
0.01763mol
mol
qrx
Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con
Kelvin.)
AS=AHIT
(1.65×10(9.64×103) + (1.0
Jimai
For the compound: C8H17NO2
Use the following information to come up with a plausible structure:
8
This compound has "carboxylic acid amide" and ether functional groups.
The peaks at 1.2ppm are two signals that are overlapping one another.
One of the two signals is a doublet that represents 6 hydrogens; the
other signal is a quartet that represents 3 hydrogens.
Vnk the elements or compounds in the table below in decreasing order of their boiling points. That is, choose 1 next to the substance with the highest bolling
point, choose 2 next to the substance with the next highest boiling point, and so on.
substance
C
D
chemical symbol,
chemical formula
or Lewis structure.
CH,-N-CH,
CH,
H
H 10: H
C-C-H
H H H
Cale
H 10:
H-C-C-N-CH,
Bri
CH,
boiling point
(C)
Сен
(C) B
(Choose
Chapter 13 Solutions
CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
Ch. 13 - Prob. 13.1PCh. 13 - Prob. 13.2ACh. 13 - Prob. 13.3PCh. 13 - Prob. 13.4ACh. 13 - PRACTICE 12.5 A 50.0 mL sample of drinking water...Ch. 13 - APPLY 12.6 The legal limit for human exposure to...Ch. 13 - PRACTICE 12.7 What mass in grams of a 0.500 m...Ch. 13 - APPLY 12.8 What is the molality of a solution...Ch. 13 - PRACTICE 12.9 The density at 20°C of a 0.500 M...Ch. 13 - APPLY 12.10 The density at 20°C of a 0.258 m...
Ch. 13 - ThesolubilityofCO2inwateris 3.2102 M at 25 °C...Ch. 13 - APPLY 12.12 Use the Henry’s law constant you...Ch. 13 - PRACTICE 12.13 What is the vapor pressure in mm Hg...Ch. 13 - APPLY 12.14 A solution made by dissolving 8.110 g...Ch. 13 - PRACTICE 12.17 What is the vapor pressure of the...Ch. 13 - Conceptual APPLY 12.18 The following diagram shows...Ch. 13 - What is the normal boiling point in °C of an...Ch. 13 - APPLY 12.20 The following phase diagram shows a...Ch. 13 - Prob. 13.19PCh. 13 - APPLY 12.22 Cells in the human eye have an osmotic...Ch. 13 - PRACTICE 12.23 A solution prepared by dissolving...Ch. 13 - Prob. 13.22ACh. 13 - PROBLEM 12.25 What is the difference between a...Ch. 13 - PROBLEM 12.26 Urea has a high solubility in blood...Ch. 13 - Use Table 13.5 to calculate the osmotic pressure...Ch. 13 - Prob. 13.26PCh. 13 - Many people take vitamin supplements to promote...Ch. 13 - Prob. 13.28CPCh. 13 - Prob. 13.29CPCh. 13 - Prob. 13.30CPCh. 13 - Prob. 13.31CPCh. 13 - Prob. 13.32CPCh. 13 - Prob. 13.33CPCh. 13 - Prob. 13.34CPCh. 13 - Prob. 13.35CPCh. 13 - Prob. 13.36SPCh. 13 - 12.41 Why do ionic substances with higher lattice...Ch. 13 - Prob. 13.38SPCh. 13 - Prob. 13.39SPCh. 13 - Classify the strongest type of intermolecular...Ch. 13 - Classify the strongest type of intermolecular...Ch. 13 - Prob. 13.42SPCh. 13 - Prob. 13.43SPCh. 13 - Br2 is much more soluble in tetrachloromethane,...Ch. 13 - Predict whether the solubility of formaldehyde,...Ch. 13 - Prob. 13.46SPCh. 13 - Prob. 13.47SPCh. 13 - Arrange the following compounds in order of their...Ch. 13 - Prob. 13.49SPCh. 13 - Prob. 13.50SPCh. 13 - Prob. 13.51SPCh. 13 - Prob. 13.52SPCh. 13 - Prob. 13.53SPCh. 13 - The dissolution of CaCl2(s) in water is...Ch. 13 - The dissolution of NH4ClO4(s) in water is...Ch. 13 - Assuming that seawater is an aqueous solution of...Ch. 13 - Prob. 13.57SPCh. 13 - Propranolol°C16H21NO2) a so-called beta-blocker...Ch. 13 - Prob. 13.59SPCh. 13 - How would you prepare each of the following...Ch. 13 - Prob. 13.61SPCh. 13 - Prob. 13.62SPCh. 13 - Prob. 13.63SPCh. 13 - Prob. 13.64SPCh. 13 - Which of the following solutions has the higher...Ch. 13 - What is the mass percent concentration of the...Ch. 13 - Prob. 13.67SPCh. 13 - Prob. 13.68SPCh. 13 - Prob. 13.69SPCh. 13 - What is the concentration of each of the following...Ch. 13 - Prob. 13.71SPCh. 13 - The density of a 16.0 mass % solution of sulfuric...Ch. 13 - Prob. 13.73SPCh. 13 - What is the molality of the 40.0 mass % ethylene...Ch. 13 - Prob. 13.75SPCh. 13 - Prob. 13.76SPCh. 13 - Prob. 13.77SPCh. 13 - Prob. 13.78SPCh. 13 - Prob. 13.79SPCh. 13 - Look at the solubility graph in Figure 13.7, and...Ch. 13 - Prob. 13.81SPCh. 13 - Prob. 13.82SPCh. 13 - Prob. 13.83SPCh. 13 - Fish generally need an O2 concentration in water...Ch. 13 - At an altitude of 10, 000 ft, the partial pressure...Ch. 13 - Prob. 13.86SPCh. 13 - Prob. 13.87SPCh. 13 - Prob. 13.88SPCh. 13 - When solid CaCl2 is added to liquid water, the...Ch. 13 - Rank the following aqueous solutions from lowest...Ch. 13 - Which of the following aqueous solutions has the...Ch. 13 - What is the vapor pressure in mm Hg of a solution...Ch. 13 - What is the normal boiling point in oC of a...Ch. 13 - What is the freezing point in °C of a solution...Ch. 13 - Assuming complete dissociation, what is the...Ch. 13 - When 9.12 g of HCI was dissolved in 190 g of...Ch. 13 - Prob. 13.97SPCh. 13 - When 1 mol of NaCI is added to 1 L of water, the...Ch. 13 - Prob. 13.99SPCh. 13 - Draw a phase diagram showing how the phase...Ch. 13 - Prob. 13.101SPCh. 13 - What is the vapor pressure in mm Hg of the...Ch. 13 - What is the vapor pressure in mm Hg of a solution...Ch. 13 - What is the boiling point in oC of each of the...Ch. 13 - What is the freezing point in oC of each of the...Ch. 13 - Prob. 13.106SPCh. 13 - The van’t Hoff factor for KCl is i=1.85. What is...Ch. 13 - Hepatane (C7H16) and octane (C8H18) are...Ch. 13 - Prob. 13.109SPCh. 13 - Acetone, C3H6O , and ethyl acetate, C4H8O2, are...Ch. 13 - Prob. 13.111SPCh. 13 - Prob. 13.112SPCh. 13 - What is the mole fraction of each component in the...Ch. 13 - Prob. 13.114SPCh. 13 - A solution prepared by dissolving 3.00 g of...Ch. 13 - Prob. 13.116SPCh. 13 - Prob. 13.117SPCh. 13 - Prob. 13.118SPCh. 13 - What osmotic presure in mm Hg would you expect for...Ch. 13 - Prob. 13.120SPCh. 13 - Prob. 13.121SPCh. 13 - Prob. 13.122SPCh. 13 - If cost per gram were not a concern, which of the...Ch. 13 - Prob. 13.124SPCh. 13 - Met-enkephalin is one of the so-called endorphins,...Ch. 13 - Prob. 13.126SPCh. 13 - Prob. 13.127SPCh. 13 - Prob. 13.128SPCh. 13 - Prob. 13.129SPCh. 13 - How many grams of naphthalene, C10H8 (commonly...Ch. 13 - Prob. 13.131SPCh. 13 - Assuming that seawater is a 3.5 mass % solution of...Ch. 13 - There’s actually much more in seawater than just...Ch. 13 - Prob. 13.134SPCh. 13 - What is the van’t Hoff factor for K2SO4 in an...Ch. 13 - If the van’t Hoff factor for Lid in a 0.62 m...Ch. 13 - What is the value of the van’t Hoff factor for KCI...Ch. 13 - A solid mixture of KCI, KNO3, and Ba(N03)2 is...Ch. 13 - Prob. 13.139SPCh. 13 - An aqueous solution of a certain organic compound...Ch. 13 - Prob. 13.141SPCh. 13 - Prob. 13.142SPCh. 13 - A solution of 0.250 g of naphthalene (mothballs)...Ch. 13 - Prob. 13.144SPCh. 13 - Prob. 13.145SPCh. 13 - The steroid hormone estradiol contains only C, H,...Ch. 13 - Many acids are partially dissociated into ions in...Ch. 13 - Addition of 50.00 mL of 2.238 H2SO4 (solution...Ch. 13 - Prob. 13.149MPCh. 13 - Prob. 13.150MPCh. 13 - Combustion analysis of a 36.72-mg sample of the...Ch. 13 - Prob. 13.152MPCh. 13 - Prob. 13.153MPCh. 13 - Prob. 13.154MP
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY