Introductory Chemistry: A Foundation
8th Edition
ISBN: 9781285199030
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 12.5, Problem 1CT
ns have different radii than their parent atoms. What if ions stayed the same size as their parent atoms? How would this affect the structure of ionic compounds?
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You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products:
xi
1. ☑
2. H₂O
хе
i
Draw the missing reagent X you think will make this synthesis work in the drawing area below.
If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank.
Click and drag to start drawing a
structure.
There is no reagent that will make this synthesis work without complications.
: ☐
S
☐
Predict the major products of this organic reaction:
H
OH
1. LiAlH4
2. H₂O
?
Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry.
Click and drag to start drawing a
structure.
G
C
टे
For each reaction below, decide if the first stable organic product that forms in solution will create a new C-C bond, and check the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first
stable product you expect to form in solution.
NH2
CI
MgCl
?
Will the first product that forms in this reaction
create a new CC bond?
Yes
No
MgBr
?
Will the first product that forms in this reaction
create a new CC bond?
Yes
No
G
टे
Chapter 12 Solutions
Introductory Chemistry: A Foundation
Ch. 12.2 - use differences in electronegativity to account...Ch. 12.2 - trong>Exercise 12.1 For each of the following...Ch. 12.5 - ns have different radii than their parent atoms....Ch. 12.6 - trong>Exercise 12.2 Write the Lewis structure for...Ch. 12.7 - trong>Exercise 12.3 Ozone is a very important...Ch. 12.7 - trong>Exercise 12.4 Write the Lewis structures...Ch. 12.9 - u have seen that molecules with four electron...Ch. 12.9 - Prob. 12.5SCCh. 12 - sing only the periodic table, predict the most...Ch. 12 - rite the proper charges so that an alkali metal, a...
Ch. 12 - hat is meant by a chemical bond?Ch. 12 - hy do atoms form bonds with one another? What can...Ch. 12 - ow does a bond between Naand Cldiffer from a bond...Ch. 12 - n your own words, what is meant by the term...Ch. 12 - xplain the difference between ionic bonding and...Ch. 12 - rue or false? In general, a larger atom has a...Ch. 12 - hy is there an octet rule (and what does actet...Ch. 12 - Does a Lewis structure tell which electrons came...Ch. 12 - If lithium and fluorine react, which has more...Ch. 12 - In a bond between fluorine and iodine, which has...Ch. 12 - We use differences in electronegative to account...Ch. 12 - Prob. 14ALQCh. 12 - Why do we only the consider the valence electrons...Ch. 12 - How do we determine the total number of valence...Ch. 12 - What is the main idea in the valence shell...Ch. 12 - The molecules NH3andBF3have the same general...Ch. 12 - How do we deal with multiple bonds in VSEPR...Ch. 12 - In Section 12.10 of your text, the term “effective...Ch. 12 - Prob. 21ALQCh. 12 - Prob. 22ALQCh. 12 - Prob. 1QAPCh. 12 - Prob. 2QAPCh. 12 - hat sorts of elements react to form ionic...Ch. 12 - n general terms, what is a covalent bond?Ch. 12 - escribe the type of bonding that exists in the...Ch. 12 - Prob. 6QAPCh. 12 - he relative ability of an atom in a molecule to...Ch. 12 - hat does it mean to say that a bond is polar? Give...Ch. 12 - Prob. 9QAPCh. 12 - What factor determines the relative level of...Ch. 12 - In each of the following groups, which element is...Ch. 12 - In each of the following groups. which element is...Ch. 12 - On the basis. of the electronegativity values...Ch. 12 - On the basis of the electronegativity values given...Ch. 12 - Which of the following molecules contain polar...Ch. 12 - Which of the following molecules contain polar...Ch. 12 - On the basis of the electronegativity values given...Ch. 12 - On the basis of the electronegativity values given...Ch. 12 - Which brand in each of the following pairs has the...Ch. 12 - Which hand in each of the following pairs has less...Ch. 12 - What is a dipole moment? Give four examples of...Ch. 12 - Why is the presence of a dipole moment in the...Ch. 12 - In each of the following diatomic molecules, which...Ch. 12 - In each of the following diatomic molecules. which...Ch. 12 - For each of the following bonds, draw a figure...Ch. 12 - For each of the following bonds, draw a figure...Ch. 12 - For each of the following bonds, draw a figure...Ch. 12 - For each of the following bonds, draw a figure...Ch. 12 - What does it mean when we say that in forming...Ch. 12 - Prob. 30QAPCh. 12 - Nonmetals form negative ions by (losing/gaining)...Ch. 12 - Explain how the atoms in covalent molecules...Ch. 12 - Which simple ion would each of the following...Ch. 12 - Which simple ion would each of the following...Ch. 12 - For each of the following numbers of electrons,...Ch. 12 - Give the formula of a negative ion that would have...Ch. 12 - On the basis of their electron configurations,...Ch. 12 - On the basis of their electron configurations,...Ch. 12 - Name the noble gas atom that has the same electron...Ch. 12 - Atoms form ions so as to achieve electron...Ch. 12 - Prob. 41QAPCh. 12 - Describe in general terms the structure of ionic...Ch. 12 - Why are cations always smaller than the atoms from...Ch. 12 - Why are anions always larger than the atoms from...Ch. 12 - For each of the following pairs, indicate which...Ch. 12 - Prob. 46QAPCh. 12 - Prob. 47QAPCh. 12 - For each of the following pairs, indicate which is...Ch. 12 - Why are the valence electrons of an atom the only...Ch. 12 - Explain what the “duet" and “octet” rules are and...Ch. 12 - What type of structure must each atom in a...Ch. 12 - When elements in the second and third periods...Ch. 12 - How many electrons are involved when two atoms in...Ch. 12 - Prob. 54QAPCh. 12 - Write the simple Lewis structure for each of the...Ch. 12 - Write the simple Lewis structure for each of the...Ch. 12 - Give the total number of valence electrons in each...Ch. 12 - Give the total number of valence electrons in each...Ch. 12 - Write a Lewis structure for each of the following...Ch. 12 - Write a Lewis structure for each of the following...Ch. 12 - Write a Lewis structure for each of the following...Ch. 12 - Prob. 62QAPCh. 12 - The “Chemistry in Focus“ segment Broccoli—Miracle...Ch. 12 - The “Chemistry in Focus" segment Hiding Carbon...Ch. 12 - Write a Lewis structure for each of the following...Ch. 12 - Write a Lewis structure for each of the following...Ch. 12 - Write a Lewis structure for each of the following...Ch. 12 - Write a Lewis structure for each of the following...Ch. 12 - What is the geometric structure of the water...Ch. 12 - What is the geometric sanctum of the ammonia...Ch. 12 - What is the geometric structure of the boron...Ch. 12 - What is the geometric structure of the...Ch. 12 - Why is the geometric structure of a molecule...Ch. 12 - Prob. 74QAPCh. 12 - How is the structure around a given atom related...Ch. 12 - Why are all diatomic molecules linear, regardless...Ch. 12 - Although the valence electron pairs in ammonia...Ch. 12 - Although both the BF3and NF3molecules contain the...Ch. 12 - For the indicated atom in each of the following...Ch. 12 - Prob. 80QAPCh. 12 - Using the VSEPR theory, predict the molecular...Ch. 12 - Prob. 82QAPCh. 12 - Using the VSEPR theory, predict the molecular...Ch. 12 - Using the VSEPR theory, predict the molecular...Ch. 12 - For each of the following molecules or ions,...Ch. 12 - For each of the following molecules or ion....Ch. 12 - The “Chemistry in Focus" segment Taste—It's the...Ch. 12 - Prob. 88QAPCh. 12 - What is resonance? Give three examples of...Ch. 12 - Prob. 90APCh. 12 - The geometric arrangement of electron pairs around...Ch. 12 - Choose the bond that is the least polar. Explain...Ch. 12 - Prob. 93APCh. 12 - Prob. 94APCh. 12 - Prob. 95APCh. 12 - For each of the following pairs of elements,...Ch. 12 - On the basis of the electronegativity values given...Ch. 12 - Which of the following molecules contain polar...Ch. 12 - Prob. 99APCh. 12 - Prob. 100APCh. 12 - or each of the following bonds, draw a figure...Ch. 12 - Prob. 102APCh. 12 - Prob. 103APCh. 12 - Prob. 104APCh. 12 - hich noble gas has the same electron configuration...Ch. 12 - Prob. 106APCh. 12 - rite the Lewis structure for each of the following...Ch. 12 - Prob. 108APCh. 12 - rite a Lewis structure for each of the following...Ch. 12 - Prob. 110APCh. 12 - rite a Lewis structure for each of the following...Ch. 12 - Prob. 112APCh. 12 - hy is the molecular structure of H2Ononlinear,...Ch. 12 - Prob. 114APCh. 12 - sing the VSEPR theory, predict the molecular...Ch. 12 - Prob. 116APCh. 12 - or each of the following molecules, indicate the...Ch. 12 - Prob. 118APCh. 12 - Prob. 119APCh. 12 - Prob. 120APCh. 12 - Prob. 121APCh. 12 - Classify the bonding in each of the following...Ch. 12 - ompare the electronegativities of each pair of...Ch. 12 - Prob. 124CPCh. 12 - rrange the atoms and/or ions in the following...Ch. 12 - Prob. 126CPCh. 12 - Prob. 127CPCh. 12 - he formulas of several chemical substances are...Ch. 12 - Prob. 1CRCh. 12 - hat does temperature measure? Are the molecules in...Ch. 12 - Prob. 3CRCh. 12 - Prob. 4CRCh. 12 - Prob. 5CRCh. 12 - hat is the enthalpy change for a process? Is...Ch. 12 - Prob. 7CRCh. 12 - Prob. 8CRCh. 12 - Prob. 9CRCh. 12 - What is a driving force? Name two common and...Ch. 12 - Prob. 11CRCh. 12 - Methane, CH4, is the major component of natural...Ch. 12 - What is electronegative radiation? Give some...Ch. 12 - Prob. 14CRCh. 12 - Do atoms in excited states emit radiation...Ch. 12 - Prob. 16CRCh. 12 - Schrodinger and de Broglie suggested a...Ch. 12 - Describe the general characteristics of the first...Ch. 12 - Prob. 19CRCh. 12 - Describe the sublevels and orbitals that...Ch. 12 - Describe electron spin. How does electron spin...Ch. 12 - Prob. 22CRCh. 12 - List the order in which the orbitals are filled as...Ch. 12 - Prob. 24CRCh. 12 - Prob. 25CRCh. 12 - Prob. 26CRCh. 12 - What are the representative elements? In what...Ch. 12 - Prob. 28CRCh. 12 - Prob. 29CRCh. 12 - Prob. 30CRCh. 12 - Prob. 31CRCh. 12 - Prob. 32CRCh. 12 - Prob. 33CRCh. 12 - Prob. 34CRCh. 12 - Give evidence that ionic bonds are very strong....Ch. 12 - Prob. 36CRCh. 12 - Prob. 37CRCh. 12 - For three simple molecules of your own choice,...Ch. 12 - Prob. 39CRCh. 12 - Prob. 40CRCh. 12 - Prob. 41CRCh. 12 - Prob. 42CRCh. 12 - Prob. 43CRCh. 12 - Prob. 44CRCh. 12 - Prob. 45CRCh. 12 - Prob. 46CR
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- For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. དྲ。 ✗MgBr ? O CI Will the first product that forms in this reaction create a new C-C bond? Yes No • ? Will the first product that forms in this reaction create a new CC bond? Yes No × : ☐ Xarrow_forwardPredict the major products of this organic reaction: OH NaBH4 H ? CH3OH Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. ☐ : Sarrow_forwardPredict the major products of this organic reaction: 1. LIAIHA 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. X : ☐arrow_forward
- For each reaction below, decide if the first stable organic product that forms in solution will create a new C - C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 tu ? ? OH Will the first product that forms in this reaction create a new CC bond? Yes No Will the first product that forms in this reaction create a new CC bond? Yes No C $ ©arrow_forwardAs the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C-C bond as its major product: 1. MgCl ? 2. H₂O* If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. This reaction will not make a product with a new CC bond. G marrow_forwardIncluding activity coefficients, find [Hg22+] in saturated Hg2Br2 in 0.00100 M NH4 Ksp Hg2Br2 = 5.6×10-23.arrow_forward
- give example for the following(by equation) a. Converting a water insoluble compound to a soluble one. b. Diazotization reaction form diazonium salt c. coupling reaction of a diazonium salt d. indacator properties of MO e. Diazotization ( diazonium salt of bromobenzene)arrow_forward2-Propanone and ethyllithium are mixed and subsequently acid hydrolyzed. Draw and name the structures of the products.arrow_forward(Methanesulfinyl)methane is reacted with NaH, and then with acetophenone. Draw and name the structures of the products.arrow_forward
- 3-Oxo-butanenitrile and (E)-2-butenal are mixed with sodium ethoxide in ethanol. Draw and name the structures of the products.arrow_forwardWhat is the reason of the following(use equations if possible) a.) In MO preperation through diazotization: Addition of sodium nitrite in acidfied solution in order to form diazonium salt b.) in MO experiment: addition of sodium hydroxide solution in the last step to isolate the product MO. What is the color of MO at low pH c.) In MO experiment: addition of sodium hydroxide solution in the last step to isolate the product MO. What is the color of MO at pH 4.5 d.) Avoiding not cooling down the reaction mixture when preparing the diazonium salt e.) Cbvcarrow_forwardA 0.552-g sample of an unknown acid was dissolved in water to a total volume of 20.0 mL. This sample was titrated with 0.1103 M KOH. The equivalence point occurred at 29.42 mL base added. The pH of the solution at 10.0 mL base added was 3.72. Determine the molar mass of the acid. Determine the Ka of the acid.arrow_forward
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