
EBK FOUNDATIONS OF COLLEGE CHEMISTRY
15th Edition
ISBN: 9781118930144
Author: Willard
Publisher: JOHN WILEY+SONS INC.
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Chapter 12, Problem 98CE
Interpretation Introduction
Interpretation:
Final pressure of in cylinder if temperature rises from
Concept Introduction:
Gay-lussac’s law represents direct relation of pressure of fixed mass of ideal gas with its temperature at fixed volume.
Mathematically relation for Gay-lussac’s law is as follows:
Or,
Here,
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NH3 decomposes through an equilibrium reaction between NH3, H2, and N2. Only one of the options is correct:(A). The mechanism of the NH3 decomposition reaction must necessarily involve the collision of two NH3 molecules to induce a rearrangement of the atoms in this molecule.(B). The molecular weight of the NH3 decomposition reaction is 2 since two NH3 molecules must collide.(C). The rate of the NH3 decomposition reaction must be greater than that of NH3 synthesis, since the former requires two molecules to collide and the latter, four.(D). The NH3 decomposition reaction cannot occur in a single step.
Given the equilibrium A2 + B2 ⇌ 2 AB where k1 is the rate coefficient of the forward reaction and k-1 is the rate coefficient of the reverse reaction, with the forward reaction being first-order in A2 and B2, and the reverse reaction being second-order in AB. Equilibrium will be reached later if the relative values of the constants are:(A) k1 high and k-1 high(B) k1 high and k-1 low(C) k1 low and k-1 high(D) k1 low and k-1 low
A 2-step reaction has the following mechanism:
|
1. (fast) R2
R+R
2. (slow) R+Q
K₂ P
k_1
What series does it have?
(A). v=
-
= (k + k1 − k-1)[R2][Q]
(B). v=-k₁[R₂] + k₁[R]² - k₂[R][Q]
(C). v=k₂[R]²[Q]²
(D). v = k[R₂]1/2[Q]
Chapter 12 Solutions
EBK FOUNDATIONS OF COLLEGE CHEMISTRY
Ch. 12.1 - Prob. 12.1PCh. 12.2 - Prob. 12.2PCh. 12.3 - Prob. 12.3PCh. 12.5 - Prob. 12.4PCh. 12.5 - Prob. 12.5PCh. 12.5 - Prob. 12.6PCh. 12.6 - Prob. 12.7PCh. 12.6 - Prob. 12.8PCh. 12.7 - Prob. 12.9PCh. 12.8 - Prob. 12.10P
Ch. 12.8 - Prob. 12.11PCh. 12.9 - Prob. 12.12PCh. 12.9 - Prob. 12.13PCh. 12 - Prob. 1RQCh. 12 - Prob. 2RQCh. 12 - Prob. 3RQCh. 12 - Prob. 4RQCh. 12 - Prob. 5RQCh. 12 - Prob. 6RQCh. 12 - Prob. 7RQCh. 12 - Prob. 8RQCh. 12 - Prob. 9RQCh. 12 - Prob. 10RQCh. 12 - Prob. 11RQCh. 12 - Prob. 12RQCh. 12 - Prob. 13RQCh. 12 - Prob. 14RQCh. 12 - Prob. 15RQCh. 12 - Prob. 16RQCh. 12 - Prob. 17RQCh. 12 - Prob. 18RQCh. 12 - Prob. 19RQCh. 12 - Prob. 20RQCh. 12 - Prob. 21RQCh. 12 - Prob. 22RQCh. 12 - Prob. 23RQCh. 12 - Prob. 24RQCh. 12 - Prob. 25RQCh. 12 - Prob. 26RQCh. 12 - Prob. 1PECh. 12 - Prob. 2PECh. 12 - Prob. 3PECh. 12 - Prob. 4PECh. 12 - Prob. 5PECh. 12 - Prob. 6PECh. 12 - Prob. 7PECh. 12 - Prob. 8PECh. 12 - Prob. 9PECh. 12 - Prob. 10PECh. 12 - Prob. 11PECh. 12 - Prob. 12PECh. 12 - Prob. 13PECh. 12 - Prob. 14PECh. 12 - Prob. 15PECh. 12 - Prob. 16PECh. 12 - Prob. 17PECh. 12 - Prob. 18PECh. 12 - Prob. 19PECh. 12 - Prob. 20PECh. 12 - Prob. 21PECh. 12 - Prob. 22PECh. 12 - Prob. 23PECh. 12 - Prob. 24PECh. 12 - Prob. 25PECh. 12 - Prob. 26PECh. 12 - Prob. 27PECh. 12 - Prob. 28PECh. 12 - Prob. 29PECh. 12 - Prob. 30PECh. 12 - Prob. 31PECh. 12 - Prob. 32PECh. 12 - Prob. 33PECh. 12 - Prob. 34PECh. 12 - Prob. 35PECh. 12 - Prob. 36PECh. 12 - Prob. 37PECh. 12 - Prob. 38PECh. 12 - Prob. 39PECh. 12 - Prob. 40PECh. 12 - Prob. 41PECh. 12 - Prob. 42PECh. 12 - Prob. 43PECh. 12 - Prob. 44PECh. 12 - Prob. 45PECh. 12 - Prob. 46PECh. 12 - Prob. 47PECh. 12 - Prob. 48PECh. 12 - Prob. 49PECh. 12 - Prob. 50PECh. 12 - Prob. 51PECh. 12 - Prob. 52PECh. 12 - Prob. 53PECh. 12 - Prob. 54PECh. 12 - Prob. 55AECh. 12 - Prob. 56AECh. 12 - Prob. 57AECh. 12 - Prob. 58AECh. 12 - Prob. 59AECh. 12 - Prob. 60AECh. 12 - Prob. 61AECh. 12 - Prob. 62AECh. 12 - Prob. 63AECh. 12 - Prob. 64AECh. 12 - Prob. 65AECh. 12 - Prob. 66AECh. 12 - Prob. 67AECh. 12 - Prob. 68AECh. 12 - Prob. 69AECh. 12 - Prob. 70AECh. 12 - Prob. 71AECh. 12 - Prob. 72AECh. 12 - Prob. 73AECh. 12 - Prob. 74AECh. 12 - Prob. 75AECh. 12 - Prob. 76AECh. 12 - Prob. 77AECh. 12 - Prob. 78AECh. 12 - Prob. 79AECh. 12 - Prob. 80AECh. 12 - Prob. 81AECh. 12 - Prob. 82AECh. 12 - Prob. 83AECh. 12 - Prob. 84AECh. 12 - Prob. 85AECh. 12 - Prob. 86AECh. 12 - Prob. 87AECh. 12 - Prob. 88AECh. 12 - Prob. 89AECh. 12 - Prob. 90AECh. 12 - Prob. 91AECh. 12 - Prob. 92AECh. 12 - Prob. 93AECh. 12 - Prob. 94CECh. 12 - Prob. 95CECh. 12 - Prob. 96CECh. 12 - Prob. 97CECh. 12 - Prob. 98CECh. 12 - Prob. 99CECh. 12 - Prob. 100CECh. 12 - Prob. 101CE
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