Bundle: Chemistry: An Atoms First Approach, Loose-leaf Version, 2nd + OWLv2 with Student Solutions Manual, 4 terms (24 months) Printed Access Card
2nd Edition
ISBN: 9781337086431
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Textbook Question
Chapter 12, Problem 68E
Hydrogen for use in ammonia production is produced by the reaction
What will happen to a reaction mixture at equilibrium if
a. H2O(g) is removed?
b. the temperature is increased (the reaction is endothermic)?
c. an inert gas is added to a rigid reaction container?
d. CO(g) is removed?
e. the volume of the container is tripled?
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The table includes macrostates characterized by 4 energy levels (&) that are
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b) Calculate the macrostate that is most likely to exist. For this macrostate,
show that the population of the levels is consistent with the Boltzmann
distribution.
macrostate 1 macrostate 2 macrostate 3
ε/k (K) Populations
Populations
Populations
300
5
3
4
200
7
9
8
100
15
17
16
0
33
31
32
DATO: k = 1,38×10-23 J K-1
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In an experiment, the viscosity of water was measured at different
temperatures and the table was constructed from the data obtained.
a) Calculate the activation energy of viscous flow (kJ/mol).
b) Calculate the viscosity at 30°C.
T/°C
0
20
40
60
80
η/cpoise 1,972 1,005 0,656 0,469 0,356
Chapter 12 Solutions
Bundle: Chemistry: An Atoms First Approach, Loose-leaf Version, 2nd + OWLv2 with Student Solutions Manual, 4 terms (24 months) Printed Access Card
Ch. 12 - Characterize a system at chemical equilibrium with...Ch. 12 - What is the law of mass action? Is it true that...Ch. 12 - Prob. 3RQCh. 12 - Prob. 4RQCh. 12 - Prob. 5RQCh. 12 - Distinguish between the terms equilibrium constant...Ch. 12 - Summarize the steps for solving equilibrium...Ch. 12 - Prob. 8RQCh. 12 - What is Le Chteliers principle? Consider the...Ch. 12 - Prob. 10RQ
Ch. 12 - Consider an equilibrium mixture of four chemicals...Ch. 12 - The boxes shown below represent a set of initial...Ch. 12 - For the reactionH2(g)+I2(g)2HI(g), consider two...Ch. 12 - Prob. 4ALQCh. 12 - Consider the reaction A(g)+2B(g)C(g)+D(g) in a...Ch. 12 - Consider the reactionA(g)+B(g)C(g)+D(g). A friend...Ch. 12 - Prob. 7ALQCh. 12 - Prob. 8ALQCh. 12 - Prob. 9ALQCh. 12 - Prob. 10QCh. 12 - Consider the following reaction:...Ch. 12 - Prob. 12QCh. 12 - Suppose a reaction has the equilibrium constant K...Ch. 12 - Prob. 14QCh. 12 - Consider the following reaction at some...Ch. 12 - Prob. 16QCh. 12 - Prob. 17QCh. 12 - Prob. 18QCh. 12 - For a typical equilibrium problem, the value of K...Ch. 12 - Prob. 20QCh. 12 - Write the equilibrium expression (K) for each of...Ch. 12 - Write the equilibrium expression (Kp) for each...Ch. 12 - Prob. 23ECh. 12 - For the reaction H2(g)+Br2(g)2HBr(g) Kp = 3.5 104...Ch. 12 - Prob. 25ECh. 12 - At high temperatures, elemental nitrogen and...Ch. 12 - At a particular temperature, a 3.0-L flask...Ch. 12 - At a particular temperature a 2.00-L flask at...Ch. 12 - Prob. 29ECh. 12 - Prob. 30ECh. 12 - Prob. 31ECh. 12 - Prob. 32ECh. 12 - Prob. 33ECh. 12 - Write expressions for Kp for the following...Ch. 12 - Prob. 35ECh. 12 - Prob. 36ECh. 12 - Prob. 37ECh. 12 - In a study of the reaction...Ch. 12 - The equilibrium constant is 0.0900 at 25C for the...Ch. 12 - The equilibrium constant is 0.0900 at 25C for the...Ch. 12 - At 900c, Kp = 1.04 for the reaction...Ch. 12 - Ethyl acetate is synthesized in a nonreacting...Ch. 12 - For the reaction 2H2O(g)2H2(g)+O2(g) K = 2.4 103...Ch. 12 - The reaction 2NO(g)+Br2(g)2NOBr(g) has Kp = 109 at...Ch. 12 - A 1.00-L flask was filled with 2.00 moles of...Ch. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Prob. 48ECh. 12 - Prob. 49ECh. 12 - Nitrogen gas (N2) reacts with hydrogen gas (H2) to...Ch. 12 - Prob. 51ECh. 12 - Prob. 52ECh. 12 - Prob. 53ECh. 12 - At 25c, K = 0.090 for the reaction...Ch. 12 - Prob. 55ECh. 12 - Prob. 56ECh. 12 - Prob. 57ECh. 12 - At o particular temperature, K = 4 .0 107 for the...Ch. 12 - Prob. 59ECh. 12 - Lexan is a plastic used to make compact discs,...Ch. 12 - At 25C, Kp. = 2.9 103 for the reaction...Ch. 12 - A sample of solid ammonium chloride was placed in...Ch. 12 - Prob. 63ECh. 12 - Predict the shift in the equilibrium position that...Ch. 12 - An important reaction in the commercial production...Ch. 12 - What will happen to the number of moles of SO3 in...Ch. 12 - Prob. 67ECh. 12 - Hydrogen for use in ammonia production is produced...Ch. 12 - Old-fashioned smelling salts consist of ammonium...Ch. 12 - Ammonia is produced by the Haber process, in which...Ch. 12 - Prob. 71AECh. 12 - Given the following equilibrium constants at...Ch. 12 - Consider the decomposition of the compound C5H6O3...Ch. 12 - Prob. 74AECh. 12 - The gas arsine, AsH3, decomposes as follows:...Ch. 12 - At a certain temperature, K = 9.1 10-4 for the...Ch. 12 - At a certain temperature, K = 1.1 l03 for the...Ch. 12 - Prob. 78AECh. 12 - At 25C, gaseous SO2Cl2 decomposes to SO2(g) and...Ch. 12 - For the following reaction at a certain...Ch. 12 - Prob. 81AECh. 12 - Consider the reaction Fe3+(aq)+SCN(aq)FeSCN2+(aq)...Ch. 12 - Chromium(VI) forms two different oxyanions, the...Ch. 12 - Prob. 84AECh. 12 - Prob. 85AECh. 12 - For the reaction below, Kp = 1.16 at 800C....Ch. 12 - Many sugars undergo a process called mutarotation,...Ch. 12 - Peptide decomposition is one of the key processes...Ch. 12 - The creation of shells by mollusk species is a...Ch. 12 - Methanol, a common laboratory solvent, poses a...Ch. 12 - Prob. 91CWPCh. 12 - Prob. 92CWPCh. 12 - Prob. 93CWPCh. 12 - Prob. 94CWPCh. 12 - Prob. 95CWPCh. 12 - Prob. 96CWPCh. 12 - Consider the following exothermic reaction at...Ch. 12 - For the following endothermic reaction at...Ch. 12 - Prob. 99CPCh. 12 - A 4.72-g sample of methanol (CH3OH) was placed in...Ch. 12 - At 35C, K = 1.6 105 for the reaction...Ch. 12 - Nitric oxide and bromine at initial partial...Ch. 12 - At 25C. Kp = 5.3 105 for the reaction...Ch. 12 - Prob. 104CPCh. 12 - The partial pressures of an equilibrium mixture of...Ch. 12 - At 125C, KP = 0.25 for the reaction...Ch. 12 - A mixture of N2, H2, and NH3 is at equilibrium...Ch. 12 - Prob. 108CPCh. 12 - Prob. 109CPCh. 12 - Prob. 110CPCh. 12 - Prob. 111CPCh. 12 - A sample of N2O4(g) is placed in an empty cylinder...Ch. 12 - A sample of gaseous nitrosyl bromide (NOBr) was...Ch. 12 - Prob. 114CPCh. 12 - For the reaction NH3(g)+H2S(g)NH4HS(s) K = 400. at...Ch. 12 - Prob. 116IPCh. 12 - In a solution with carbon tetrachloride as the...Ch. 12 - Prob. 118IPCh. 12 - A gaseous material XY(g) dissociates to some...
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