The pressure at which 95 % of the Oxygen molecules dissociate is to be calculated. Concept introduction: The equilibrium constant K describes the ratio of the reactant to the product on the equilibrium conditions in terms of molar concentration. The equilibrium constant depends upon temperature. Law of mass action is applicable on the equilibrium reactions. The Le Chatelier’s principle states that the addition of the reactants shifts the equilibrium to the right while the addition of product shifts the equilibrium to the left at constant temperature. The dissociation of the species is denotes by the symbol α . To determine: The pressure at which 95 % of the Oxygen molecules dissociate at the constant temperature.
The pressure at which 95 % of the Oxygen molecules dissociate is to be calculated. Concept introduction: The equilibrium constant K describes the ratio of the reactant to the product on the equilibrium conditions in terms of molar concentration. The equilibrium constant depends upon temperature. Law of mass action is applicable on the equilibrium reactions. The Le Chatelier’s principle states that the addition of the reactants shifts the equilibrium to the right while the addition of product shifts the equilibrium to the left at constant temperature. The dissociation of the species is denotes by the symbol α . To determine: The pressure at which 95 % of the Oxygen molecules dissociate at the constant temperature.
Solution Summary: The author explains that the equilibrium constant K describes the ratio of the reactant to the product on equilibrium conditions in terms of molar concentration.
Interpretation: The pressure at which
95% of the Oxygen molecules dissociate is to be calculated.
Concept introduction: The equilibrium constant
K describes the ratio of the reactant to the product on the equilibrium conditions in terms of molar concentration.
The equilibrium constant depends upon temperature.
Law of mass action is applicable on the equilibrium reactions.
The Le Chatelier’s principle states that the addition of the reactants shifts the equilibrium to the right while the addition of product shifts the equilibrium to the left at constant temperature.
The dissociation of the species is denotes by the symbol
α.
To determine: The pressure at which
95% of the Oxygen molecules dissociate at the constant temperature.
20.33 Think-Pair-Share
(a) Rank the following dienes and dienophiles in order of increasing reactivity in the
Diels-Alder reaction.
(i)
CO₂Et
(ii)
COEt
||
CO₂Et
MeO
MeO
(b) Draw the product that results from the most reactive diene and most reactive
dienophile shown in part (a).
(c) Draw a depiction of the orbital overlap involved in the pericyclic reaction that oc-
curs between the diene and dienophile in part (b).
(d) Is the major product formed in part (b) the endo or exo configuration? Explain
your reasoning.
20.40 The following compound undergoes an intramolecular Diels-Alder reaction to give a
tricyclic product. Propose a structural formula for the product.
CN
heat
An intramolecular
Diels-Alder adduct
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Chapter 12 Solutions
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell