![EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG](https://www.bartleby.com/isbn_cover_images/9781119659525/9781119659525_largeCoverImage.gif)
(a)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction:
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
(b)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
(c)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
(d)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
(e)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
(f)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
(g)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
(h)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
(i)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
(j)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
(k)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
(l)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
(m)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
(n)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
(o)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
(p)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
(q)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
(r)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
(s)
Interpretation:
The synthesis of the given product transformation should be identified.
Concept introduction:
Bromination:
Alcohols brominated by using Pbr3 which provides corresponding brominated products.
Chlorination:
Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.
E1 Elimination: Formation of alkene from alkyl bromide or alcohol through the formation of stable carbocation followed by elimination.
Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.
Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7 (chromic acid) which provides carboxylic acid.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Alcohols treated with any metals or base which provides alkoxide.
9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols
Reduction: Aldehydes or ketones undergoing reduction by using reducing agent like LAH or NaBH4 which provides alcohol.
Lindlar catalyst: it is a heterogeneous catalyst that consists of palladium deposited on calcium carbonate. Lindlar catalyst is used for the hydrogenation process of alkynes to alkenes.
Potassium tert-butoxide is a strong base, which used for the abstraction of acidic hydrogen from the molecule.
Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.
Kucherov Reaction:
Acetylene compounds Undergoes hydration with water which provides carbonyl compounds.
![Check Mark](/static/check-mark.png)
Want to see the full answer?
Check out a sample textbook solution![Blurred answer](/static/blurred-answer.jpg)
Chapter 12 Solutions
EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
- 2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11arrow_forwardComplete the spectroscopy with structurearrow_forwardComplete the spectroscopy with structurearrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9780078021558/9780078021558_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305079373/9781305079373_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781118431221/9781118431221_smallCoverImage.gif)