Chemistry In Focus
7th Edition
ISBN: 9781337399692
Author: Tro, Nivaldo J.
Publisher: Cengage Learning,
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Chapter 12, Problem 3SC
Interpretation Introduction
Interpretation:
The change in the composition of the mixture of pentane and decane left in an open beaker overnight is to be determined.
Concept Introduction:
The boiling point of a substance depends upon the intermolecular forces and the thermal energy of the molecules.
All atoms and molecules possess dispersion forces which depend upon their molar mass.
Polar molecules have dipole forces between them which depend upon the polarity of the molecules.
Molecules which have a lower boiling point vaporize easily and form what are known as volatile liquids.
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2. Write a complete mechanism for the reaction shown below.
NaOCH
LOCH₁
O₂N
NO2
CH₂OH, 20 °C
O₂N
NO2
4. Propose a synthesis of the target molecules from the respective starting materials.
a)
b)
LUCH
C
Br
OH
The following mechanism for the gas phase reaction of H2 and ICI that is consistent with the observed rate
law is:
step 1
step 2
slow: H2(g) +ICI(g) → HCl(g) + HI(g)
fast: ICI(g) + HI(g) → HCl(g) + |2(g)
(1) What is the equation for the overall reaction? Use the smallest integer coefficients possible. If a box is
not needed, leave it blank.
+
→
+
(2) Which species acts as a catalyst? Enter formula. If none, leave box blank:
(3) Which species acts as a reaction intermediate? Enter formula. If none, leave box blank:
(4) Complete the rate law for the overall reaction that is consistent with this mechanism.
(Use the form k[A][B]"..., where '1' is understood (so don't write it) for m, n etc.)
Rate =
Chapter 12 Solutions
Chemistry In Focus
Ch. 12 - Prob. 12.1YTCh. 12 - Which of the following molecules are polar?...Ch. 12 - Which of the following molecules do you expect to...Ch. 12 - Prob. 12.4YTCh. 12 - Prob. 12.5YTCh. 12 - Prob. 12.6YTCh. 12 - Prob. 12.7YTCh. 12 - Prob. 12.8YTCh. 12 - Prob. 12.9YTCh. 12 - Substance A is composed of molecules that have...
Ch. 12 - A representation of liquid water is shown below....Ch. 12 - Prob. 3SCCh. 12 - Prob. 4SCCh. 12 - Prob. 1ECh. 12 - Prob. 2ECh. 12 - Prob. 3ECh. 12 - Prob. 4ECh. 12 - Prob. 5ECh. 12 - Prob. 6ECh. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Prob. 10ECh. 12 - Why does sweating cool the human body?Ch. 12 - Prob. 12ECh. 12 - Prob. 13ECh. 12 - Prob. 14ECh. 12 - Explain the hydrologic cycle.Ch. 12 - Prob. 16ECh. 12 - Prob. 17ECh. 12 - How does a water softener work?Ch. 12 - Prob. 19ECh. 12 - Prob. 20ECh. 12 - Prob. 21ECh. 12 - What is the SDWA?Ch. 12 - Prob. 23ECh. 12 - Prob. 24ECh. 12 - Prob. 25ECh. 12 - Explain the concerns that groups like the EWG or...Ch. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Which compound would you expect to have the...Ch. 12 - Which compound would you expect to have the...Ch. 12 - Prob. 31ECh. 12 - Prob. 32ECh. 12 - Classify each molecule as polar or nonpolar:...Ch. 12 - Classify each molecule as polar or nonpolar:...Ch. 12 - Prob. 35ECh. 12 - Prob. 36ECh. 12 - Prob. 37ECh. 12 - Prob. 38ECh. 12 - How many grams of sucrose (C12H22O11) are present...Ch. 12 - How many grams of glucose (C6H12O6) are present in...Ch. 12 - Prob. 41ECh. 12 - How many grams of NaF are present in 4.5 L of a...Ch. 12 - A 250-g sample of hard water contains...Ch. 12 - Prob. 44ECh. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Prob. 48ECh. 12 - Prob. 49ECh. 12 - Prob. 50ECh. 12 - Prob. 51ECh. 12 - Prob. 52ECh. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - Prob. 55ECh. 12 - Prob. 56ECh. 12 - Prob. 57ECh. 12 - Prob. 58E
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