ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
12th Edition
ISBN: 9781119664635
Author: Solomons
Publisher: WILEY
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Chapter 12, Problem 34P
Synthesize the following compound using cyclopentane and ethyne (acetylene) as the sole source of carbon atoms.
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2. Provide a complete retrosynthetic analysis and a complete forward
synthetic scheme to make the following target molecule from the
given starting material. You may use any other reagents necessary.
Br
146. Use the following data for NH3(g) at 273 K to determine B2p (T) at 273 K.
P (bar)
0.10
0.20
0.30
0.40
0.50
0.60
(Z -1)/10-4
1.519
3.038
4.557
6.071
7.583
9.002
0.70
10.551
110. Compare the pressures given by (a) the ideal gas law, (b) the van der Waals equation, and
(c) the Redlic-Kwong equation for propane at 400 K and p = 10.62 mol dm³. The van der
Waals parameters for propane are a = 9.3919 dm6 bar mol-2 and b = 0.090494 dm³ mol−1.
The Redlich-Kwong parameters are A = 183.02 dm bar mol-2 and B =
0.062723 dm³ mol-1. The experimental value is 400 bar.
Chapter 12 Solutions
ORGANIC CHEMISTRY (LL) W/WILEYPLUS NEXT
Ch. 12 - Prob. 1PPCh. 12 - Prob. 2PPCh. 12 - Prob. 3PPCh. 12 - PRACTICE PROBLEM 12.4 Predict the products of the...Ch. 12 - Prob. 5PPCh. 12 - Prob. 6PPCh. 12 - Practice Problem 12.7
Provide retrosynthetic...Ch. 12 - Prob. 8PPCh. 12 - What products would you expect from the reaction...Ch. 12 - What products would you expect from the reaction...
Ch. 12 - What product (or products) would be formed from...Ch. 12 - Prob. 12PCh. 12 - 12.13 Write reaction conditions and the product...Ch. 12 - Prob. 14PCh. 12 - Predict the organic product from each of the...Ch. 12 - Predict the organic product from each of the...Ch. 12 - Predict the organic product from each of the...Ch. 12 - Predict the major organic product from each of the...Ch. 12 - Synthesize each of the following compounds from...Ch. 12 - Prob. 20PCh. 12 - 21. Write a mechanism for the following reaction....Ch. 12 - Prob. 22PCh. 12 - 23. What organic products A-H would you expect...Ch. 12 - Prob. 24PCh. 12 - Show how 1-pentanol could be transformed into each...Ch. 12 - Provide the reagents needed to accomplish...Ch. 12 - Prob. 27PCh. 12 - For each of the following alcohols, write a...Ch. 12 - Prob. 29PCh. 12 - Prob. 30PCh. 12 - Prob. 31PCh. 12 - Prob. 32PCh. 12 - Predict the major organic product from each of the...Ch. 12 - 34. Synthesize the following compound using...Ch. 12 - Prob. 35PCh. 12 - Prob. 36PCh. 12 - 37. Explain how and IR spectroscopy could be used...Ch. 12 - 38. An unknown X shows a broad absorption band in...Ch. 12 - Prob. 39PCh. 12 - The problem below is directed toward devising a...
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