What is the difference between average rate, initial rate, and instantaneous rate?
Interpretation: The difference between average rate, initial rate, and instantaneous rate is to be determined.
Concept Introduction: The average rate is the rate of reaction over a longer period of time as compared to the instantaneous rate which is the rate at a particular instant. The initial rate is the instantaneous rate of reaction when a reaction commences.
Explanation of Solution
Average rate over a specific time period is defined as the change in a concentration over that period divided by the time interval. The initial rate is the instantaneous rate of reaction when a reaction commences, just as the new product begins to get formed. The instantaneous rate is the rate of a reaction at any specific point in time, expressed as the differential of concentration with respect to time. Thus, the average rate is the rate of reaction over a longer period of time as compared to the instantaneous rate which is the rate at a particular instant.
Want to see more full solutions like this?
Chapter 12 Solutions
Chemistry by OpenStax (2015-05-04)
Additional Science Textbook Solutions
Introductory Chemistry (6th Edition)
Anatomy & Physiology (6th Edition)
Organic Chemistry (8th Edition)
Human Biology: Concepts and Current Issues (8th Edition)
College Physics: A Strategic Approach (3rd Edition)
Chemistry: Structure and Properties (2nd Edition)
- Express the rate of the reaction 2N2O(g)2N2(g)+O2(g) in terms of (b) [ N2O ] (a) [ O2 ]arrow_forwardCandle wax is a mixture of hydrocarbons. In the reaction of oxygen with candle w ax in Figure 11.2, the rate of consumption of oxygen decreased with time after the flask was covered, and eventually' the flame went out. From the perspective of the kinetic-molecular theory, describe what is happening in the flask. FIGURE 11.2 When a candle burns in a closed container, the flame will diminish and eventually go out. As the amount of oxygen present decreases, the rate of combustion will also decrease. Eventually, the rate of combustion is no longer sufficient to sustain the flame even though there is still some oxygen present in the vessel.arrow_forwardSucrose decomposes to fructose and glucose in acid solution. A plot of the concentration of sucrose as a function of time is given in the margin. What is the rate of change of the sucrose concentration over the first 2 hours? What is the rate of change over the last 2 hours? Concentration versus time for the decomposition of sucrose.arrow_forward
- The rate of the reaction HOCH2CH2NO2+2HNO2NO2CH2CH2NO2+2H2O is 0.045molHNO2/s. What are the rates of appearance and disappearance with respect to the other three substances?arrow_forwardThe type of rate law for a reaction, either the differential rate law or the integrated rate law, is usually determined by which data is easiest to collect. Explain.arrow_forwardBased on the kinetic theory of matter, what would the action of a catalyst do to a reaction that is the reverse of some reaction that we say is catalyzed?arrow_forward
- Cyclobutane can decompose to form ethylene: The cyclobutane concentration can be measured as a function of time by mass spectrometry (a graph is nearby). Write an expression for the rate of reaction in terms of a changing concentration. Calculate the average rate of reaction between 10. and 30. s. Calculate the instantaneous rate of reaction after 20. s. Calculate the initial rate of reaction. Calculate the instantaneous rate of formation of ethylene 40. s after the start of the reaction.arrow_forwardChlorine dioxide, ClO2, is a reddish-yellow gas that is soluble in water. In basic solution it gives ClO3 and ClO2 ions. 2ClO2(aq)+2OH(aq)ClO3(aq)+ClO2(aq)+H2O To obtain the rate law for this reaction, the following experiments were run and, for each, the initial rate of reaction of ClO2 was determined. Obtain the rate law and the value of the rate constant.arrow_forwardDefine these terms: (a) unimolecular reaction (b) bimolecular reaction (c) elementary reaction (d) overall reactionarrow_forward
- Based on the diagram in Exercise 12.83, which of the reactions has the fastest rate? Which has the slowest rate?arrow_forwardConsider the decomposition reaction 2X2Y+ZThe following graph shows the change in concentration with respect to time for the reaction. What does each of the curves labeled 1, 2, and 3 represent?arrow_forwardThe enzyme carbonic anhydrase catalyzes the transformation of carbon dioxide into hydrogen carbonate ions. This reaction was studied by H. DeVoe and G. B. Kistiakowsky (Journal of the American Chemical Society, Vol. 83, p. 274, 1961) and found to obey the Michaelis-Menten model. Use the data below at a given temperature to calculate the maximum rate of the reaction. Ratemax. See Question 45 for the graphical method to use.arrow_forward
- Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxChemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoChemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningPhysical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning