The potential energy, kinetic energy should be defined along with the law of conversation of energy, Concept Introduction: The property which is quantitative in nature and must be transferred to an object in order to heat the object and do work on the object is known as energy. Energy is a conserved quantity and can be classified as kinetic energy and potential energy. In thermodynamics , two functions are used to identify the variables that are state functions and path functions. The function which depends upon the state of the reaction is known as state function whereas which depend upon the path of the reaction is known as path function.

Question

Using the bond energy values, calculate the energy that must be supplied or is released upon the polymerization of 755 monomers. If energy must be supplied, provide a positive number; if energy is released, provide a negative number. Hint: Avogadro’s number is 6.02 × 1023.

Answer 1

Question

Chapter 12, Problem 1CR

Interpretation Introduction

Interpretation:

The potential energy, kinetic energy should be defined along with the law of conversation of energy,

Concept Introduction:

The property which is quantitative in nature and must be transferred to an object in order to heat the object and do work on the object is known as energy. Energy is a conserved quantity and can be classified as kinetic energy and potential energy.

In thermodynamics, two functions are used to identify the variables that are state functions and path functions. The function which depends upon the state of the reaction is known as state function whereas which depend upon the path of the reaction is known as path function.

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Using the bond energy values, calculate the energy that must be supplied or is released upon the polymerization of 755 monomers. If energy must be supplied, provide a positive number; if energy is released, provide a negative number. Hint: Avogadro’s number is 6.02 × 1023.

-AG|F=2E|V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: Acidic solution -0.93 +0.38 -0.51 -0.06 H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3 -0.28 -0.50 → -0.50 Basic solution 3-1.12 -1.57 -2.05 -0.89 PO HPO →→H2PO2 P PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH, 0.0 -0.5- 2 3 9 3 -1.5 -2.0 Pa H,PO H,PO H,PO -3 -1 0 2 4 Oxidation state, N 2 b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…

These two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?