Interpretation:
The value of equilibrium constant for the given reaction needs to be determined.
Concept introduction:
The system is said to be in equilibrium if the there is no change in the partial pressure or concentration of reactant and product takes place.
For a general reaction as follows:
The expression for the equilibrium constant is represented as follows:
Here, to calculate the equilibrium constant, the values of partial pressure of all the species in reactant and product side are required.
If an equilibrium reaction is reversed, the value of its equilibrium constant gets inversed. If an equilibrium reaction is multiplied by any value, the value will become the power of the equilibrium constant. On adding two equilibrium reactions, the value of their equilibrium constant gets multiplied. On subtracting two equilibrium reactions, the value of their equilibrium constant gets divided.
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Chapter 12 Solutions
Chemistry: Principles and Reactions
- Write the equilibrium constant expression for each of the following reactions in terms of concentrations. (a) CO2(g) + C(s) 2 CO(g) (b) [Cu(NH3)4)2+(aq) Cu2+(aq) + 4 NH3(aq) (c) CH3CO2H(aq) + H2O() CH3CO2(aq) + H3O+(aq)arrow_forwardWrite the expression for the equilibrium constant and calculate the partial pressure of CO2(g), given that Kp is 0.25 (at 427 C) for NaHCO3(s) NaOH(s) + CO2(g)arrow_forwardWhen carbon dioxide dissolves in water it reacts to produce carbonic acid, H2CO3(aq), which can ionize in two steps. H2CO3(aq)HCO3(aq)+H+(aq)Kc1=4.2107HCO3(aq)CO32(aq)+H+(aq)Kc2=4.81011 Calculate the equilibrium constant for the reaction H2CO3(aq)CO32(aq)+2H+(aq)arrow_forward
- Actually, the carbon in CO2(g) is thermodynamically unstable with respect to the carbon in calcium carbonate(limestone). Verify this by determining the standardGibbs free energy change for the reaction of lime,CaO(s), with CO2(g) to make CaCO3(s).arrow_forwardThe equilibrium constant for the reaction N2(g) + O2(g) 2 NO(g) is 1.7 103 at 2300 K. (a) What is K for the reaction when written as follows? N2(g) + O2(g) NO(g) (b) What is K for the following reaction? 2 NO(g) N2(g) + O2(g)arrow_forwardA 1.00 L flask was filled with 2.00 mol gaseous SO2 and 2.00 mol gaseous NO2 and heated. After equilibrium was reached, it was found that 1.30 mol of gaseous NO was present. Assume that the reaction SO2(g) + NO2(g) SO3(g) + NO(g) occurs under these conditions. Calculate the value of the equilibrium constant, K, for this reactionarrow_forward
- Given the following reactions and their equilibrium constants, H2O(g) + CO(g) ↽−−⇀↽−−⇀ H2(g) + CO2(g) K = 1.6 FeO(s) + CO(g) ↽−−⇀↽−−⇀ Fe(s) + CO2(g) K = 0.67 calculate K for the reaction Fe(s) + H2O(g) ↽−−⇀↽−−⇀ FeO(s) + H2(g)arrow_forwardAt a given temperature, K = 1.3 x 102 for the reaction 3H2(g) + N2(g) → 2NH3(g) Calculate the values of K for the following reactions at this temperature 1/2 N2(g) + 3/2 H2(g) → NH3(g)arrow_forwardAt 25 °C, the following reactions have the equilibrium constants noted to the right of their equations. 2CO(g) + O₂(g) ⇒ 2CO₂(g) Kç= 3.3 × 10⁹1 2H₂(g) + O₂(g) → 2H₂O(g) Kc= 9.1 × 108⁰ Use these data to calculate Kc for the reaction H₂O(g) + CO(g) ⇒ CO₂(g) + H₂(g) Kc= iarrow_forward
- The equilibrium constant for the reaction, 3 H2(g) + N2(g)= 2NH3(g), at a given temperature is 1.4 x 10–7. Calculate the equilibrium concentration of ammonia, if [H2] = 1.2 x 10–2 mol L–1 and [N2] = 3.2 x 10–3 mol L–1.arrow_forwardA 1.00-L flask was filled with 2.14 mol gaseous SO2 and 2.14 mol gaseous NO2 and heated. After equilibrium was reached, it was found that 1.55 mol gaseous NO was present. Assume that the reaction SO2 (g) + NO, (g) = SO3(g) + NO(g) occurs under these conditions. Calculate the value of the equilibrium constant, K, for this reaction. HOW DO WE GET THERE? What are the equilibrium concentrations of SO2, NO2, and SO3? [SO2] = [NO2] = M [SO3] = Marrow_forwardIf the K eq = 798 at 25°C for the reaction 2So2 (g) + O2 (g) -> 2SO3 (g) calculate the equilibrium concentration of O2 given that the concentrations of the other chemicals are: [SO2] = 4.20 M; [SO3] = 11.0 Marrow_forward
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