The meaning for an atom to be in an excited state and to be in its ground state is to be stated. The procedure by which an excited atom returns to its ground state is to be stated. The meaning of a photon is to be stated. The relation between the wavelength of light and the energy of the photons being emitted by an atom is to be stated. The relation between the energy of the photons being emitted by an atom and the energy changes that takes place within the atom is to be stated. Concept Introduction: The distribution of the electrons that exists in the atomic orbital of an atom is collectively known as electronic configuration. The description of every electron in an orbital is given by the electronic configuration of that atom. A photon always moves with a speed of light that is equal to 3 × 10 8 m/s .
The meaning for an atom to be in an excited state and to be in its ground state is to be stated. The procedure by which an excited atom returns to its ground state is to be stated. The meaning of a photon is to be stated. The relation between the wavelength of light and the energy of the photons being emitted by an atom is to be stated. The relation between the energy of the photons being emitted by an atom and the energy changes that takes place within the atom is to be stated. Concept Introduction: The distribution of the electrons that exists in the atomic orbital of an atom is collectively known as electronic configuration. The description of every electron in an orbital is given by the electronic configuration of that atom. A photon always moves with a speed of light that is equal to 3 × 10 8 m/s .
Solution Summary: The author explains the meaning of an atom in an excited state and in its ground state. The relation between the wavelength of light and the energy of the photons is to be stated.
The meaning for an atom to be in an excited state and to be in its ground state is to be stated. The procedure by which an excited atom returns to its ground state is to be stated. The meaning of a photon is to be stated. The relation between the wavelength of light and the energy of the photons being emitted by an atom is to be stated. The relation between the energy of the photons being emitted by an atom and the energy changes that takes place within the atom is to be stated.
Concept Introduction:
The distribution of the electrons that exists in the atomic orbital of an atom is collectively known as electronic configuration. The description of every electron in an orbital is given by the electronic configuration of that atom.
A photon always moves with a speed of light that is equal to 3×108m/s.
Liquid chromatography has been used to track the concentration of remdesivir
(a broad-spectrum antiviral drug, structure shown at right) in COVID patients
undergoing experimental treatments.
Intensity
The authors provide the following details regarding standard solutions
preparation:
HN
CN
HO
OH
NH2
Remdesivir (RDV) stock solution (5000 µg/mL) was prepared by
dissolving RDV drug powder using the mixture of DMSO: MeOH (30:70
v/v). The RDV working standard solutions for calibration and quality
controls were prepared using methanol in concentrations of 100, 10, 1,
0.1, 0.01 µg/mL. 1, 2.5, 5, 7.5, 10, 25, 50, 75, 100, 250, 500, 1000, and 5000 ng/mL sample solutions
were prepared freshly by spiking calibration standard solutions into the blank human plasma samples
for method calibration.
a) What type of calibration method is being described? Why do you think the authors chose this
method as opposed to another?
b) Based on the details provided in part a, describe an appropriate method blank…
Recent advancements in liquid chromatography include the development of ultrahigh pressure liquid
chromatography (UHPLC) and an increased use of capillary columns that had previously only been used
with gas chromatography. Both of these advances have made the development of portable LC systems
possible. For example, Axcend Corp. makes a portable system that uses a capillary column with an
internal diameter of 150-μm-that is packed with 1.7-um stationary phase particles. In contrast, a traditional
LC column has a 4.6 mm internal diameter and utilizes 5-um stationary phase particles.
a) Explain one advantage that is afforded by the use of a capillary column in liquid chromatographic
separation. Explain one disadvantage of capillary columns.
b) Explain how the use of smaller stationary phase particles can improve the resolution of a separation.
Include any relevant equations that support your explanation.
c) A scientist at Rowan University is using
the Axcend LC to conduct analyses of F…
This paper describes the use of fullerene molecules, also known as buckyballs, as a stationary phase for
liquid chromatography. The performance of the fullerene-modified stationary phase (FMS) is compared to
that of a more common C18 stationary phase and to two other carbon-based stationary phases, PGC and
COZ.
A.
10A
OM
B.
-
Figure 1. Idealized drawing of the
cross-section of a pore inside a silica
particle, showing the relative densities
of aminopropylsilyl (red/green) and
fullerene (blue) groups: (A) full cross-
section; (B) detailed view of covalent
bonding of fullerene to the silica
surface. Surface densities of silyl and
fullerene groups were inferred from
elemental composition results obtained
at each stage of the synthesis (see Table
1).
Absorbance (mAU, 220 nm)
700
600
500
400
300
200
100
a. Define selectivity, a, with words and an equation.
b. Explain how the choice of stationary phase affects selectivity.
c. Calculate the resolution of the nitrobenzene and toluene peaks in…
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