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Chemistry for Engineering Students
3rd Edition
ISBN: 9781285199023
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Question
Chapter 12, Problem 12.85PAE
a)
Interpretation Introduction
To determine: The sign of the
b)
Interpretation Introduction
To determine: The
Expert Solution & Answer
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Students have asked these similar questions
Complete the following table. The only density needed is already given. Show your
calculations in a neat and easy-to-follow manner in the space below the table. All units
should be included and significant figures should be given close attention. Be sure to notice
that the amount of material should be in millimoles rather than moles, and the theoretical
mass of the product should in milligrams rather than grams.
LOCH 3
+
H2SO4
HNO 3
O=C-OCH 3
NO2
x
H₂O
F.W.
4.0 mL 1.3 M
amount
0.50 mL
in H2SO4
mg Theoretical
Theoretical
mmoles
density
1.09
Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 12 Solutions
Chemistry for Engineering Students
Ch. 12 - list chemical reactions important in the...Ch. 12 - Explain that equilibrium is dynamic, and that at...Ch. 12 - Prob. 3COCh. 12 - calculate equilibrium constants from experimental...Ch. 12 - Prob. 5COCh. 12 - calculate molar solubility from Kspor vice versa.Ch. 12 - Prob. 7COCh. 12 - Prob. 8COCh. 12 - calculate the new equilibrium composition of a...Ch. 12 - Explain the importance of both kinetic and...
Ch. 12 - Identify the first chemical step in the production...Ch. 12 - Explain why the hydration process for concrete is...Ch. 12 - Prob. 12.3PAECh. 12 - 12.4 In what geographical region of the country...Ch. 12 - Prob. 12.5PAECh. 12 - Prob. 12.6PAECh. 12 - Prob. 12.7PAECh. 12 - On your desk is a glass half-filled with water and...Ch. 12 - In the figure, orange fish are placed in one...Ch. 12 - At a particular temperature, iodine vapor, I2, is...Ch. 12 - Prob. 12.11PAECh. 12 - An equilibrium involving the carbonate and...Ch. 12 - Prob. 12.13PAECh. 12 - A small quantity of a soluble salt is placed in...Ch. 12 - Prob. 12.15PAECh. 12 - Prob. 12.16PAECh. 12 - Write equilibrium (mass action) expressions for...Ch. 12 - What is the difference between homogeneous...Ch. 12 - Write equilibrium expressions for each of the...Ch. 12 - Write equilibrium expressions for each of the...Ch. 12 - Prob. 12.21PAECh. 12 - Which of the following is more likely to...Ch. 12 - 12.17 Which of the following is more likely to...Ch. 12 - The reaction, 3 H2(g) + N2(g) (g), has the fol...Ch. 12 - 12.19 For each of the following equations, write...Ch. 12 - Consider the following equilibria involving SO2(g)...Ch. 12 - Prob. 12.27PAECh. 12 - Prob. 12.28PAECh. 12 - Prob. 12.29PAECh. 12 - Prob. 12.30PAECh. 12 - Prob. 12.31PAECh. 12 - The following data were collected for the...Ch. 12 - The following data were collected for a system at...Ch. 12 - Prob. 12.34PAECh. 12 - Nitrosyl chloride, NOCI, decomposes to NO and Cl,...Ch. 12 - Hydrogen gas and iodine gas react via the...Ch. 12 - 12.31 A system consisting of 0.100 mole of oxygen...Ch. 12 - Prob. 12.38PAECh. 12 - Prob. 12.39PAECh. 12 - 1’he reaction in Exercise 12.33 was repeated. This...Ch. 12 - In the reaction in Exercise 12.33, another trial...Ch. 12 - The experiment in Exercise 12.33 was redesigned so...Ch. 12 - Again the experiment in Exercise 12.33 was...Ch. 12 - At a particular temperature, the equilibrium...Ch. 12 - A student is simulating the carbonic acid—hydrogen...Ch. 12 - Because carbonic acid undergoes a second...Ch. 12 - Because calcium carbonate is a sink for CO32- in a...Ch. 12 - 12.42 The following reaction is in equilibrium in...Ch. 12 - In the following equilibrium in a closed system,...Ch. 12 - In each of the reactions, how does the equilibrium...Ch. 12 - Prob. 12.51PAECh. 12 - Prob. 12.52PAECh. 12 - The decomposition of NH4HS, NH 4 HS( s )NH3( g )+...Ch. 12 - Consider the following system: 4NH 3 ( g )+ 3O 2 (...Ch. 12 - The following equilibrium is established in a...Ch. 12 - Write the K_, expression for each of the following...Ch. 12 - Prob. 12.57PAECh. 12 - calculate the molar solubility of the following...Ch. 12 - 12.49 The Safe Drinking Water Act of 1974...Ch. 12 - In Exercise 12.49, what is the allowed...Ch. 12 - Prob. 12.61PAECh. 12 - Because barium sulfate is opaque to X-rays, it is...Ch. 12 - The ore cinnabar (HgS) is an important source of...Ch. 12 - Prob. 12.64PAECh. 12 - From the solubility data given for the following...Ch. 12 - The solubility of magnesium fluoride, MgF2, in...Ch. 12 - Solid Na2SO4 is added slowly to a solution that is...Ch. 12 - Will a precipitate of Mg(OH)2 form when 25.0 mL of...Ch. 12 - Use the web to look up boiler scale and explain...Ch. 12 - Prob. 12.70PAECh. 12 - Prob. 12.71PAECh. 12 - 12.62 Write the formula of the conjugate acid of...Ch. 12 - 12.63 For each of the following reactions,...Ch. 12 - What are the products of each of the following...Ch. 12 - Prob. 12.75PAECh. 12 - Prob. 12.76PAECh. 12 - 12.67 Hydrofluoric acid is a weak acid used in the...Ch. 12 - The pH of a 0.129 M solution of a weak acid, HB,...Ch. 12 - Calculate the pH of a 0.10 M solution of propanoic...Ch. 12 - Find the pH of a 0.115 M solution of NH3(aq).Ch. 12 - Acrylic acid is used in the polymer industry in...Ch. 12 - Prob. 12.82PAECh. 12 - Prob. 12.83PAECh. 12 - In a particular experiment, the equilibrium...Ch. 12 - Prob. 12.85PAECh. 12 - Prob. 12.86PAECh. 12 - Prob. 12.87PAECh. 12 - Prob. 12.88PAECh. 12 - Prob. 12.89PAECh. 12 - Prob. 12.90PAECh. 12 - Prob. 12.91PAECh. 12 - Prob. 12.92PAECh. 12 - Solid CaCO3 ; is placed in a closed container and...Ch. 12 - 12.100 A reaction important in smog formation is...Ch. 12 - 12.101 An engineer working on a design to extract...Ch. 12 - 12.102 A chemical engineer is working to optimize...Ch. 12 - 12.103 Methanol, CH3OH, can be produced by the...Ch. 12 - Prob. 12.98PAECh. 12 - 12.105 Using the kinetic-molecular theory, explain...Ch. 12 - 12.106 The solubility of KCl is 34.7 g per 100 g...Ch. 12 - Prob. 12.101PAECh. 12 - 12.108 A nuclear engineer is considering the...Ch. 12 - 12.109 Copper(II) iodate has a solubility of 0.136...Ch. 12 - 12.110 In Exercise 12.109, what do you predict...Ch. 12 - 12.111 You have three white solids. What...Ch. 12 - Prob. 12.106PAECh. 12 - Prob. 12.107PAECh. 12 - Prob. 12.108PAECh. 12 - Prob. 12.109PAECh. 12 - Prob. 12.110PAECh. 12 - 12.117 The vapor pressure of water at 80.0 °C is...Ch. 12 - Prob. 12.112PAE
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