
Chemistry for Engineering Students
3rd Edition
ISBN: 9781285199023
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Question
Chapter 12, Problem 12.7PAE
Interpretation Introduction
Interpretation:
The result of spraying a solution of phenolphthalein on the surface of a piece of old concrete should be explained.
Concept Introduction:
- Concrete is a mixture of cement, water and other additives that are mixed in order to produce concrete with the desired composition and characteristics.
- Hydration is a process through which water is added to the cement mixture to form silicate hydrates and calcium hydroxide, which makes concrete alkaline.
- Phenolphthalein is an indicator that is used to the test the extent of carbonation in concrete.
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14:33 A
Candidate Identification
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11. Compound A can transform into
compound B through an organic reaction.
From the structures below, mark the
correct one:
HO
A
تھے۔
די
HO
B
○ A) Compounds A and B are isomers.
B) Both have the same number of chiral
carbons.
C) Compound A underwent an addition
reaction of Cl2 and H2O to form
compound B.
D) Compound A underwent a
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intermediate chlorohydrin to obtain
compound B.
E) Compound A underwent an addition
reaction of Cl2 forming the chloronium
ion and then added methanol to obtain
compound B.
60
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14:40 A
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13. The compound 1-bromo-hex-2-ene
reacts with methanol to form two
products. About this reaction, mark the
correct statement:
OCH3
CH3OH
Br
OCH3 +
+ HBr
A
B
A) The two products formed will have
the same percentage of formation.
B) Product B will be formed by SN1
substitution reaction with the formation
of an allylic carbocation.
C) Product A will be formed by SN1
substitution reaction with the formation
of a more stable carbocation than
product B.
D) Product A will be formed by an SN2
substitution reaction occurring in two
stages, the first with slow kinetics and
the second with fast kinetics.
E) The two compounds were obtained
by addition reaction, with compound B
having the highest percentage of
formation.
57
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14:30 A
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10. Amoxicillin (figure X) is one of the
most widely used antibiotics in the
penicillin family. The discovery and
synthesis of these antibiotics in the 20th
century made the treatment of infections
that were previously fatal routine.
About amoxicillin, mark the correct one:
HO
NH2 H
S
-N.
HO
Figura X. Amoxicilina
A) It has the organic functions amide,
ester, phenol and amine.
B) It has four chiral carbons and 8
stereoisomers.
C) The substitution of the aromatic ring
is of the ortho-meta type.
D) If amoxicillin reacts with an alcohol it
can form an ester.
E) The structure has two tertiary
amides.
62
Chapter 12 Solutions
Chemistry for Engineering Students
Ch. 12 - list chemical reactions important in the...Ch. 12 - Explain that equilibrium is dynamic, and that at...Ch. 12 - Prob. 3COCh. 12 - calculate equilibrium constants from experimental...Ch. 12 - Prob. 5COCh. 12 - calculate molar solubility from Kspor vice versa.Ch. 12 - Prob. 7COCh. 12 - Prob. 8COCh. 12 - calculate the new equilibrium composition of a...Ch. 12 - Explain the importance of both kinetic and...
Ch. 12 - Identify the first chemical step in the production...Ch. 12 - Explain why the hydration process for concrete is...Ch. 12 - Prob. 12.3PAECh. 12 - 12.4 In what geographical region of the country...Ch. 12 - Prob. 12.5PAECh. 12 - Prob. 12.6PAECh. 12 - Prob. 12.7PAECh. 12 - On your desk is a glass half-filled with water and...Ch. 12 - In the figure, orange fish are placed in one...Ch. 12 - At a particular temperature, iodine vapor, I2, is...Ch. 12 - Prob. 12.11PAECh. 12 - An equilibrium involving the carbonate and...Ch. 12 - Prob. 12.13PAECh. 12 - A small quantity of a soluble salt is placed in...Ch. 12 - Prob. 12.15PAECh. 12 - Prob. 12.16PAECh. 12 - Write equilibrium (mass action) expressions for...Ch. 12 - What is the difference between homogeneous...Ch. 12 - Write equilibrium expressions for each of the...Ch. 12 - Write equilibrium expressions for each of the...Ch. 12 - Prob. 12.21PAECh. 12 - Which of the following is more likely to...Ch. 12 - 12.17 Which of the following is more likely to...Ch. 12 - The reaction, 3 H2(g) + N2(g) (g), has the fol...Ch. 12 - 12.19 For each of the following equations, write...Ch. 12 - Consider the following equilibria involving SO2(g)...Ch. 12 - Prob. 12.27PAECh. 12 - Prob. 12.28PAECh. 12 - Prob. 12.29PAECh. 12 - Prob. 12.30PAECh. 12 - Prob. 12.31PAECh. 12 - The following data were collected for the...Ch. 12 - The following data were collected for a system at...Ch. 12 - Prob. 12.34PAECh. 12 - Nitrosyl chloride, NOCI, decomposes to NO and Cl,...Ch. 12 - Hydrogen gas and iodine gas react via the...Ch. 12 - 12.31 A system consisting of 0.100 mole of oxygen...Ch. 12 - Prob. 12.38PAECh. 12 - Prob. 12.39PAECh. 12 - 1’he reaction in Exercise 12.33 was repeated. This...Ch. 12 - In the reaction in Exercise 12.33, another trial...Ch. 12 - The experiment in Exercise 12.33 was redesigned so...Ch. 12 - Again the experiment in Exercise 12.33 was...Ch. 12 - At a particular temperature, the equilibrium...Ch. 12 - A student is simulating the carbonic acid—hydrogen...Ch. 12 - Because carbonic acid undergoes a second...Ch. 12 - Because calcium carbonate is a sink for CO32- in a...Ch. 12 - 12.42 The following reaction is in equilibrium in...Ch. 12 - In the following equilibrium in a closed system,...Ch. 12 - In each of the reactions, how does the equilibrium...Ch. 12 - Prob. 12.51PAECh. 12 - Prob. 12.52PAECh. 12 - The decomposition of NH4HS, NH 4 HS( s )NH3( g )+...Ch. 12 - Consider the following system: 4NH 3 ( g )+ 3O 2 (...Ch. 12 - The following equilibrium is established in a...Ch. 12 - Write the K_, expression for each of the following...Ch. 12 - Prob. 12.57PAECh. 12 - calculate the molar solubility of the following...Ch. 12 - 12.49 The Safe Drinking Water Act of 1974...Ch. 12 - In Exercise 12.49, what is the allowed...Ch. 12 - Prob. 12.61PAECh. 12 - Because barium sulfate is opaque to X-rays, it is...Ch. 12 - The ore cinnabar (HgS) is an important source of...Ch. 12 - Prob. 12.64PAECh. 12 - From the solubility data given for the following...Ch. 12 - The solubility of magnesium fluoride, MgF2, in...Ch. 12 - Solid Na2SO4 is added slowly to a solution that is...Ch. 12 - Will a precipitate of Mg(OH)2 form when 25.0 mL of...Ch. 12 - Use the web to look up boiler scale and explain...Ch. 12 - Prob. 12.70PAECh. 12 - Prob. 12.71PAECh. 12 - 12.62 Write the formula of the conjugate acid of...Ch. 12 - 12.63 For each of the following reactions,...Ch. 12 - What are the products of each of the following...Ch. 12 - Prob. 12.75PAECh. 12 - Prob. 12.76PAECh. 12 - 12.67 Hydrofluoric acid is a weak acid used in the...Ch. 12 - The pH of a 0.129 M solution of a weak acid, HB,...Ch. 12 - Calculate the pH of a 0.10 M solution of propanoic...Ch. 12 - Find the pH of a 0.115 M solution of NH3(aq).Ch. 12 - Acrylic acid is used in the polymer industry in...Ch. 12 - Prob. 12.82PAECh. 12 - Prob. 12.83PAECh. 12 - In a particular experiment, the equilibrium...Ch. 12 - Prob. 12.85PAECh. 12 - Prob. 12.86PAECh. 12 - Prob. 12.87PAECh. 12 - Prob. 12.88PAECh. 12 - Prob. 12.89PAECh. 12 - Prob. 12.90PAECh. 12 - Prob. 12.91PAECh. 12 - Prob. 12.92PAECh. 12 - Solid CaCO3 ; is placed in a closed container and...Ch. 12 - 12.100 A reaction important in smog formation is...Ch. 12 - 12.101 An engineer working on a design to extract...Ch. 12 - 12.102 A chemical engineer is working to optimize...Ch. 12 - 12.103 Methanol, CH3OH, can be produced by the...Ch. 12 - Prob. 12.98PAECh. 12 - 12.105 Using the kinetic-molecular theory, explain...Ch. 12 - 12.106 The solubility of KCl is 34.7 g per 100 g...Ch. 12 - Prob. 12.101PAECh. 12 - 12.108 A nuclear engineer is considering the...Ch. 12 - 12.109 Copper(II) iodate has a solubility of 0.136...Ch. 12 - 12.110 In Exercise 12.109, what do you predict...Ch. 12 - 12.111 You have three white solids. What...Ch. 12 - Prob. 12.106PAECh. 12 - Prob. 12.107PAECh. 12 - Prob. 12.108PAECh. 12 - Prob. 12.109PAECh. 12 - Prob. 12.110PAECh. 12 - 12.117 The vapor pressure of water at 80.0 °C is...Ch. 12 - Prob. 12.112PAE
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