(a) Interpretation: The bond at which fragmentation occurs in the structure of 2, 2, 5, 5-tetramethylhexane is to be stated. Concept introduction: Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as ( M + 1 ) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

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Answer 1

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Chapter 12, Problem 12.18P

Interpretation Introduction

(a)

Interpretation:

The bond at which fragmentation occurs in the structure of 2, 2, 5, 5-tetramethylhexane is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

Interpretation Introduction

(b)

Interpretation:

The mechanism for the fragmentation of the bond between two methylene group is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

Interpretation Introduction

(c)

Interpretation:

The structure of the fragment ion of 2, 2, 5, 5-tetramethylhexane at m/z=71 is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

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Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br‍(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.

Answer 2

Question

Chapter 12, Problem 12.18P

Interpretation Introduction

(a)

Interpretation:

The bond at which fragmentation occurs in the structure of 2, 2, 5, 5-tetramethylhexane is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

Interpretation Introduction

(b)

Interpretation:

The mechanism for the fragmentation of the bond between two methylene group is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

Interpretation Introduction

(c)

Interpretation:

The structure of the fragment ion of 2, 2, 5, 5-tetramethylhexane at m/z=71 is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

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Answer 3

Question

Chapter 12, Problem 12.18P

Interpretation Introduction

(a)

Interpretation:

The bond at which fragmentation occurs in the structure of 2, 2, 5, 5-tetramethylhexane is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

Interpretation Introduction

(b)

Interpretation:

The mechanism for the fragmentation of the bond between two methylene group is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

Interpretation Introduction

(c)

Interpretation:

The structure of the fragment ion of 2, 2, 5, 5-tetramethylhexane at m/z=71 is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

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Answer 4

Question

Chapter 12, Problem 12.18P

Interpretation Introduction

(a)

Interpretation:

The bond at which fragmentation occurs in the structure of 2, 2, 5, 5-tetramethylhexane is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

Interpretation Introduction

(b)

Interpretation:

The mechanism for the fragmentation of the bond between two methylene group is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

Interpretation Introduction

(c)

Interpretation:

The structure of the fragment ion of 2, 2, 5, 5-tetramethylhexane at m/z=71 is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

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Answer 5

Chapter 12, Problem 12.18P

Interpretation Introduction

(a)

Interpretation:

The bond at which fragmentation occurs in the structure of 2, 2, 5, 5-tetramethylhexane is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

Interpretation Introduction

(b)

Interpretation:

The mechanism for the fragmentation of the bond between two methylene group is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

Interpretation Introduction

(c)

Interpretation:

The structure of the fragment ion of 2, 2, 5, 5-tetramethylhexane at m/z=71 is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

Answer 6

Chapter 12, Problem 12.18P

Interpretation Introduction

(a)

Interpretation:

The bond at which fragmentation occurs in the structure of 2, 2, 5, 5-tetramethylhexane is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

Answer 7

Chapter 12, Problem 12.18P

Interpretation Introduction

(a)

Interpretation:

The bond at which fragmentation occurs in the structure of 2, 2, 5, 5-tetramethylhexane is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The mechanism for the fragmentation of the bond between two methylene group is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The mechanism for the fragmentation of the bond between two methylene group is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of the fragment ion of 2, 2, 5, 5-tetramethylhexane at m/z=71 is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of the fragment ion of 2, 2, 5, 5-tetramethylhexane at m/z=71 is to be stated.

Concept introduction:

Mass spectroscopy is used to calculate mass to charge ratio of ions. Isotopic peak is also known as (M+1) peak because it shows one unit mass more than the mass of the molecular ion. This is because the molecule consists of different isotopes of an element.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 12 - Prob. 12.1P Ch. 12 - Prob. 12.2P Ch. 12 - Prob. 12.3P Ch. 12 - Prob. 12.4P Ch. 12 - Prob. 12.5P Ch. 12 - Prob. 12.6P Ch. 12 - Prob. 12.7P Ch. 12 - Prob. 12.8P Ch. 12 - Prob. 12.9P Ch. 12 - Prob. 12.10P

Solution Summary: The author describes the mechanism for the fragmentation of the bond between two methylene groups in 2, 2, 5, 5-tetramethylhexane.

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Chapter 12 Solutions