
(a)
Interpretation:
Whether the
Concept introduction:
The IR rays are able to stretch the bond in the compound as they carry the energy sufficient to perform this task. The compound is said to be IR active if the energy absorbed the bond leads to change in the dipole moment of the molecule.

Answer to Problem 12.10P
The
Explanation of Solution
Change in the dipole moment of the molecule on IR absorption is the necessary condition to be IR active.
The
Therefore,
The
(b)
Interpretation:
Whether the
Concept introduction:
The IR rays are able to stretch the bond in the compound as they carry the energy sufficient to perform this task. The compound is said to be IR active if the energy absorbed the bond leads to change in the dipole moment of the molecule.

Answer to Problem 12.10P
The
Explanation of Solution
Change in the dipole moment of the molecule on IR absorption is the necessary condition to be IR active.
The
Therefore,
The
(c)
Interpretation:
Whether the cyclohexane ring “breathing” or simultaneous stretching of the all
Concept introduction:
The IR rays are able to stretch the bond in the compound as they carry the energy sufficient to perform this task. The compound is said to be IR active if the energy absorbed the bond leads to change in the dipole moment of the molecule.

Answer to Problem 12.10P
The simultaneous stretch of all
Explanation of Solution
Change in the dipole moment of the molecule on IR absorption is the necessary condition to be IR active.
The simultaneous stretch of all
Therefore, simultaneous stretch of all
The simultaneous stretch of all
(d)
Interpretation:
Whether the
Concept introduction:
The IR rays are able to stretch the bond in the compound as they carry the energy sufficient to perform this task. The compound is said to be IR active if the energy absorbed the bond leads to change in the dipole moment of the molecule.

Answer to Problem 12.10P
The
Explanation of Solution
Change in the dipole moment of the molecule on IR absorption is the necessary condition to be IR active.
The
Therefore,
The
(e)
Interpretation:
Whether the symmetrical stretching of the
Concept introduction:
The IR rays are able to stretch the bond in the compound as they carry the energy sufficient to perform this task. The compound is said to be IR active if the energy absorbed the bond leads to change in the dipole moment of the molecule.

Answer to Problem 12.10P
The symmetric stretch of
Explanation of Solution
Change in the dipole moment of the molecule on IR absorption is the necessary condition to be IR active.
The symmetric stretch of
Therefore, symmetric stretch of
The symmetric stretch of
(f)
Interpretation:
Whether the
Concept introduction:
The IR rays are able to stretch the bond in the compound as they carry the energy sufficient to perform this task. The compound is said to be IR active if the energy absorbed the bond leads to change in the dipole moment of the molecule.

Answer to Problem 12.10P
The stretch of
Explanation of Solution
Change in the dipole moment of the molecule on IR absorption is the necessary condition to be IR active.
The stretch of
Therefore, stretch of
The stretch of
(g)
Interpretation:
Whether the
Concept introduction:
The IR rays are able to stretch the bond in the compound as they carry the energy sufficient to perform this task. The compound is said to be IR active if the energy absorbed the bond leads to change in the dipole moment of the molecule.

Answer to Problem 12.10P
The
Explanation of Solution
Change in the dipole moment of the molecule on IR absorption is the necessary condition to be IR active.
The structure of
Figure 1
The
Therefore,
The
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Chapter 12 Solutions
Organic Chemistry
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- Can I please get the graph 1: Concentration vs. Density?arrow_forwardOrder the following series of compounds from highest to lowest reactivity to electrophilic aromatic substitution, explaining your answer: 2-nitrophenol, p-Toluidine, N-(4-methylphenyl)acetamide, 4-methylbenzonitrile, 4-(trifluoromethyl)benzonitrile.arrow_forwardOrdene la siguiente serie de compuestos de mayor a menor reactividad a la sustitución aromática electrofílica, explicando su respuesta: ácido bencenosulfónico, fluorobenceno, etilbenceno, clorobenceno, terc-butilbenceno, acetofenona.arrow_forward
- Can I please get all final concentrations please!arrow_forwardState the detailed mechanism of the reaction of benzene with isopropanol in sulfuric acid.arrow_forwardDo not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction. For the decomposition reaction of N2O5(g): 2 N2O5(g) · 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 -> NO2 + NO3_(K1) NO2 + NO3 →> N2O5 (k-1) → NO2 + NO3 → NO2 + O2 + NO (K2) NO + N2O5 → NO2 + NO2 + NO2 (K3) Give the expression for the acceptable rate. (A). d[N₂O] dt = -1 2k,k₂[N205] k₁+k₂ d[N₂O5] (B). dt =-k₁[N₂O₂] + k₁[NO2][NO3] - k₂[NO2]³ (C). d[N₂O] dt =-k₁[N₂O] + k₁[N205] - K3 [NO] [N205] (D). d[N2O5] =-k₁[NO] - K3[NO] [N₂05] dtarrow_forward
- A 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 20.0 mL of the base solution, what is the pH of the resulting solution?arrow_forwardFor the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3) → Give the expression for the acceptable rate. → → (A). d[N205] dt == 2k,k₂[N₂O₂] k₁+k₁₂ (B). d[N2O5] =-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³ dt (C). d[N2O5] =-k₁[N₂O] + k [NO] - k₂[NO] [NO] d[N2O5] (D). = dt = -k₁[N2O5] - k¸[NO][N₂05] dt Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.arrow_forwardFor the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed: N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3) → Give the expression for the acceptable rate. → → (A). d[N205] dt == 2k,k₂[N₂O₂] k₁+k₁₂ (B). d[N2O5] =-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³ dt (C). d[N2O5] =-k₁[N₂O] + k [NO] - k₂[NO] [NO] d[N2O5] (D). = dt = -k₁[N2O5] - k¸[NO][N₂05] dt Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.arrow_forward
- Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
