The member of the given pair which is expected to have high boiling point has to be identified. Concept Introduction: The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens. Physical properties of halogenated alkanes : Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations. General trend considering the boiling point and melting point of halogenated hydrocarbon are, Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases. As the size of halogen atom increases, the melting point and boiling point also increases. Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Question

Correctly name this compound using the IUPAC naming system by sorting the components into the correct order. Br IN Ν H

Answer 1

Question

Chapter 12, Problem 12.143EP

(a)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(b)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(c)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(d)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Students have asked these similar questions

Correctly name this compound using the IUPAC naming system by sorting the components into the correct order. Br IN Ν H

How is the radical intermediate for this structure formed? Can you please draw arrows from the first radical to the resonance form that would result in this product? I'm lost.

Part VI. (a) calculate the λ max of the compound using woodward - Fieser rules. (b) what types of electronic transitions are present in the compound? (c) what are the prominent peaks in the IR spectrum of the compound?

Answer 2

Question

Chapter 12, Problem 12.143EP

(a)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(b)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(c)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(d)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 3

Question

Chapter 12, Problem 12.143EP

(a)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(b)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(c)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(d)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Chapter 12, Problem 12.143EP

(a)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(b)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(c)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(d)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 5

Chapter 12, Problem 12.143EP

(a)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(b)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(c)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

(d)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Answer 6

Chapter 12, Problem 12.143EP

(a)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Answer 7

Chapter 12, Problem 12.143EP

(a)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The member of the given pair which is expected to have high boiling point has to be identified.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

Physical properties of halogenated alkanes:

Boiling point of halogenated hydrocarbon is usually higher than the corresponding hydrocarbon. This is because, there is a polarity difference between carbon and halogen atom. This result in increased dipole‑dipole interations.

General trend considering the boiling point and melting point of halogenated hydrocarbon are,

Melting and boiling points increase with the increase in size of alkyl groups that is present. Due to the increasing intermolecular forces, the melting and boiling point increases.

As the size of halogen atom increases, the melting point and boiling point also increases.

Halogenated hydrocarbons do not possess hydrogen bonding capability. Therefore, solubility of halogenated hydrocarbon is limited.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 17

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 18

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 19

Trending nowThis is a popular solution!

Answer 20

Trending nowThis is a popular solution!

Answer 21

Trending nowThis is a popular solution!

Answer 22

Trending now

Answer 23

This is a popular solution!

Answer 24

See solution

Check out sample textbook solution

Answer 25

Ch. 12.1 - Prob. 1QQ Ch. 12.1 - Prob. 2QQ Ch. 12.2 - Prob. 1QQ Ch. 12.2 - Prob. 2QQ Ch. 12.3 - Prob. 1QQ Ch. 12.3 - Prob. 2QQ Ch. 12.4 - Prob. 1QQ Ch. 12.4 - Prob. 2QQ Ch. 12.4 - Prob. 3QQ Ch. 12.5 - Prob. 1QQ

Solution Summary: The author explains the physical properties of halogenated hydrocarbons.

Concept explainers

Videos

Chapter 12 Solutions