The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas. Concept Introduction: Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word. Prefix represents the substituent present in the molecule and its position in the root name. Suffix denotes the presence of functional group if any in the molecule. It can be an alkene , alkyne , alcohol, carboxylic acid , alcohol etc. Root word represents the longest continuous carbon skeleton of the organic molecule. To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

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Answer 1

Question

Chapter 12, Problem 12.48EP

(a)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

(b)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

(c)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

(d)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

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Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed a chemical structure shown below: % Transmittance 4000 3500 3000 2500 2000 Wavenumber (cm-1) 1500 1000 (a) Explain why her proposed structure is inconsistent with the IR spectrum obtained (b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure and explain why it is more compatible with the obtained spectrum. (C) what is the possible source for the fairly intense signal at 1621cm1

AE>AE₁ (Y/N) AE=AE₁ (Y/N) AE

Treatment of 2-phenylpropan-2-amine with methyl 2,4-dibromobutanoate in the presence of a nonnucleophilic base, R3N, involves two successive SN2 reactions and gives compound A. ? NH2 Br Br Propose a structural formula for compound A. You do not have to explicitly draw H atoms. You do not have to consider stereochemistry. In cases where there is more than one answer, just draw one. R3N C14H19NO2 + 2 R3NH*Br A

Answer 2

Question

Chapter 12, Problem 12.48EP

(a)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

(b)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

(c)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

(d)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

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Answer 3

Question

Chapter 12, Problem 12.48EP

(a)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

(b)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

(c)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

(d)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

Expert Solution & Answer

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See solution

Answer 4

Question

Chapter 12, Problem 12.48EP

(a)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

(b)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

(c)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

(d)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

Expert Solution & Answer

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See solution

Answer 5

Chapter 12, Problem 12.48EP

(a)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

(b)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

(c)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

(d)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

Answer 6

Chapter 12, Problem 12.48EP

(a)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

Answer 7

Chapter 12, Problem 12.48EP

(a)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The total number of carbon atoms that is present in the longest continuous chain has to be found for the given skeletal structural formulas.

Concept Introduction:

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule and its position in the root name.

Suffix denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc.

Root word represents the longest continuous carbon skeleton of the organic molecule.

To name an alkane the first step is to found out the longest continuous chain. The other carbon atoms that are present apart from the longest carbon chain is the substituents.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 12.1 - Prob. 1QQ Ch. 12.1 - Prob. 2QQ Ch. 12.2 - Prob. 1QQ Ch. 12.2 - Prob. 2QQ Ch. 12.3 - Prob. 1QQ Ch. 12.3 - Prob. 2QQ Ch. 12.4 - Prob. 1QQ Ch. 12.4 - Prob. 2QQ Ch. 12.4 - Prob. 3QQ Ch. 12.5 - Prob. 1QQ

Solution Summary: The author explains that any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).

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