The common name for the given halogenated hydrocarbon has to be given. Concept Introduction: The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens. IUPAC nomenclature for halogenated alkanes /cycloalkanes: Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-. If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group. In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order. Common names: Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

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Answer 1

Question

Chapter 12, Problem 12.137EP

(a)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

(b)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

(c)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

(d)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

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6. Match each of the lettered items in the column on the left with the most appropriate numbered item(s) in the column on the right. Some of the numbered items may be used more than once and some not at all. a. Z = 37 1. b. Mn 2. C. Pr element in period 5 and group 14 element in period 5 and group 15 d. S e. [Rn] 7s¹ f. d block metal 3. highest metallic character of all the elements 4. paramagnetic with 5 unpaired electrons 5. 4f36s2 6. isoelectronic with Ca²+ cation 7. an alkaline metal 8. an f-block element

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Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed a chemical structure shown below: % Transmittance 4000 3500 3000 2500 2000 Wavenumber (cm-1) 1500 1000 (a) Explain why her proposed structure is inconsistent with the IR spectrum obtained (b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure and explain why it is more compatible with the obtained spectrum. (C) what is the possible source for the fairly intense signal at 1621cm1

Answer 2

Question

Chapter 12, Problem 12.137EP

(a)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

(b)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

(c)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

(d)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

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Answer 3

Question

Chapter 12, Problem 12.137EP

(a)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

(b)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

(c)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

(d)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

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Answer 4

Question

Chapter 12, Problem 12.137EP

(a)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

(b)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

(c)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

(d)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

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Answer 5

Chapter 12, Problem 12.137EP

(a)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

(b)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

(c)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

(d)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

Answer 6

Chapter 12, Problem 12.137EP

(a)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

Answer 7

Chapter 12, Problem 12.137EP

(a)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The common name for the given halogenated hydrocarbon has to be given.

Concept Introduction:

The derivative of alkane with halogen instead of one or more hydrogen atoms is known as halogenated alkane. If the same is present in cycloalkane, then it is known as halogenated cycloalkane. They are product of reaction between alkane/cycloalkane with halogens.

IUPAC nomenclature for halogenated alkanes/cycloalkanes:

Similar to the alkyl groups, the halogen is also treated as substituents present on the carbon chain. They are called as fluoro-, chloro-, bromo-, and iodo-.

If the carbon chain contains both alkyl and halogen, they both are considered of equal ranks. The numbering is done in a way so that the substituents get the least number, whether it is an alkyl or a halo group.

In IUPAC names, the groups that are present on the carbon chain are written in alphabetical order.

Common names:

Halogenated alkanes are also named as alkyl halides. These are not IUPAC names. They are common names. In a common name, two parts are present. First part is the name of the hydrocarbon (alkyl group). Second part gives the halogen present in the compound. The halogen is considered as though it is present as an ion even though no ions are present.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 12.1 - Prob. 1QQ Ch. 12.1 - Prob. 2QQ Ch. 12.2 - Prob. 1QQ Ch. 12.2 - Prob. 2QQ Ch. 12.3 - Prob. 1QQ Ch. 12.3 - Prob. 2QQ Ch. 12.4 - Prob. 1QQ Ch. 12.4 - Prob. 2QQ Ch. 12.4 - Prob. 3QQ Ch. 12.5 - Prob. 1QQ

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