For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn. Concept Introduction: Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula. Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism. If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group , but they differ in the connectivity between the atoms in the molecule. For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present. Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

Question

Correctly name this compound using the IUPAC naming system by sorting the components into the correct order. Br IN Ν H

Answer 1

Question

Chapter 12, Problem 12.113EP

(a)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

(b)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

(c)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

(d)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

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Correctly name this compound using the IUPAC naming system by sorting the components into the correct order. Br IN Ν H

How is the radical intermediate for this structure formed? Can you please draw arrows from the first radical to the resonance form that would result in this product? I'm lost.

Part VI. (a) calculate the λ max of the compound using woodward - Fieser rules. (b) what types of electronic transitions are present in the compound? (c) what are the prominent peaks in the IR spectrum of the compound?

Answer 2

Question

Chapter 12, Problem 12.113EP

(a)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

(b)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

(c)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

(d)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

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Answer 3

Question

Chapter 12, Problem 12.113EP

(a)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

(b)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

(c)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

(d)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

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Answer 4

Question

Chapter 12, Problem 12.113EP

(a)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

(b)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

(c)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

(d)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

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Answer 5

Chapter 12, Problem 12.113EP

(a)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

(b)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

(c)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

(d)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

Answer 6

Chapter 12, Problem 12.113EP

(a)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

Answer 7

Chapter 12, Problem 12.113EP

(a)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

Answer 8

(b)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

Answer 9

(b)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

Answer 10

(c)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

Answer 11

(c)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

Answer 12

(d)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

Answer 13

(d)

Interpretation Introduction

Interpretation:

For the given cycloalkane, cis‑trans isomerism is possible or not has to be determined and if it is possible, the structural formula has to be drawn.

Concept Introduction:

Organic compounds are represented shortly by the molecular formula and structural formula. Each and every compound has its own molecular formula. Compounds can have same molecular formula but not same structural formula.

Isomers are the compounds that have same molecular formula but different structural formula. The main difference lies in the way the atoms are arranged in the structure. Isomers have different chemical and physical properties even when they have same molecular formula. This is known as Isomerism.

If there is difference only in the connectivity of the atoms in the molecule, then it is known as constitutional isomerism. The isomers are known as constitutional isomers. They will have same molecular formula and same functional group, but they differ in the connectivity between the atoms in the molecule.

For constitutional isomers to be present in cycloalkane, a minimum of four carbon atoms has to be present.

Cycloalkanes can also exhibit stereoisomerism. The difference between constitutional isomerism and stereoisomerism is that, the result of difference in connectivity of carbon atoms is known as constitutional isomerism and the result of differences in configuration is known as stereoisomerism. Stereoisomers are compounds that possess same molecular formula and connectivity of atoms but different orientations of atoms in space. Cis isomers are the one where the two substituted groups on different carbon atom are present above or below the plane or the ring of carbon atoms. Trans isomers are the one where the two substituted groups on different carbon atom are present one above and one below the plane or the ring of carbon atoms.

Answer 14

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Answer 25

Ch. 12.1 - Prob. 1QQ Ch. 12.1 - Prob. 2QQ Ch. 12.2 - Prob. 1QQ Ch. 12.2 - Prob. 2QQ Ch. 12.3 - Prob. 1QQ Ch. 12.3 - Prob. 2QQ Ch. 12.4 - Prob. 1QQ Ch. 12.4 - Prob. 2QQ Ch. 12.4 - Prob. 3QQ Ch. 12.5 - Prob. 1QQ

Solution Summary: The author explains that cistrans isomerism is possible or not for cycloalkane. Compounds can have same molecular formula but not same structural formula.

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