
Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781305176461
Author: Kotz
Publisher: Cengage
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Question
Chapter 11.6, Problem 2RC
Interpretation Introduction
Interpretation: It should be determined for the enthalpy of vaporization of diethyl ether compound.
Concept introduction:
Given
Vapor pressure
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Identify and provide an explanation that distinguishes a qualitative and quantitative chemical analysis. Provide examples.
Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
Chapter 11 Solutions
Chemistry & Chemical Reactivity
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Ch. 11.6 - The molar enthalpy of vaporization of methanol,...Ch. 11.6 - Prob. 2CYUCh. 11.6 - Prob. 1RCCh. 11.6 - Prob. 2RCCh. 11.6 - Prob. 3RCCh. 11.6 - Prob. 1QCh. 11.6 - Prob. 2QCh. 11.A - Prob. 1QCh. 11.A - Prob. 2QCh. 11 - Prob. 1PSCh. 11 - Intermolecular forces: What type of forces must be...Ch. 11 - Prob. 3PSCh. 11 - Prob. 4PSCh. 11 - Considering intermolecular forces in the pure...Ch. 11 - Considering intermolecular forces in the pure...Ch. 11 - Prob. 7PSCh. 11 - Which of the following compounds would be expected...Ch. 11 - Prob. 9PSCh. 11 - When salts of Mg2+, Na+, and Cs+ are placed in...Ch. 11 - Prob. 11PSCh. 11 - The enthalpy of vaporization of liquid mercury is...Ch. 11 - Answer the following questions using Figure 11.12:...Ch. 11 - Answer the following questions using Figure 11.12:...Ch. 11 - Prob. 15PSCh. 11 - Refer to Figure 11.12 to answer these questions:...Ch. 11 - Which member of each of the following pairs of...Ch. 11 - Place the following four compounds in order of...Ch. 11 - Prob. 19PSCh. 11 - You are comparing three different substances, A,...Ch. 11 - Equilibrium vapor pressures of benzene, C6H6, at...Ch. 11 - Prob. 22PSCh. 11 - Can carbon monoxide (Tc = 132.9 K; Pc = 34.5 atm...Ch. 11 - Methane (CH4) cannot be liquefied at room...Ch. 11 - What is surface tension? Give an example...Ch. 11 - What factors affect the viscosity of a substance?...Ch. 11 - If a piece of filter paper (an absorbent paper...Ch. 11 - When water is placed in a buret it forms a concave...Ch. 11 - Prob. 29GQCh. 11 - What types of intermolecular forces are important...Ch. 11 - Which of the following salts, Li2SO4 or Cs2SO4, is...Ch. 11 - Prob. 32GQCh. 11 - Prob. 33GQCh. 11 - Prob. 34GQCh. 11 - Rank the following compounds in order of...Ch. 11 - Prob. 36GQCh. 11 - Prob. 37GQCh. 11 - The following data are the equilibrium vapor...Ch. 11 - Prob. 39ILCh. 11 - A hand boiler can be purchased in toy stores or at...Ch. 11 - Prob. 41ILCh. 11 - Prob. 42ILCh. 11 - Acetone, CH3COCH3, is a common laboratory solvent....Ch. 11 - Cooking oil floats on top of water. From this...Ch. 11 - Liquid ethylene glycol, HOCH2CH2OH, is one of the...Ch. 11 - Liquid methanol, CH3OH, is placed in a glass tube....Ch. 11 - Account for these facts: (a) Although ethanol...Ch. 11 - Prob. 48SCQCh. 11 - Prob. 49SCQCh. 11 - Prob. 50SCQCh. 11 - Prob. 51SCQCh. 11 - Prob. 52SCQCh. 11 - A fluorocarbon, CF4, has a critical temperature of...Ch. 11 - Prob. 55SCQCh. 11 - List four properties of liquids that are directly...Ch. 11 - List the following ions in order of hydration...Ch. 11 - Prob. 59SCQCh. 11 - An 8.82-g sample of Br2 is placed in an evacuated...Ch. 11 - Polarizability is defined as the extent to which...Ch. 11 - Prob. 62SCQCh. 11 - A pressure cooker (a kitchen appliance) is a pot...Ch. 11 - Vapor pressures of NH3() at several temperatures...Ch. 11 - Prob. 65SCQCh. 11 - Prob. 66SCQCh. 11 - Prob. 67SCQ
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