Among the given hydrogen halide, the one with largest total intermolecular forces has to be identified. Concept Introduction: London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles. Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule. Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole. A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

Question

Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.

Answer 1

Question

Chapter 11, Problem 51SCQ

(a)

Interpretation Introduction

Interpretation:

Among the given hydrogen halide, the one with largest total intermolecular forces has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

(b)

Interpretation Introduction

Interpretation:

Reason for the dispersion forces greater for HI than HCl has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

(c)

Interpretation Introduction

Interpretation:

Reason for dipole-dipole forces greater for HCl than for HI has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

(d)

Interpretation Introduction

Interpretation:

Hydrogen halide that has largest dispersion forces has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.

Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br‍(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.

е. Д CH3 D*, D20

Answer 2

Question

Chapter 11, Problem 51SCQ

(a)

Interpretation Introduction

Interpretation:

Among the given hydrogen halide, the one with largest total intermolecular forces has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

(b)

Interpretation Introduction

Interpretation:

Reason for the dispersion forces greater for HI than HCl has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

(c)

Interpretation Introduction

Interpretation:

Reason for dipole-dipole forces greater for HCl than for HI has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

(d)

Interpretation Introduction

Interpretation:

Hydrogen halide that has largest dispersion forces has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

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Answer 3

Question

Chapter 11, Problem 51SCQ

(a)

Interpretation Introduction

Interpretation:

Among the given hydrogen halide, the one with largest total intermolecular forces has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

(b)

Interpretation Introduction

Interpretation:

Reason for the dispersion forces greater for HI than HCl has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

(c)

Interpretation Introduction

Interpretation:

Reason for dipole-dipole forces greater for HCl than for HI has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

(d)

Interpretation Introduction

Interpretation:

Hydrogen halide that has largest dispersion forces has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

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Answer 4

Question

Chapter 11, Problem 51SCQ

(a)

Interpretation Introduction

Interpretation:

Among the given hydrogen halide, the one with largest total intermolecular forces has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

(b)

Interpretation Introduction

Interpretation:

Reason for the dispersion forces greater for HI than HCl has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

(c)

Interpretation Introduction

Interpretation:

Reason for dipole-dipole forces greater for HCl than for HI has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

(d)

Interpretation Introduction

Interpretation:

Hydrogen halide that has largest dispersion forces has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

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Answer 5

Chapter 11, Problem 51SCQ

(a)

Interpretation Introduction

Interpretation:

Among the given hydrogen halide, the one with largest total intermolecular forces has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

(b)

Interpretation Introduction

Interpretation:

Reason for the dispersion forces greater for HI than HCl has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

(c)

Interpretation Introduction

Interpretation:

Reason for dipole-dipole forces greater for HCl than for HI has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

(d)

Interpretation Introduction

Interpretation:

Hydrogen halide that has largest dispersion forces has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

Answer 6

Chapter 11, Problem 51SCQ

(a)

Interpretation Introduction

Interpretation:

Among the given hydrogen halide, the one with largest total intermolecular forces has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

Answer 7

Chapter 11, Problem 51SCQ

(a)

Interpretation Introduction

Interpretation:

Among the given hydrogen halide, the one with largest total intermolecular forces has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

Answer 8

(b)

Interpretation Introduction

Interpretation:

Reason for the dispersion forces greater for HI than HCl has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

Answer 9

(b)

Interpretation Introduction

Interpretation:

Reason for the dispersion forces greater for HI than HCl has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

Answer 10

(c)

Interpretation Introduction

Interpretation:

Reason for dipole-dipole forces greater for HCl than for HI has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

Answer 11

(c)

Interpretation Introduction

Interpretation:

Reason for dipole-dipole forces greater for HCl than for HI has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

Answer 12

(d)

Interpretation Introduction

Interpretation:

Hydrogen halide that has largest dispersion forces has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

Answer 13

(d)

Interpretation Introduction

Interpretation:

Hydrogen halide that has largest dispersion forces has to be identified.

Concept Introduction:

London dispersion force also called an induced dipole-induced dipole attraction is a temporary attractive force that results when the electrons in two adjacent atoms occupy positions that make the atoms form temporary dipoles.

Dipole-dipole interaction results when two dipolar molecules interact with each other through space, there occurs a partially negative charge of one of the polar molecules is attracted to the partially positive charge of the second polar molecule.

Ion-dipole interaction results of an electrostatic interaction between a charged ion and a molecule that has a dipole.

A hydrogen bonding is partially an electrostatic attraction between H atom which is bonded to more electronegative atom such as N, O, or F and another adjacent atom bearing a lone pair of electron

Answer 14

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Ch. 11.2 - Which should have the more negative hydration...Ch. 11.2 - Prob. 1RC Ch. 11.3 - Using structural formulas, describe the hydrogen...Ch. 11.3 - Prob. 1RC Ch. 11.3 - Prob. 2RC Ch. 11.4 - Prob. 1CYU Ch. 11.4 - Prob. 1RC Ch. 11.4 - Prob. 2RC Ch. 11.5 - Prob. 1CYU Ch. 11.5 - 1. What type of intermolecular forces is likely to...

Solution Summary: The author explains that the hydrogen halide with the largest total intermolecular forces is HF Fluorine is small and thus the outer shell of electrons is more affected by the positive nucleus and bound more

Chapter 11 Solutions