Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781305176461
Author: Kotz
Publisher: Cengage
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Chapter 11, Problem 62SCQ
Interpretation Introduction
Interpretation: The organic compounds which have hydrogen bonding have to be identified.
Concept Introduction:
Intermolecular force: The attractive force that withholds two molecules is called as intermolecular force. The influence of intermolecular forces depends on molar mass and the
Hydrogen bonding: The attractive force that holds two polar molecules (containing Hydrogen and highly electronegative atom, such as N, O, or F) is called as hydrogen boding. This is also called as intermolecular hydrogen bonding.
The hydrogen bonding takes place within a molecule is called as intramolecular hydrogen bonding.
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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10
Consider the following reaction:
CH3OH(g)
CO(g) + 2H2(g)
(Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.)
Part A
Calculate AG for this reaction at 25 °C under the following conditions:
PCH₂OH
Pco
PH2
0.815 atm
=
0.140 atm
0.170 atm
Express your answer in kilojoules to three significant figures.
Ο ΑΣΦ
AG = -150
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Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship:
AGrxn = AGrxn + RTInQ,
AGxn+RTInQ,
where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a
is the reaction quotient.
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Chapter 11 Solutions
Chemistry & Chemical Reactivity
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