Organic Chemistry
11th Edition
ISBN: 9781118133576
Author: T. W. Graham Solomons, Craig Fryhle
Publisher: Wiley, John & Sons, Incorporated
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Chapter 11, Problem 42P
Provide reagents that would accomplish the following syntheses.
(a)
(b)
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Provide reagents
(a)
(b)
(c)
Suggest a synthesis of the following alkene (A) using a Wittig reaction strategy. Draw
the starting material(s), key reagent and a full reaction mechanism including an
explanation of the observed geometry.
Which of the following (B) and (C) will favour the enol form? Briefly explain your
reasoning.
Predict the product(s) and provide a mechanism for each of the following
transformations:
(i)
(ii)
OMe
OMe
Base
OEt
NaOEt
(b)
(c)
Suggest a synthesis of the following compound (D) which utilises a conjugate
addition strategy. Explain your reasoning clearly by drawing the mechanism.
D
Ph3P
Me
Predict the product and provide a mechanism for each of the following transformations;
(i)
H
Chapter 11 Solutions
Organic Chemistry
Ch. 11 - Prob. 1PPCh. 11 - Practice Problem 11.2 Give bond-line formulas and...Ch. 11 - Prob. 3PPCh. 11 - Prob. 4PPCh. 11 - Prob. 5PPCh. 11 - Prob. 6PPCh. 11 - Prob. 7PPCh. 11 - PRACTICE PROBLEM
11.8 Show how you would prepare...Ch. 11 - PRACTICE PROBLEM
11.9 Write structures for...Ch. 11 - Prob. 10PP
Ch. 11 - Practice Problem 11.11
An exception to what is...Ch. 11 - Prob. 12PPCh. 11 - Prob. 13PPCh. 11 - Prob. 14PPCh. 11 - Prob. 15PPCh. 11 - Prob. 16PPCh. 11 - Prob. 17PPCh. 11 - Prob. 18PPCh. 11 - Practice Problem 11.19
Propose structures for each...Ch. 11 - Prob. 20PPCh. 11 - Prob. 21PPCh. 11 - Prob. 22PPCh. 11 - Prob. 23PPCh. 11 - Prob. 24PPCh. 11 - Give an IUPAC substitutive name for each of the...Ch. 11 - Prob. 26PCh. 11 - Prob. 27PCh. 11 - Prob. 28PCh. 11 - Prob. 29PCh. 11 - 11.30. Show how you might prepare 2-bromobutane...Ch. 11 - Prob. 31PCh. 11 - Prob. 32PCh. 11 - 11.33 What compounds would you expect to be formed...Ch. 11 - Considering A-L to represent the major products...Ch. 11 - Write structures for the products that would be...Ch. 11 - Prob. 36PCh. 11 - 11.37 Outlined below is a synthesis of the gypsy...Ch. 11 - Provide the reagents necessary for the following...Ch. 11 - 11.38. Predict the major product from each of the...Ch. 11 - Prob. 40PCh. 11 - Provide the reagents necessary to accomplish the...Ch. 11 - 11.41. Provide reagents that would accomplish the...Ch. 11 - Prob. 43PCh. 11 - 11.44 Write a mechanism that accounts for the...Ch. 11 - Prob. 45PCh. 11 - Prob. 46PCh. 11 - Prob. 47PCh. 11 - 11.47. Vicinal halo alcohols (halohydrins) can be...Ch. 11 - Prob. 49PCh. 11 - Prob. 50PCh. 11 - Prob. 51PCh. 11 - Prob. 52PCh. 11 - Prob. 53PCh. 11 - 11.57. When the 3-bromo-2-butanol with the...Ch. 11 - 11.58. Reaction of an alcohol with thionyl...Ch. 11 - Prob. 56PCh. 11 - Prob. 57PCh. 11 - Prob. 1LGPCh. 11 - Prob. 2LGPCh. 11 - Synthesize the compound shown below from...Ch. 11 - 11.1 Which set of reagents would effect the...Ch. 11 - Prob. 2QCh. 11 - 11.3 The following compounds have identical...Ch. 11 - Complete the following synthesis:Ch. 11 - Two configurations can actually be envisioned for...
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