A mechanism for the given reaction is to be proposed. Concept introduction: In an acidic condition, the opening of an epoxide ring occurs. Epoxide open in such a manner that more stable carbocation will form which has the stability order 3 0 > 2 0 >1 0 . The nucleophile attacks on carbocation. Carbocations are planer species so nucleophile prefer to attack from opposite to hydroxyl group present on adjacent carbon due to steric reason.

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Chapter 11, Problem 47P

Interpretation Introduction

Interpretation:

A mechanism for the given reaction is to be proposed.

Concept introduction:

In an acidic condition, the opening of an epoxide ring occurs.

Epoxide open in such a manner that more stable carbocation will form which has the stability order 3⁰ > 2⁰ >1⁰.

The nucleophile attacks on carbocation.

Carbocations are planer species so nucleophile prefer to attack from opposite to hydroxyl group present on adjacent carbon due to steric reason.

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Answer 2

Question

Chapter 11, Problem 47P

Interpretation Introduction

Interpretation:

A mechanism for the given reaction is to be proposed.

Concept introduction:

In an acidic condition, the opening of an epoxide ring occurs.

Epoxide open in such a manner that more stable carbocation will form which has the stability order 3⁰ > 2⁰ >1⁰.

The nucleophile attacks on carbocation.

Carbocations are planer species so nucleophile prefer to attack from opposite to hydroxyl group present on adjacent carbon due to steric reason.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 3

Question

Chapter 11, Problem 47P

Interpretation Introduction

Interpretation:

A mechanism for the given reaction is to be proposed.

Concept introduction:

In an acidic condition, the opening of an epoxide ring occurs.

Epoxide open in such a manner that more stable carbocation will form which has the stability order 3⁰ > 2⁰ >1⁰.

The nucleophile attacks on carbocation.

Carbocations are planer species so nucleophile prefer to attack from opposite to hydroxyl group present on adjacent carbon due to steric reason.

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Answer 4

Question

Chapter 11, Problem 47P

Interpretation Introduction

Interpretation:

A mechanism for the given reaction is to be proposed.

Concept introduction:

In an acidic condition, the opening of an epoxide ring occurs.

Epoxide open in such a manner that more stable carbocation will form which has the stability order 3⁰ > 2⁰ >1⁰.

The nucleophile attacks on carbocation.

Carbocations are planer species so nucleophile prefer to attack from opposite to hydroxyl group present on adjacent carbon due to steric reason.

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Answer 5

Chapter 11, Problem 47P

Interpretation Introduction

Interpretation:

A mechanism for the given reaction is to be proposed.

Concept introduction:

In an acidic condition, the opening of an epoxide ring occurs.

Epoxide open in such a manner that more stable carbocation will form which has the stability order 3⁰ > 2⁰ >1⁰.

The nucleophile attacks on carbocation.

Carbocations are planer species so nucleophile prefer to attack from opposite to hydroxyl group present on adjacent carbon due to steric reason.

Answer 6

Chapter 11, Problem 47P

Interpretation Introduction

Interpretation:

A mechanism for the given reaction is to be proposed.

Concept introduction:

In an acidic condition, the opening of an epoxide ring occurs.

Epoxide open in such a manner that more stable carbocation will form which has the stability order 3⁰ > 2⁰ >1⁰.

The nucleophile attacks on carbocation.

Carbocations are planer species so nucleophile prefer to attack from opposite to hydroxyl group present on adjacent carbon due to steric reason.

Answer 7

Chapter 11, Problem 47P

Interpretation Introduction

Interpretation:

A mechanism for the given reaction is to be proposed.

Concept introduction:

In an acidic condition, the opening of an epoxide ring occurs.

Epoxide open in such a manner that more stable carbocation will form which has the stability order 3⁰ > 2⁰ >1⁰.

The nucleophile attacks on carbocation.

Carbocations are planer species so nucleophile prefer to attack from opposite to hydroxyl group present on adjacent carbon due to steric reason.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 11 - Prob. 1PP Ch. 11 - Practice Problem 11.2 Give bond-line formulas and...Ch. 11 - Prob. 3PP Ch. 11 - Prob. 4PP Ch. 11 - Prob. 5PP Ch. 11 - Prob. 6PP Ch. 11 - Prob. 7PP Ch. 11 - PRACTICE PROBLEM 11.8 Show how you would prepare...Ch. 11 - PRACTICE PROBLEM 11.9 Write structures for...Ch. 11 - Prob. 10PP

Solution Summary: The author explains the mechanism of the reaction. The acid donates the proton to the epoxide oxygen, and the nucleophile attacks the carbocation.

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Chapter 11 Solutions