Organic Chemistry
11th Edition
ISBN: 9781118133576
Author: T. W. Graham Solomons, Craig Fryhle
Publisher: Wiley, John & Sons, Incorporated
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Chapter 11, Problem 13PP
Interpretation Introduction
Interpretation:
Reaction mechanism for the reactions (a) and (b) are to be written. Explanation of no
Concept introduction:
If a proton is removed from the hydroxyl group, the result obtained is an alkoxide ion.
The alkoxide ion reacts further with itself in an intramolecular manner via a
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3. Arrange the different acids in Exercise B # 2 from the strongest (1) to the weakest acid
(10).
1.
2.
(strongest)
3.
4.
5.
6.
7.
8.
9.
10
10.
(weakest)
Name
Section
Score
Date
EXERCISE B
pH, pOH, pка, AND PKD CALCULATIONS
1. Complete the following table.
Solution
[H+]
[OH-]
PH
РОН
Nature of Solution
A
2 x 10-8 M
B
1 x 10-7 M
C
D
12.3
6.8
2. The following table contains the names, formulas, ka or pka for some common acids. Fill
in the blanks in the table. (17 Points)
Acid Name
Formula
Dissociation reaction
Ka
pka
Phosphoric acid
H₂PO₁
H3PO4
H++ H₂PO
7.08 x 10-3
Dihydrogen
H₂PO
H₂PO
H+ HPO
6.31 x 10-6
phosphate
Hydrogen
HPO₁
12.4
phosphate
Carbonic acid
H2CO3
Hydrogen
HCO
6.35
10.3
carbonate or
bicarbonate
Acetic acid
CH,COOH
4.76
Lactic acid
CH₂CHOH-
COOH
1.38 x 10
Ammonium
NH
5.63 x 10-10
Phenol
CH₂OH
1 x 10-10
Protonated form
CH3NH3*
3.16 x 10-11
of methylamine
Indicate whether it is true that Co(III) complexes are very stable.
Chapter 11 Solutions
Organic Chemistry
Ch. 11 - Prob. 1PPCh. 11 - Practice Problem 11.2 Give bond-line formulas and...Ch. 11 - Prob. 3PPCh. 11 - Prob. 4PPCh. 11 - Prob. 5PPCh. 11 - Prob. 6PPCh. 11 - Prob. 7PPCh. 11 - PRACTICE PROBLEM
11.8 Show how you would prepare...Ch. 11 - PRACTICE PROBLEM
11.9 Write structures for...Ch. 11 - Prob. 10PP
Ch. 11 - Practice Problem 11.11
An exception to what is...Ch. 11 - Prob. 12PPCh. 11 - Prob. 13PPCh. 11 - Prob. 14PPCh. 11 - Prob. 15PPCh. 11 - Prob. 16PPCh. 11 - Prob. 17PPCh. 11 - Prob. 18PPCh. 11 - Practice Problem 11.19
Propose structures for each...Ch. 11 - Prob. 20PPCh. 11 - Prob. 21PPCh. 11 - Prob. 22PPCh. 11 - Prob. 23PPCh. 11 - Prob. 24PPCh. 11 - Give an IUPAC substitutive name for each of the...Ch. 11 - Prob. 26PCh. 11 - Prob. 27PCh. 11 - Prob. 28PCh. 11 - Prob. 29PCh. 11 - 11.30. Show how you might prepare 2-bromobutane...Ch. 11 - Prob. 31PCh. 11 - Prob. 32PCh. 11 - 11.33 What compounds would you expect to be formed...Ch. 11 - Considering A-L to represent the major products...Ch. 11 - Write structures for the products that would be...Ch. 11 - Prob. 36PCh. 11 - 11.37 Outlined below is a synthesis of the gypsy...Ch. 11 - Provide the reagents necessary for the following...Ch. 11 - 11.38. Predict the major product from each of the...Ch. 11 - Prob. 40PCh. 11 - Provide the reagents necessary to accomplish the...Ch. 11 - 11.41. Provide reagents that would accomplish the...Ch. 11 - Prob. 43PCh. 11 - 11.44 Write a mechanism that accounts for the...Ch. 11 - Prob. 45PCh. 11 - Prob. 46PCh. 11 - Prob. 47PCh. 11 - 11.47. Vicinal halo alcohols (halohydrins) can be...Ch. 11 - Prob. 49PCh. 11 - Prob. 50PCh. 11 - Prob. 51PCh. 11 - Prob. 52PCh. 11 - Prob. 53PCh. 11 - 11.57. When the 3-bromo-2-butanol with the...Ch. 11 - 11.58. Reaction of an alcohol with thionyl...Ch. 11 - Prob. 56PCh. 11 - Prob. 57PCh. 11 - Prob. 1LGPCh. 11 - Prob. 2LGPCh. 11 - Synthesize the compound shown below from...Ch. 11 - 11.1 Which set of reagents would effect the...Ch. 11 - Prob. 2QCh. 11 - 11.3 The following compounds have identical...Ch. 11 - Complete the following synthesis:Ch. 11 - Two configurations can actually be envisioned for...
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