Principles of Chemistry: A Molecular Approach Plus Mastering Chemistry with eText -- Access Card Package (3rd Edition) (New Chemistry Titles from Niva Tro)
3rd Edition
ISBN: 9780321971166
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 11, Problem 19E
Which evaporates more quickly 55 mL of water in a beaker with a diameter of 4. 5 cm, or 55 mL of water in a dish with a diameter of 12 cm? Is the vapor pressure of the water different in the two containers? Explain.
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Complete the following table. The only density needed is already given. Show your
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should be included and significant figures should be given close attention. Be sure to notice
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mass of the product should in milligrams rather than grams.
LOCH 3
+
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Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 11 Solutions
Principles of Chemistry: A Molecular Approach Plus Mastering Chemistry with eText -- Access Card Package (3rd Edition) (New Chemistry Titles from Niva Tro)
Ch. 11 - Prob. 11.1PCh. 11 - Prob. 11.2PCh. 11 - For Practice 11.3 Calculate the amount of heat (in...Ch. 11 - Prob. 11.3MPCh. 11 - Prob. 11.4PCh. 11 - Prob. 11.5PCh. 11 - Prob. 11.6PCh. 11 - Prob. 1SAQCh. 11 - Liquid nitrogen boils at 77K .The image shown here...Ch. 11 - Prob. 3SAQ
Ch. 11 - Prob. 4SAQCh. 11 - Prob. 5SAQCh. 11 - Prob. 6SAQCh. 11 - Determine the amount of heat (in kJ) required to...Ch. 11 - Prob. 8SAQCh. 11 - Prob. 9SAQCh. 11 - Prob. 10SAQCh. 11 - Prob. 11SAQCh. 11 - Prob. 12SAQCh. 11 - Prob. 13SAQCh. 11 - Prob. 14SAQCh. 11 - Prob. 15SAQCh. 11 - Prob. 1ECh. 11 - Prob. 2ECh. 11 - Prob. 3ECh. 11 - Prob. 4ECh. 11 - Prob. 5ECh. 11 - Prob. 6ECh. 11 - Prob. 7ECh. 11 - Prob. 8ECh. 11 - Prob. 9ECh. 11 - Prob. 10ECh. 11 - Prob. 11ECh. 11 - Prob. 12ECh. 11 - Prob. 13ECh. 11 - Water (a) “wets” some surfaces and beads up on...Ch. 11 - Prob. 15ECh. 11 - Prob. 16ECh. 11 - Prob. 17ECh. 11 - When a thin glass tube is put into water, the...Ch. 11 - Which evaporates more quickly 55 mL of water in a...Ch. 11 - Prob. 20ECh. 11 - Prob. 21ECh. 11 - Prob. 22ECh. 11 - Prob. 23ECh. 11 - Prob. 24ECh. 11 - Prob. 25ECh. 11 - Prob. 26ECh. 11 - Prob. 27ECh. 11 - Prob. 28ECh. 11 - Prob. 29ECh. 11 - Prob. 30ECh. 11 - Prob. 31ECh. 11 - Prob. 32ECh. 11 - Prob. 33ECh. 11 - Prob. 34ECh. 11 - Prob. 35ECh. 11 - Prob. 36ECh. 11 -
37. How muchheat (in kJ) is required to warm 10.0...Ch. 11 - Prob. 38ECh. 11 - Prob. 39ECh. 11 - Consider the phase diagram for iodine and answer...Ch. 11 - Prob. 41ECh. 11 - Prob. 42ECh. 11 - Prob. 43ECh. 11 - Prob. 44ECh. 11 - Water has a high boiling point for its relatively...Ch. 11 - Prob. 46ECh. 11 - Prob. 47ECh. 11 - Prob. 48ECh. 11 - Prob. 49ECh. 11 - Prob. 50ECh. 11 - Prob. 51ECh. 11 - Prob. 52ECh. 11 - Prob. 53ECh. 11 - Barium has a density of 3.59 g/cm3 and...Ch. 11 - Prob. 55ECh. 11 - Prob. 56ECh. 11 - Prob. 57ECh. 11 - Prob. 58ECh. 11 - Prob. 59ECh. 11 - Prob. 60ECh. 11 - Prob. 61ECh. 11 - Prob. 62ECh. 11 - An oxide of titanium crystallizes with the unit...Ch. 11 - Prob. 64ECh. 11 - Prob. 65ECh. 11 - Prob. 66ECh. 11 - Prob. 67ECh. 11 - Prob. 68ECh. 11 - Prob. 69ECh. 11 - Prob. 70ECh. 11 - Prob. 71ECh. 11 - Prob. 72ECh. 11 - Prob. 73ECh. 11 - Carbon tetrachloride displays a triple point at...Ch. 11 - Prob. 75ECh. 11 - Prob. 76ECh. 11 - Prob. 77ECh. 11 - Draw a heating curve (such as the one in Figure...Ch. 11 - Prob. 79ECh. 11 - Prob. 80ECh. 11 - Prob. 81ECh. 11 - Prob. 82ECh. 11 - Prob. 83ECh. 11 - Prob. 84ECh. 11 - Prob. 85ECh. 11 - Prob. 86ECh. 11 - Prob. 87ECh. 11 - Consider a planet where the pressure of the...Ch. 11 - Prob. 89ECh. 11 - Prob. 90ECh. 11 - Prob. 91ECh. 11 - Prob. 92ECh. 11 - Prob. 93ECh. 11 - Prob. 94ECh. 11 - Prob. 95ECh. 11 - Prob. 96ECh. 11 - Prob. 97ECh. 11 - Prob. 98ECh. 11 - Prob. 99ECh. 11 - Prob. 100ECh. 11 - Prob. 101ECh. 11 - Prob. 102ECh. 11 - Prob. 103ECh. 11 - Examine the heating curve for water in Section...Ch. 11 - Prob. 105ECh. 11 - Prob. 106ECh. 11 - Prob. 107ECh. 11 - Prob. 108E
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