The molecular formula and the class of hydrocarbon of cyclohexane have to be given. Concept Introduction: A cyclic hydrocarbon is given by the prefix- cyclo . Class of hydrocarbons: Alkanes : Saturated hydrocarbons are called as alkanes. Each atom in an alkane shows the presence of four single bonds in a tetrahedral arrangement with sp 3 hybridization. The name of alkane ends with “-ane” . Alkenes : The simplest unsaturated hydrocarbon with a double bond is called as alkene. The name of alkane ends with “-ene” . Alkynes : Alkynes are hydrocarbons with one carbon-carbon triple bond. The name of the alkyne ends with “-yne” .

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Answer 1

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Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 11, Problem 11A.2E

(a)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of cyclohexane have to be given.

Concept Introduction:

A cyclic hydrocarbon is given by the prefix-cyclo.

Class of hydrocarbons:

Alkanes: Saturated hydrocarbons are called as alkanes. Each atom in an alkane shows the presence of four single bonds in a tetrahedral arrangement with sp3 hybridization. The name of alkane ends with “-ane”.

Alkenes: The simplest unsaturated hydrocarbon with a double bond is called as alkene. The name of alkane ends with “-ene”.

Alkynes: Alkynes are hydrocarbons with one carbon-carbon triple bond. The name of the alkyne ends with “-yne”.

(b)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of cyclopentadiene have to be given.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of propene have to be given.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of butyne have to be given.

Concept Introduction:

Refer to part (a).

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Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…

Propose a synthesis pathway for the following transformations. b) c) d)

Answer 2

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 11, Problem 11A.2E

(a)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of cyclohexane have to be given.

Concept Introduction:

A cyclic hydrocarbon is given by the prefix-cyclo.

Class of hydrocarbons:

Alkanes: Saturated hydrocarbons are called as alkanes. Each atom in an alkane shows the presence of four single bonds in a tetrahedral arrangement with sp3 hybridization. The name of alkane ends with “-ane”.

Alkenes: The simplest unsaturated hydrocarbon with a double bond is called as alkene. The name of alkane ends with “-ene”.

Alkynes: Alkynes are hydrocarbons with one carbon-carbon triple bond. The name of the alkyne ends with “-yne”.

(b)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of cyclopentadiene have to be given.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of propene have to be given.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of butyne have to be given.

Concept Introduction:

Refer to part (a).

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Answer 3

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 11, Problem 11A.2E

(a)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of cyclohexane have to be given.

Concept Introduction:

A cyclic hydrocarbon is given by the prefix-cyclo.

Class of hydrocarbons:

Alkanes: Saturated hydrocarbons are called as alkanes. Each atom in an alkane shows the presence of four single bonds in a tetrahedral arrangement with sp3 hybridization. The name of alkane ends with “-ane”.

Alkenes: The simplest unsaturated hydrocarbon with a double bond is called as alkene. The name of alkane ends with “-ene”.

Alkynes: Alkynes are hydrocarbons with one carbon-carbon triple bond. The name of the alkyne ends with “-yne”.

(b)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of cyclopentadiene have to be given.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of propene have to be given.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of butyne have to be given.

Concept Introduction:

Refer to part (a).

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Answer 4

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 11, Problem 11A.2E

(a)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of cyclohexane have to be given.

Concept Introduction:

A cyclic hydrocarbon is given by the prefix-cyclo.

Class of hydrocarbons:

Alkanes: Saturated hydrocarbons are called as alkanes. Each atom in an alkane shows the presence of four single bonds in a tetrahedral arrangement with sp3 hybridization. The name of alkane ends with “-ane”.

Alkenes: The simplest unsaturated hydrocarbon with a double bond is called as alkene. The name of alkane ends with “-ene”.

Alkynes: Alkynes are hydrocarbons with one carbon-carbon triple bond. The name of the alkyne ends with “-yne”.

(b)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of cyclopentadiene have to be given.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of propene have to be given.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of butyne have to be given.

Concept Introduction:

Refer to part (a).

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Answer 5

Chapter 11, Problem 11A.2E

(a)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of cyclohexane have to be given.

Concept Introduction:

A cyclic hydrocarbon is given by the prefix-cyclo.

Class of hydrocarbons:

Alkanes: Saturated hydrocarbons are called as alkanes. Each atom in an alkane shows the presence of four single bonds in a tetrahedral arrangement with sp3 hybridization. The name of alkane ends with “-ane”.

Alkenes: The simplest unsaturated hydrocarbon with a double bond is called as alkene. The name of alkane ends with “-ene”.

Alkynes: Alkynes are hydrocarbons with one carbon-carbon triple bond. The name of the alkyne ends with “-yne”.

(b)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of cyclopentadiene have to be given.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of propene have to be given.

Concept Introduction:

Refer to part (a).

(d)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of butyne have to be given.

Concept Introduction:

Refer to part (a).

Answer 6

Chapter 11, Problem 11A.2E

(a)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of cyclohexane have to be given.

Concept Introduction:

A cyclic hydrocarbon is given by the prefix-cyclo.

Class of hydrocarbons:

Alkanes: Saturated hydrocarbons are called as alkanes. Each atom in an alkane shows the presence of four single bonds in a tetrahedral arrangement with sp3 hybridization. The name of alkane ends with “-ane”.

Alkenes: The simplest unsaturated hydrocarbon with a double bond is called as alkene. The name of alkane ends with “-ene”.

Alkynes: Alkynes are hydrocarbons with one carbon-carbon triple bond. The name of the alkyne ends with “-yne”.

Answer 7

Chapter 11, Problem 11A.2E

(a)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of cyclohexane have to be given.

Concept Introduction:

A cyclic hydrocarbon is given by the prefix-cyclo.

Class of hydrocarbons:

Alkanes: Saturated hydrocarbons are called as alkanes. Each atom in an alkane shows the presence of four single bonds in a tetrahedral arrangement with sp3 hybridization. The name of alkane ends with “-ane”.

Alkenes: The simplest unsaturated hydrocarbon with a double bond is called as alkene. The name of alkane ends with “-ene”.

Alkynes: Alkynes are hydrocarbons with one carbon-carbon triple bond. The name of the alkyne ends with “-yne”.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of cyclopentadiene have to be given.

Concept Introduction:

Refer to part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of cyclopentadiene have to be given.

Concept Introduction:

Refer to part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of propene have to be given.

Concept Introduction:

Refer to part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of propene have to be given.

Concept Introduction:

Refer to part (a).

Answer 12

(d)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of butyne have to be given.

Concept Introduction:

Refer to part (a).

Answer 13

(d)

Interpretation Introduction

Interpretation:

The molecular formula and the class of hydrocarbon of butyne have to be given.

Concept Introduction:

Refer to part (a).

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 11 - Prob. 11A.1AST Ch. 11 - Prob. 11A.1BST Ch. 11 - Prob. 11A.2AST Ch. 11 - Prob. 11A.2BST Ch. 11 - Prob. 11A.3AST Ch. 11 - Prob. 11A.3BST Ch. 11 - Prob. 11A.4AST Ch. 11 - Prob. 11A.4BST Ch. 11 - Prob. 11A.5AST Ch. 11 - Prob. 11A.5BST

Solution Summary: The author explains the molecular formula and the class of hydrocarbon of cyclohexane.

Concept explainers

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Interpretation:

The molecular formula and the class of hydrocarbon of cyclopentadiene have to be given.

Concept Introduction:

Refer to part (a).

Interpretation:

The molecular formula and the class of hydrocarbon of propene have to be given.

Concept Introduction:

Refer to part (a).

Interpretation:

The molecular formula and the class of hydrocarbon of butyne have to be given.

Concept Introduction:

Refer to part (a).

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Chapter 11 Solutions

Solution Summary: The author explains the molecular formula and the class of hydrocarbon of cyclohexane.

Concept explainers

Videos

Interpretation: The molecular formula and the class of hydrocarbon of cyclopentadiene have to be given. Concept Introduction: Refer to part (a).

Interpretation: The molecular formula and the class of hydrocarbon of propene have to be given. Concept Introduction: Refer to part (a).

Interpretation: The molecular formula and the class of hydrocarbon of butyne have to be given. Concept Introduction: Refer to part (a).

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Chapter 11 Solutions

Interpretation:

The molecular formula and the class of hydrocarbon of cyclopentadiene have to be given.

Concept Introduction:

Refer to part (a).

Interpretation:

The molecular formula and the class of hydrocarbon of propene have to be given.

Concept Introduction:

Refer to part (a).

Interpretation:

The molecular formula and the class of hydrocarbon of butyne have to be given.

Concept Introduction:

Refer to part (a).