The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified. Concept Introduction: Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms. Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms. Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

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Answer 1

Question

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

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Experiment: Each team will be provided with 5g of a mixture of acetanilide and salicylic acid. You will divide it into three 1.5 g portions in separate 125 mL Erlenmeyer flasks savıng some for melting point analysis. Dissolve the mixture in each flask in ~60mL of DI water by heating to boiling on a hotplate. Take the flasks off the hotplate once you have a clear solution and let them stand on the bench top for 5 mins and then allow them to cool as described below. Sample A-Let the first sample cool slowly to room temperature by letting it stand on your lab bench, with occasional stirring to promote crystallization. Sample B-Cool the second sample 1n a tap-water bath to 10-15 °C Sample C-Cool the third sample in an ice-bath to 0-2 °C Results: weight after recrystalization and melting point temp. A=0.624g,102-115° B=0.765g, 80-105° C=1.135g, 77-108 What is the percent yield of A,B, and C.

Answer 2

Question

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

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Answer 3

Question

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

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Answer 4

Question

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

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Answer 5

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

Answer 6

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

Answer 7

Chapter 11, Problem 11A.24E

(a)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-chlorohexane and chlorocyclohexane has to be identified.

Concept Introduction:

Structural isomers: Structural isomers of the compounds have same molecular formula but difference in the spatial arrangement of atoms.

Stereoisomers: Stereoisomers have the same connectivity but difference in the spatial arrangement of atoms.

Geometrical isomers: In geometrical isomers, atoms have different arrangements on either side of a double bond above or below the ring of a cycloalkane or cycloalkane. If the atoms are present on the same side of the double bond, then it is cis-isomer and if they are present on the opposite side of the double bond, then it is trans-isomer.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 11 - Prob. 11A.1AST Ch. 11 - Prob. 11A.1BST Ch. 11 - Prob. 11A.2AST Ch. 11 - Prob. 11A.2BST Ch. 11 - Prob. 11A.3AST Ch. 11 - Prob. 11A.3BST Ch. 11 - Prob. 11A.4AST Ch. 11 - Prob. 11A.4BST Ch. 11 - Prob. 11A.5AST Ch. 11 - Prob. 11A.5BST

Solution Summary: The author explains that 1-chlorohexane and 2-butene are structural isomers with the same molecular formula but different spatial arrangement of atoms.

Concept explainers

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).

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Chapter 11 Solutions

Solution Summary: The author explains that 1-chlorohexane and 2-butene are structural isomers with the same molecular formula but different spatial arrangement of atoms.

Concept explainers

Interpretation: The isomeric relationship between 1-butene and 2-butene has to be identified. Concept Introduction: Refer to part (a).

Interpretation: The isomeric relationship between 1,2-dichloroethene has to be identified. Concept Introduction: Refer to part (a).

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Chapter 11 Solutions

Interpretation:

The isomeric relationship between 1-butene and 2-butene has to be identified.

Concept Introduction:

Refer to part (a).

Interpretation:

The isomeric relationship between 1,2-dichloroethene has to be identified.

Concept Introduction:

Refer to part (a).